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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
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Volume 9, issue 14 | Copyright
Atmos. Chem. Phys., 9, 4987-5005, 2009
https://doi.org/10.5194/acp-9-4987-2009
© Author(s) 2009. This work is distributed under
the Creative Commons Attribution 3.0 License.

  27 Jul 2009

27 Jul 2009

A review of Secondary Organic Aerosol (SOA) formation from isoprene

A. G. Carlton1, C. Wiedinmyer2, and J. H. Kroll3,* A. G. Carlton et al.
  • 1US EPA, Office of Research and Development, Atmospheric Modeling and Analysis Division, Research Triangle Park, NC 27711, USA
  • 2National Center for Atmospheric Research, Atmospheric Chemistry Division, Boulder, CO 80309, USA
  • 3Aerodyne Research, Inc. 45 Manning Road, Billerica, MA 01821, USA
  • *currently at: Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, 15 Vassar St. Bldg. 48–323, Cambridge, MA 02139, USA

Abstract. Recent field and laboratory evidence indicates that the oxidation of isoprene, (2-methyl-1,3-butadiene, C5H8) forms secondary organic aerosol (SOA). Global biogenic emissions of isoprene (600 Tg yr−1) are sufficiently large that the formation of SOA in even small yields results in substantial production of atmospheric particulate matter, likely having implications for air quality and climate. Here we present a review of field measurements, experimental work, and modeling studies aimed at understanding the mechanisms, yield, and atmospheric importance of isoprene-derived SOA. SOA yields depend on a number of factors, including organic aerosol loading (Mo), NOx level (RO2 chemistry), and, because of the importance of multigenerational chemistry, the degree of oxidation. These dependences are not always included in SOA modules used in atmospheric transport models, and instead most yield parameterizations rely on a single set of chamber experiments (carried out over a limited range of conditions); this may lead to very different estimates of the atmospheric importance of isoprene SOA. New yield parameterizations, based on all available laboratory data (Mo=0–50 μg m−3), are presented here, so that SOA formation may be computed as a function of Mo, NOx level, and temperature. Current research needs and future research directions are identified.

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