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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
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Volume 7, issue 19 | Copyright
Atmos. Chem. Phys., 7, 5159-5174, 2007
https://doi.org/10.5194/acp-7-5159-2007
© Author(s) 2007. This work is licensed under
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.

  08 Oct 2007

08 Oct 2007

Effect of NOx level on secondary organic aerosol (SOA) formation from the photooxidation of terpenes

N. L. Ng1, P. S. Chhabra1, A. W. H. Chan1, J. D. Surratt2, J. H. Kroll3, A. J. Kwan4, D. C. McCabe4, P. O. Wennberg4, A. Sorooshian1, S. M. Murphy1, N. F. Dalleska4, R. C. Flagan1,4, and J. H. Seinfeld1,4 N. L. Ng et al.
  • 1Department of Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA
  • 2Department of Chemistry, California Institute of Technology, Pasadena, CA 91125, USA
  • 3Aerodyne Research, Inc., Billerica, MA 01821, USA
  • 4Department of Environmental Science and Engineering, California Institute of Technology, Pasadena, CA 91125, USA

Abstract. Secondary organic aerosol (SOA) formation from the photooxidation of one monoterpene (α-pinene) and two sesquiterpenes (longifolene and aromadendrene) is investigated in the Caltech environmental chambers. The effect of NOx on SOA formation for these biogenic hydrocarbons is evaluated by performing photooxidation experiments under varying NOx conditions. The NOx dependence of α-pinene SOA formation follows the same trend as that observed previously for a number of SOA precursors, including isoprene, in which SOA yield (defined as the ratio of the mass of organic aerosol formed to the mass of parent hydrocarbon reacted) decreases as NOx level increases. The NOx dependence of SOA yield for the sesquiterpenes, longifolene and aromadendrene, however, differs from that determined for isoprene and α-pinene; the aerosol yield under high-NOx conditions substantially exceeds that under low-NOx conditions. The reversal of the NOx dependence of SOA formation for the sesquiterpenes is consistent with formation of relatively low-volatility organic nitrates, and/or the isomerization of large alkoxy radicals leading to less volatile products. Analysis of the aerosol chemical composition for longifolene confirms the presence of organic nitrates under high-NOx conditions. Consequently the formation of SOA from certain biogenic hydrocarbons such as sesquiterpenes (and possibly large anthropogenic hydrocarbons as well) may be more efficient in polluted air.

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