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ACP | Articles | Volume 20, issue 9
Atmos. Chem. Phys., 20, 5513–5526, 2020
https://doi.org/10.5194/acp-20-5513-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 20, 5513–5526, 2020
https://doi.org/10.5194/acp-20-5513-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 12 May 2020

Research article | 12 May 2020

Partitioning of hydrogen peroxide in gas-liquid and gas-aerosol phases

Xiaoning Xuan et al.

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Cited articles

Adamowicz, R. F.: A model for the reversible washout of sulfur-dioxide, ammonia and carbon-dioxide from a polluted atmosphere and the production of sulfates in raindrops, Atmos. Environ., 13, 105–121, https://doi.org/10.1016/0004-6981(79)90250-6, 1979. 
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Banerjee, D. K. and Budke, C. C.: Spectrophotometric determination of traces of peroxides in organic solvents, Anal. Chem., 36, 792–796, https://doi.org/10.1021/ac60210a027, 1964. 
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Campbell, S. J., Stevanovic, S., Miljevic, B., Bottle, S. E., Ristovski, Z., and Kalberer, M.: Quantification of particle-bound organic radicals in secondary organic aerosol, Environ. Sci. Technol., 53, 6729–6737, https://doi.org/10.1021/acs.est.9b00825, 2019. 
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In this study, we found that the effective field-derived Henry's law constant for the ground rainwater and the gas-phase H2O2 was about 2.5 times that of the theoretical value, and the effective gas–particle partitioning coefficient for the aerosol particle and the gas-phase H2O2 was 4 orders of magnitude higher than the theoretical one. We suggested the missing source of H2O2 in the particulate phase, e.g. the contribution from the decomposition/hydrolysis of organic peroxides.
In this study, we found that the effective field-derived Henry's law constant for the ground...
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