Articles | Volume 20, issue 9
https://doi.org/10.5194/acp-20-5405-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-5405-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Characteristics of methanesulfonic acid, non-sea-salt sulfate and organic carbon aerosols over the Amundsen Sea, Antarctica
Korea Polar Research Institute, 26 Songdomirae-ro, Yeonsu-gu, Incheon
21990, Republic of Korea
Sang-Bum Hong
Korea Polar Research Institute, 26 Songdomirae-ro, Yeonsu-gu, Incheon
21990, Republic of Korea
Meilian Chen
Sejong University, 209 Neungdong-ro, Gwangjin-gu, Seoul 05006,
Republic of Korea
Environmental program, Guangdong Technion-Israel Institute of
Technology, Shantou 515063, China
Jin Hur
Sejong University, 209 Neungdong-ro, Gwangjin-gu, Seoul 05006,
Republic of Korea
Liping Jiao
Third Institute of Oceanography, State Oceanic Administration, Xiamen
361005, China
Youngju Lee
Korea Polar Research Institute, 26 Songdomirae-ro, Yeonsu-gu, Incheon
21990, Republic of Korea
Keyhong Park
Korea Polar Research Institute, 26 Songdomirae-ro, Yeonsu-gu, Incheon
21990, Republic of Korea
Doshik Hahm
Pusan National University, Busan 46241, Republic of Korea
Jung-Ok Choi
Korea Polar Research Institute, 26 Songdomirae-ro, Yeonsu-gu, Incheon
21990, Republic of Korea
Eun Jin Yang
Korea Polar Research Institute, 26 Songdomirae-ro, Yeonsu-gu, Incheon
21990, Republic of Korea
Jisoo Park
Korea Polar Research Institute, 26 Songdomirae-ro, Yeonsu-gu, Incheon
21990, Republic of Korea
Tae-Wan Kim
Korea Polar Research Institute, 26 Songdomirae-ro, Yeonsu-gu, Incheon
21990, Republic of Korea
SangHoon Lee
Korea Polar Research Institute, 26 Songdomirae-ro, Yeonsu-gu, Incheon
21990, Republic of Korea
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Sang H. Lee, Bo Kyung Kim, Yu Jeong Lim, HuiTae Joo, Jae Joong Kang, Dabin Lee, Jisoo Park, Sun-Yong Ha, and Sang Hoon Lee
Biogeosciences, 14, 3705–3713, https://doi.org/10.5194/bg-14-3705-2017, https://doi.org/10.5194/bg-14-3705-2017, 2017
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Little information on the contribution of small-sized phytoplankton is currently available in the Amundsen Sea. Based on a strong negative correlation between the contributions of small phytoplankton and the total daily primary production of phytoplankton found in this study, we concluded that a potential decrease in total primary production would be led by increasing contribution of small phytoplankton in the Amundsen Sea under rapidly warming environmental conditions.
J. Jung, H. Furutani, M. Uematsu, S. Kim, and S. Yoon
Atmos. Chem. Phys., 13, 411–428, https://doi.org/10.5194/acp-13-411-2013, https://doi.org/10.5194/acp-13-411-2013, 2013
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
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We investigate Cl− depletion in sea salt particles over the northwest Atlantic from December 2021 to June 2022 using an airborne dataset. Losses of Cl− are greatest in May and least in December–February and March. Inorganic acidic species can account for all depletion observed for December–February, March, and June near Bermuda but none in May. Quantifying Cl− depletion as a percentage captures seasonal trends in depletion but fails to convey the effects it may have on atmospheric oxidation.
Yue Sun, Yujiao Zhu, Yanbin Qi, Lanxiadi Chen, Jiangshan Mu, Ye Shan, Yu Yang, Yanqiu Nie, Ping Liu, Can Cui, Ji Zhang, Mingxuan Liu, Lingli Zhang, Yufei Wang, Xinfeng Wang, Mingjin Tang, Wenxing Wang, and Likun Xue
Atmos. Chem. Phys., 24, 3241–3256, https://doi.org/10.5194/acp-24-3241-2024, https://doi.org/10.5194/acp-24-3241-2024, 2024
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Field observations were conducted at the summit of Changbai Mountain in northeast Asia. The cumulative number concentration of ice-nucleating particles (INPs) varied from 1.6 × 10−3 to 78.3 L−1 over the temperature range of −5.5 to −29.0 ℃. Biological INPs (bio-INPs) accounted for the majority of INPs, and the proportion exceeded 90% above −13.0 ℃. Planetary boundary layer height, valley breezes, and long-distance transport of air mass influence the abundance of bio-INPs.
Cuizhi Sun, Yongyun Zhang, Baoling Liang, Min Gao, Xi Sun, Fei Li, Xue Ni, Qibin Sun, Hengjia Ou, Dexian Chen, Shengzhen Zhou, and Jun Zhao
Atmos. Chem. Phys., 24, 3043–3063, https://doi.org/10.5194/acp-24-3043-2024, https://doi.org/10.5194/acp-24-3043-2024, 2024
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In a May–June 2021 expedition in the South China Sea, we analyzed black and brown carbon in marine aerosols, key to light absorption and climate impact. Using advanced in situ and microscope techniques, we observed particle size, structure, and tar balls mixed with various elements. Results showed biomass burning and fossil fuels majorly influence light absorption, especially during significant burning events. This research aids the understanding of carbonaceous aerosols' role in marine climate.
C. Isabel Moreno, Radovan Krejci, Jean-Luc Jaffrezo, Gaëlle Uzu, Andrés Alastuey, Marcos F. Andrade, Valeria Mardóñez, Alkuin Maximilian Koenig, Diego Aliaga, Claudia Mohr, Laura Ticona, Fernando Velarde, Luis Blacutt, Ricardo Forno, David N. Whiteman, Alfred Wiedensohler, Patrick Ginot, and Paolo Laj
Atmos. Chem. Phys., 24, 2837–2860, https://doi.org/10.5194/acp-24-2837-2024, https://doi.org/10.5194/acp-24-2837-2024, 2024
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Aerosol chemical composition (ions, sugars, carbonaceous matter) from 2011 to 2020 was studied at Mt. Chacaltaya (5380 m a.s.l., Bolivian Andes). Minimum concentrations occur in the rainy season with maxima in the dry and transition seasons. The origins of the aerosol are located in a radius of hundreds of kilometers: nearby urban and rural areas, natural biogenic emissions, vegetation burning from Amazonia and Chaco, Pacific Ocean emissions, soil dust, and Peruvian volcanism.
Junke Zhang, Yunfei Su, Chunying Chen, Wenkai Guo, Qinwen Tan, Miao Feng, Danlin Song, Tao Jiang, Qiang Chen, Yuan Li, Wei Li, Yizhi Wang, Xiaojuan Huang, Lin Han, Wanqing Wu, and Gehui Wang
Atmos. Chem. Phys., 24, 2803–2820, https://doi.org/10.5194/acp-24-2803-2024, https://doi.org/10.5194/acp-24-2803-2024, 2024
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Typical haze events in Chengdu at the beginning of 2023 were investigated with bulk-chemical and single-particle analyses along with numerical model simulations. By integrating the obtained chemical composition, source, mixing state and numerical simulation results, we infer that Haze-1 was mainly caused by pollutants related to fossil fuel combustion, especially local mobile sources, while Haze-2 was triggered by the secondary pollutants, which mainly came from regional transmission.
Elena Barbaro, Matteo Feltracco, Fabrizio De Blasi, Clara Turetta, Marta Radaelli, Warren Cairns, Giulio Cozzi, Giovanna Mazzi, Marco Casula, Jacopo Gabrieli, Carlo Barbante, and Andrea Gambaro
Atmos. Chem. Phys., 24, 2821–2835, https://doi.org/10.5194/acp-24-2821-2024, https://doi.org/10.5194/acp-24-2821-2024, 2024
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The study analyzed a year of atmospheric aerosol composition at Col Margherita in the Italian Alps. Over 100 chemical markers were identified, including major ions, organic compounds, and trace elements. It revealed sources of aerosol, highlighted impacts of Saharan dust events, and showed anthropogenic pollution's influence despite the site's remoteness. Enrichment factors emphasized non-natural sources of trace elements. Source apportionment identified four key factors affecting the area.
Karl Espen Yttri, Are Bäcklund, Franz Conen, Sabine Eckhardt, Nikolaos Evangeliou, Markus Fiebig, Anne Kasper-Giebl, Avram Gold, Hans Gundersen, Cathrine Lund Myhre, Stephen Matthew Platt, David Simpson, Jason D. Surratt, Sönke Szidat, Martin Rauber, Kjetil Tørseth, Martin Album Ytre-Eide, Zhenfa Zhang, and Wenche Aas
Atmos. Chem. Phys., 24, 2731–2758, https://doi.org/10.5194/acp-24-2731-2024, https://doi.org/10.5194/acp-24-2731-2024, 2024
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We discuss carbonaceous aerosol (CA) observed at the high Arctic Zeppelin Observatory (2017 to 2020). We find that organic aerosol is a significant fraction of the Arctic aerosol, though less than sea salt aerosol and mineral dust, as well as non-sea-salt sulfate, originating mainly from anthropogenic sources in winter and from natural sources in summer, emphasizing the importance of wildfires for biogenic secondary organic aerosol and primary biological aerosol particles observed in the Arctic.
Wei Huang, Cheng Wu, Linyu Gao, Yvette Gramlich, Sophie L. Haslett, Joel Thornton, Felipe D. Lopez-Hilfiker, Ben H. Lee, Junwei Song, Harald Saathoff, Xiaoli Shen, Ramakrishna Ramisetty, Sachchida N. Tripathi, Dilip Ganguly, Feng Jiang, Magdalena Vallon, Siegfried Schobesberger, Taina Yli-Juuti, and Claudia Mohr
Atmos. Chem. Phys., 24, 2607–2624, https://doi.org/10.5194/acp-24-2607-2024, https://doi.org/10.5194/acp-24-2607-2024, 2024
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We present distinct molecular composition and volatility of oxygenated organic aerosol particles in different rural, urban, and mountain environments. We do a comprehensive investigation of the relationship between the chemical composition and volatility of oxygenated organic aerosol particles across different systems and environments. This study provides implications for volatility descriptions of oxygenated organic aerosol particles in different model frameworks.
Jing Cai, Juha Sulo, Yifang Gu, Sebastian Holm, Runlong Cai, Steven Thomas, Almuth Neuberger, Fredrik Mattsson, Marco Paglione, Stefano Decesari, Matteo Rinaldi, Rujing Yin, Diego Aliaga, Wei Huang, Yuanyuan Li, Yvette Gramlich, Giancarlo Ciarelli, Lauriane Quéléver, Nina Sarnela, Katrianne Lehtipalo, Nora Zannoni, Cheng Wu, Wei Nie, Juha Kangasluoma, Claudia Mohr, Markku Kulmala, Qiaozhi Zha, Dominik Stolzenburg, and Federico Bianchi
Atmos. Chem. Phys., 24, 2423–2441, https://doi.org/10.5194/acp-24-2423-2024, https://doi.org/10.5194/acp-24-2423-2024, 2024
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By combining field measurements, simulations and recent chamber experiments, we investigate new particle formation (NPF) and growth in the Po Valley, where both haze and frequent NPF occur. Our results show that sulfuric acid, ammonia and amines are the dominant NPF precursors there. A high NPF rate and a lower condensation sink lead to a greater survival probability for newly formed particles, highlighting the importance of gas-to-particle conversion for aerosol concentrations.
Kaori Kawana, Fumikazu Taketani, Kazuhiko Matsumoto, Yutaka Tobo, Yoko Iwamoto, Takuma Miyakawa, Akinori Ito, and Yugo Kanaya
Atmos. Chem. Phys., 24, 1777–1799, https://doi.org/10.5194/acp-24-1777-2024, https://doi.org/10.5194/acp-24-1777-2024, 2024
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Based on comprehensive shipborne observations, we found strong links between sea-surface biological materials and the formation of atmospheric fluorescent bioaerosols, cloud condensation nuclei, and ice-nucleating particles over the Arctic Ocean and Bering Sea during autumn 2019. Taking the wind-speed effect into account, we propose equations to approximate the links for this cruise, which can be used as a guide for modeling as well as for systematic comparisons with other observations.
Chen He, Hanxiong Che, Zier Bao, Yiliang Liu, Qing Li, Miao Hu, Jiawei Zhou, Shumin Zhang, Xiaojiang Yao, Quan Shi, Chunmao Chen, Yan Han, Lingshuo Meng, Xin Long, Fumo Yang, and Yang Chen
Atmos. Chem. Phys., 24, 1627–1639, https://doi.org/10.5194/acp-24-1627-2024, https://doi.org/10.5194/acp-24-1627-2024, 2024
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We examined the daily evolution of high molecular-weight organic compounds with a molecular weight of up to 1000 Da in order to comprehend their behaviors in the atmosphere under actual conditions. These compounds were proven to undergo multi-generation oxidation, carboxylation, and nitrification via both day- and nighttime chemistry.
Karine Desboeufs, Paola Formenti, Raquel Torres-Sánchez, Kerstin Schepanski, Jean-Pierre Chaboureau, Hendrik Andersen, Jan Cermak, Stefanie Feuerstein, Benoit Laurent, Danitza Klopper, Andreas Namwoonde, Mathieu Cazaunau, Servanne Chevaillier, Anaïs Feron, Cécile Mirande-Bret, Sylvain Triquet, and Stuart J. Piketh
Atmos. Chem. Phys., 24, 1525–1541, https://doi.org/10.5194/acp-24-1525-2024, https://doi.org/10.5194/acp-24-1525-2024, 2024
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This study investigates the fractional solubility of iron (Fe) in dust particles along the coast of Namibia, a critical region for the atmospheric Fe supply of the South Atlantic Ocean. Our results suggest a possible two-way interplay whereby marine biogenic emissions from the coastal marine ecosystems into the atmosphere would increase the solubility of Fe-bearing dust by photo-reduction processes. The subsequent deposition of soluble Fe could act to further enhance marine biogenic emissions.
Sunhye Kim, Jo Machesky, Drew R. Gentner, and Albert A. Presto
Atmos. Chem. Phys., 24, 1281–1298, https://doi.org/10.5194/acp-24-1281-2024, https://doi.org/10.5194/acp-24-1281-2024, 2024
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Cooking emissions are often an overlooked source of air pollution. We used a mobile lab to measure the characteristics of particles emitted from cooking sites in two cities. Our findings showed that cooking releases a substantial number of fine particles. While most emissions were similar, a bakery site showed distinctive chemical compositions with higher nitrogen compound levels. Thus, understanding the particle emissions from different cooking activities is crucial.
Nansi Fakhri, Robin Stevens, Arnold Downey, Konstantina Oikonomou, Jean Sciare, Charbel Afif, and Patrick L. Hayes
Atmos. Chem. Phys., 24, 1193–1212, https://doi.org/10.5194/acp-24-1193-2024, https://doi.org/10.5194/acp-24-1193-2024, 2024
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We investigated the chemical composition of atmospheric fine particles, their emission sources, and the potential human health risk associated with trace elements in particles for an urban site in Montréal over a 3-month period (August–November). This study represents the first time that such extensive composition measurements were included in an urban source apportionment study in Canada, and it provides greater resolution of fine-particle sources than has been previously achieved in Canada.
Hanjin Yoo, Li Wu, Hong Geng, and Chul-Un Ro
Atmos. Chem. Phys., 24, 853–867, https://doi.org/10.5194/acp-24-853-2024, https://doi.org/10.5194/acp-24-853-2024, 2024
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We conducted an investigation of atmospheric aerosols collected in Seoul, South Korea, during the KORUS-AQ campaign on a single-particle basis. We were able to identify their sources, the atmospheric fate, and the impacts of local emissions and long-range transport on aerosol composition. Additionally, we traced potential sources of non-exhaust heavy-metal particles. This comprehensive analysis provides valuable insights into the complex dynamics of urban aerosols.
Eric Schneider, Hendryk Czech, Olga Popovicheva, Marina Chichaeva, Vasily Kobelev, Nikolay Kasimov, Tatiana Minkina, Christopher Paul Rüger, and Ralf Zimmermann
Atmos. Chem. Phys., 24, 553–576, https://doi.org/10.5194/acp-24-553-2024, https://doi.org/10.5194/acp-24-553-2024, 2024
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This study provides insights into the complex chemical composition of long-range-transported wildfire plumes from Yakutia, which underwent different levels of atmospheric processing. With complementary mass spectrometric techniques, we improve our understanding of the chemical processes and atmospheric fate of wildfire plumes. Unprecedented high levels of carbonaceous aerosols crossed the polar circle with implications for the Arctic ecosystem and consequently climate.
Qiongqiong Wang, Shuhui Zhu, Shan Wang, Cheng Huang, Yusen Duan, and Jian Zhen Yu
Atmos. Chem. Phys., 24, 475–486, https://doi.org/10.5194/acp-24-475-2024, https://doi.org/10.5194/acp-24-475-2024, 2024
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We investigated short-term source apportionment of PM2.5 utilizing rolling positive matrix factorization (PMF) and online PM chemical speciation data, which included source-specific organic tracers collected over a period of 37 d during the winter of 2019–2020 in suburban Shanghai, China. The findings highlight that by imposing constraints on the primary source profiles, short-term PMF analysis successfully replicated both the individual primary sources and the total secondary sources.
Jiyuan Yang, Guoyang Lei, Jinfeng Zhu, Yutong Wu, Chang Liu, Kai Hu, Junsong Bao, Zitong Zhang, Weili Lin, and Jun Jin
Atmos. Chem. Phys., 24, 123–136, https://doi.org/10.5194/acp-24-123-2024, https://doi.org/10.5194/acp-24-123-2024, 2024
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The atmospheric pollution and formation mechanisms of particulate-bound alkyl nitrate in Beijing were studied. C9–C16 long-chain n-alkyl nitrates negatively correlated with O3 but positively correlated with PM2.5 and NO2, so they may not be produced during gas-phase homogeneous reactions in the photochemical process but form through reactions between alkanes and nitrates on PM surfaces. Particulate-bound n-alkyl nitrates strongly affect both haze pollution and atmospheric visibility.
Lisa Azzarello, Rebecca A. Washenfelder, Michael A. Robinson, Alessandro Franchin, Caroline C. Womack, Christopher D. Holmes, Steven S. Brown, Ann Middlebrook, Tim Newberger, Colm Sweeney, and Cora J. Young
Atmos. Chem. Phys., 23, 15643–15654, https://doi.org/10.5194/acp-23-15643-2023, https://doi.org/10.5194/acp-23-15643-2023, 2023
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We present a molecular size-resolved offline analysis of water-soluble brown carbon collected on an aircraft during FIREX-AQ. The smoke plumes were aged 0 to 5 h, where absorption was dominated by small molecular weight molecules, brown carbon absorption downwind did not consistently decrease, and the measurements differed from online absorption measurements of the same samples. We show how differences between online and offline absorption could be related to different measurement conditions.
Sebastian Zeppenfeld, Manuela van Pinxteren, Markus Hartmann, Moritz Zeising, Astrid Bracher, and Hartmut Herrmann
Atmos. Chem. Phys., 23, 15561–15587, https://doi.org/10.5194/acp-23-15561-2023, https://doi.org/10.5194/acp-23-15561-2023, 2023
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Marine carbohydrates are produced in the surface of the ocean, enter the atmophere as part of sea spray aerosol particles, and potentially contribute to the formation of fog and clouds. Here, we present the results of a sea–air transfer study of marine carbohydrates conducted in the high Arctic. Besides a chemo-selective transfer, we observed a quick atmospheric aging of carbohydrates, possibly as a result of both biotic and abiotic processes.
Xing Wei, Yanjie Shen, Xiao-Ying Yu, Yang Gao, Huiwang Gao, Ming Chu, Yujiao Zhu, and Xiaohong Yao
Atmos. Chem. Phys., 23, 15325–15350, https://doi.org/10.5194/acp-23-15325-2023, https://doi.org/10.5194/acp-23-15325-2023, 2023
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We investigate the contribution of grown new particles to Nccn at a rural mountain site in the North China Plain. The total particle number concentrations (Ncn) observed on 8 new particle formation (NPF) days were higher compared to non-NPF days. The Nccn at 0.2 % supersaturation (SS) and 0.4 % SS on the NPF days was significantly lower than on non-NPF days. Only one of eight NPF events had detectable net contributions to Nccn at 0.4 % SS and 1.0 % SS with increased κ values.
Yuquan Gong, Ru-Jin Huang, Lu Yang, Ting Wang, Wei Yuan, Wei Xu, Wenjuan Cao, Yang Wang, and Yongjie Li
Atmos. Chem. Phys., 23, 15197–15207, https://doi.org/10.5194/acp-23-15197-2023, https://doi.org/10.5194/acp-23-15197-2023, 2023
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This study reveals the large day–night differences in brown carbon (BrC) chromophore composition, which was not known previously. The results provide insights into the effects of atmospheric processes and emissions on BrC composition.
Ryan N. Farley, Sonya Collier, Christopher D. Cappa, Leah R. Williams, Timothy B. Onasch, Lynn M. Russell, Hwajin Kim, and Qi Zhang
Atmos. Chem. Phys., 23, 15039–15056, https://doi.org/10.5194/acp-23-15039-2023, https://doi.org/10.5194/acp-23-15039-2023, 2023
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Soot particles, also known as black carbon (BC), have important implications for global climate and regional air quality. After the particles are emitted, BC can be coated with other material, impacting the aerosol properties. We selectively measured the composition of particles containing BC to explore their sources and chemical transformations in the atmosphere. We focus on a persistent, multiday fog event in order to study the effects of chemical reactions occurring within liquid droplets.
Wenshuai Li, Yuxuan Qi, Yingchen Liu, Guanru Wu, Yanjing Zhang, Jinhui Shi, Wenjun Qu, Lifang Sheng, Wencai Wang, Daizhou Zhang, and Yang Zhou
EGUsphere, https://doi.org/10.5194/egusphere-2023-2698, https://doi.org/10.5194/egusphere-2023-2698, 2023
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Aerosol particles from mainland can transport to oceans and deposit, providing soluble Fe and affecting phytoplankton growth. Thus, we studied the dissolution process of aerosol Fe and found that photochemistry played a key role in promoting Fe dissolution in clean conditions. RH-dependent reactions were more influential in slightly-polluted conditions. These results highlight the distinct roles of two weather-related parameters (radiation and RH) in influencing geochemical cycles related to Fe.
Xiaoxiao Li, Yijing Chen, Yuyang Li, Runlong Cai, Yiran Li, Chenjuan Deng, Jin Wu, Chao Yan, Hairong Cheng, Yongchun Liu, Markku Kulmala, Jiming Hao, James N. Smith, and Jingkun Jiang
Atmos. Chem. Phys., 23, 14801–14812, https://doi.org/10.5194/acp-23-14801-2023, https://doi.org/10.5194/acp-23-14801-2023, 2023
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Near-continuous measurements show the composition, sources, and seasonal variations of ultrafine particles (UFPs) in urban Beijing. Vehicle and cooking emissions and new particle formation are the main sources of UFPs, and aqueous/heterogeneous processes increase UFP mode diameters. UFPs are the highest in winter due to the highest primary particle emission rates and new particle formation rates, and CHO fractions are the highest in summer due to the strongest photooxidation.
Jiaqi Wang, Jian Gao, Fei Che, Xin Yang, Yuanqin Yang, Lei Liu, Yan Xiang, and Haisheng Li
Atmos. Chem. Phys., 23, 14715–14733, https://doi.org/10.5194/acp-23-14715-2023, https://doi.org/10.5194/acp-23-14715-2023, 2023
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Regional-scale observations of surface O3, PM2.5 and its major chemical species, mixing layer height (MLH), and other meteorological parameters were made in the North China Plain during summer. Unlike the cold season, synchronized increases in MDA8 O3 and PM2.5 under medium MLH conditions have been witnessed. The increasing trend of PM2.5 was associated with enhanced secondary chemical formation. The correlation between MLH and secondary air pollutants should be treated with care in hot seasons.
Takuma Miyakawa, Akinori Ito, Chunmao Zhu, Atsushi Shimizu, Erika Matsumoto, Yusuke Mizuno, and Yugo Kanaya
Atmos. Chem. Phys., 23, 14609–14626, https://doi.org/10.5194/acp-23-14609-2023, https://doi.org/10.5194/acp-23-14609-2023, 2023
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This study conducted semi-continuous measurements of PM2.5 aerosols and their elemental composition in western Japan, during spring 2018. It analyzed the emissions, transport, and wet removal of elements such as Pb, Cu, Fe, and Mn. It also assessed the accuracy of modeled concentrations and found overestimations of BC and underestimations of Cu and anthropogenic Fe in East Asia. Insights into emissions, removals, and source apportionment of trace metals in the East Asian outflow were provided.
Jingjing Meng, Yachen Wang, Yuanyuan Li, Tonglin Huang, Zhifei Wang, Yiqiu Wang, Min Chen, Zhanfang Hou, Houhua Zhou, Keding Lu, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 23, 14481–14503, https://doi.org/10.5194/acp-23-14481-2023, https://doi.org/10.5194/acp-23-14481-2023, 2023
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This study investigated the effect of COVID-19 lockdown (LCD) measures on the formation and evolutionary process of diacids and related compounds from field observations. Results demonstrate that more aged organic aerosols are observed during the LCD due to the enhanced photochemical oxidation. Our study also found that the reactivity of 13C was higher than that of 12C in the gaseous photochemical oxidation, leading to higher δ13C values of C2 during the LCD than before the LCD.
Christopher J. Hennigan, Michael McKee, Vikram Pratap, Bryanna Boegner, Jasper Reno, Lucia Garcia, Madison McLaren, and Sara M. Lance
Atmos. Chem. Phys., 23, 14437–14449, https://doi.org/10.5194/acp-23-14437-2023, https://doi.org/10.5194/acp-23-14437-2023, 2023
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This study characterized the optical properties of light-absorbing organic compounds, called brown carbon (BrC), in atmospheric cloud water samples. In all samples, light absorption by BrC increased linearly with increasing pH. There was variability in the sensitivity of the absorption–pH relationship, depending on the degree of influence from fire emissions. Overall, these results show that the climate forcing of BrC is quite strongly affected by its pH-dependent absorption.
Máté Vörösmarty, Gaëlle Uzu, Jean-Luc Jaffrezo, Pamela Dominutti, Zsófia Kertész, Enikő Papp, and Imre Salma
Atmos. Chem. Phys., 23, 14255–14269, https://doi.org/10.5194/acp-23-14255-2023, https://doi.org/10.5194/acp-23-14255-2023, 2023
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Poor air quality caused by high concentrations of particulate matter is one of the most severe public health concerns for humans worldwide. One of the most important biological mechanisms inducing adverse health effects is the oxidant–antioxidant imbalance. We showed that the oxidative stress changed substantially and in a complex manner with location and season. Biomass burning exhibited the dominant influence, while motor vehicles played an important role in the non-heating period.
Da Lu, Hao Li, Mengke Tian, Guochen Wang, Xiaofei Qin, Na Zhao, Juntao Huo, Fan Yang, Yanfen Lin, Jia Chen, Qingyan Fu, Yusen Duan, Xinyi Dong, Congrui Deng, Sabur F. Abdullaev, and Kan Huang
Atmos. Chem. Phys., 23, 13853–13868, https://doi.org/10.5194/acp-23-13853-2023, https://doi.org/10.5194/acp-23-13853-2023, 2023
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Environmental conditions during dust are usually not favorable for secondary aerosol formation. However in this study, an unusual dust event was captured in a Chinese mega-city and showed “anomalous” meteorology and a special dust backflow transport pathway. The underlying formation mechanisms of secondary aerosols are probed in the context of this special dust event. This study shows significant implications for the varying dust aerosol chemistry in the future changing climate.
Thomas Audoux, Benoit Laurent, Karine Desboeufs, Gael Noyalet, Franck Maisonneuve, Olivier Lauret, and Servanne Chevaillier
Atmos. Chem. Phys., 23, 13485–13503, https://doi.org/10.5194/acp-23-13485-2023, https://doi.org/10.5194/acp-23-13485-2023, 2023
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In the Paris region, a campaign was conducted to study wet deposition of aerosol particles during rainfall events. Simultaneous measurements of aerosol and wet deposition allowed us to discuss their transfer from the atmosphere to rain. Chemical evolution within events revealed meteorology, atmospheric conditions and local vs. long range sources as key factors. This study highlights the variability of wet deposition and the need to consider event-specific factors to understand its mechanisms.
Ting Yang, Yu Xu, Qing Ye, Yi-Jia Ma, Yu-Chen Wang, Jian-Zhen Yu, Yu-Sen Duan, Chen-Xi Li, Hong-Wei Xiao, Zi-Yue Li, Yue Zhao, and Hua-Yun Xiao
Atmos. Chem. Phys., 23, 13433–13450, https://doi.org/10.5194/acp-23-13433-2023, https://doi.org/10.5194/acp-23-13433-2023, 2023
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In this study, 130 OS species were quantified in ambient fine particulate matter (PM2.5) collected in urban and suburban Shanghai (East China) in the summer of 2021. The daytime OS formation was concretized based on the interactions among OSs, ultraviolet (UV), ozone (O3), and sulfate. Our finding provides field evidence for the influence of photochemical process and anthropogenic sulfate on OS formation and has important implications for the mitigation of organic particulate pollution.
Shan Wang, Kezheng Liao, Zijing Zhang, Yuk Ying Cheng, Qiongqiong Wang, Hanzhe Chen, and Jian Zhen Yu
EGUsphere, https://doi.org/10.5194/egusphere-2023-2286, https://doi.org/10.5194/egusphere-2023-2286, 2023
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In this work, hourly primary and secondary organic carbon were estimated by a novel Bayesian inference approach in suburban Hong Kong. Their multi-temporal scale variations and evolution characteristics during PM2.5 episodes were examined. The methodology could serve as a guide for other locations with similar monitoring capabilities. The observation-based results are helpful for understanding the evolving nature of secondary organic aerosols and refining the accuracy of model simulations.
Marco Paglione, David C. S. Beddows, Anna Jones, Thomas Lachlan-Cope, Matteo Rinaldi, Stefano Decesari, Francesco Manarini, Mara Russo, Karam Mansour, Roy M. Harrison, Andrea Mazzanti, Emilio Tagliavini, and Manuel Dall'Osto
EGUsphere, https://doi.org/10.5194/egusphere-2023-2275, https://doi.org/10.5194/egusphere-2023-2275, 2023
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Applying factor analysis techniques to H-NMR spectra, we present the Organic Aerosol (OA) source apportionment of PM1 samples collected in parallel at two peri-Antarctic stations, namely Signy and Halley, important to investigate aerosol-climate interactions in an unperturbed atmosphere. Our results show remarkable differences between pelagic (open ocean) and sympagic (sea-ice influenced) air masses and indicate that various sources and processes are controlling Antarctic aerosols.
Miao Zhong, Jianzhong Xu, Huiqin Wang, Li Gao, Haixia Zhu, Lixiang Zhai, Xinghua Zhang, and Wenhui Zhao
Atmos. Chem. Phys., 23, 12609–12630, https://doi.org/10.5194/acp-23-12609-2023, https://doi.org/10.5194/acp-23-12609-2023, 2023
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This study focus on coal-combustion-dominated aerosol in urban areas in northwestern China and combines the results of optical measurement and chemical analysis to deduce the evolution of these characteristics in the atmosphere, which has previously been unknown. The results provide insights into the effects of atmospheric processes and emissions on brown carbon properties.
Li Wu, Hyo-Jin Eom, Hanjin Yoo, Dhrubajyoti Gupta, Hye-Rin Cho, Pingqing Fu, and Chul-Un Ro
Atmos. Chem. Phys., 23, 12571–12588, https://doi.org/10.5194/acp-23-12571-2023, https://doi.org/10.5194/acp-23-12571-2023, 2023
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Hygroscopicity of ambient marine aerosols is of critical relevance to investigate their atmospheric impacts, which, however, remain uncertain due to their complex compositions and mixing states. Therefore, a study on the hygroscopic behavior of ambient marine aerosols for understanding the phase states when interacting with water vapor at different RH levels and their subsequent impacts on the heterogeneous chemical reactions, atmospheric environment, and human health is of vital importance.
Yutong Liang, Rebecca A. Wernis, Kasper Kristensen, Nathan M. Kreisberg, Philip L. Croteau, Scott C. Herndon, Arthur W. H. Chan, Nga L. Ng, and Allen H. Goldstein
Atmos. Chem. Phys., 23, 12441–12454, https://doi.org/10.5194/acp-23-12441-2023, https://doi.org/10.5194/acp-23-12441-2023, 2023
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We measured the gas–particle partitioning behaviors of biomass burning markers and examined the effect of wildfire organic aerosol on the partitioning of semivolatile organic compounds. Most compounds measured are less volatile than model predictions. Wildfire aerosol enhanced the condensation of polar compounds and caused some nonpolar (e.g., polycyclic aromatic hydrocarbons) compounds to partition into the gas phase, thus affecting their lifetimes in the atmosphere and the mode of exposure.
Bojiang Su, Xinhui Bi, Zhou Zhang, Yue Liang, Congbo Song, Tao Wang, Yaohao Hu, Lei Li, Zhen Zhou, Jinpei Yan, Xinming Wang, and Guohua Zhang
Atmos. Chem. Phys., 23, 10697–10711, https://doi.org/10.5194/acp-23-10697-2023, https://doi.org/10.5194/acp-23-10697-2023, 2023
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During the R/V Xuelong cruise observation over the Ross Sea, Antarctica, the mass concentrations of water-soluble Ca2+ and the mass spectra of individual calcareous particles were measured. Our results indicated that lower temperature, lower wind speed, and the presence of sea ice may facilitate Ca2+ enrichment in sea spray aerosols and highlighted the potential contribution of organically complexed calcium to calcium enrichment, which is inaccurate based solely on water-soluble Ca2+ estimation.
Valeria Mardoñez, Marco Pandolfi, Lucille Joanna S. Borlaza, Jean-Luc Jaffrezo, Andrés Alastuey, Jean-Luc Besombes, Isabel Moreno R., Noemi Perez, Griša Močnik, Patrick Ginot, Radovan Krejci, Vladislav Chrastny, Alfred Wiedensohler, Paolo Laj, Marcos Andrade, and Gaëlle Uzu
Atmos. Chem. Phys., 23, 10325–10347, https://doi.org/10.5194/acp-23-10325-2023, https://doi.org/10.5194/acp-23-10325-2023, 2023
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La Paz and El Alto are two fast-growing, high-altitude Bolivian cities forming the second-largest metropolitan area in the country. The sources of particulate matter (PM) in this conurbation were not previously investigated. This study identified 11 main sources of PM, of which dust and vehicular emissions stand out as the main ones. The influence of regional biomass combustion and local waste combustion was also observed, with the latter being a major source of hazardous compounds.
Sayako Ueda, Yoko Iwamoto, Fumikazu Taketani, Mingxu Liu, and Hitoshi Matsui
Atmos. Chem. Phys., 23, 10117–10135, https://doi.org/10.5194/acp-23-10117-2023, https://doi.org/10.5194/acp-23-10117-2023, 2023
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We examine iron in atmospheric fine aerosol particles collected over the Indian Ocean during shipborne observations in November 2018. Transmission electron microscopy analysis with water dialysis shows that various types of iron (fly ash, iron oxide, and mineral dust) co-exist with ammonium sulfate and that their solubility differs depending on the iron type. Using PM2.5 bulk samples and global model simulations, we elucidate their origins, aging, and implications for present iron simulations.
Farhan R. Nursanto, Roy Meinen, Rupert Holzinger, Maarten C. Krol, Xinya Liu, Ulrike Dusek, Bas Henzing, and Juliane L. Fry
Atmos. Chem. Phys., 23, 10015–10034, https://doi.org/10.5194/acp-23-10015-2023, https://doi.org/10.5194/acp-23-10015-2023, 2023
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Particulate matter (PM) is a harmful air pollutant that depends on the complex mixture of natural and anthropogenic emissions into the atmosphere. Thus, in different regions and seasons, the way that PM is formed and grows can differ. In this study, we use a combined statistical analysis of the chemical composition and particle size distribution to determine what drives particle formation and growth across seasons, using varying wind directions to elucidate the role of different sources.
Kohei Sakata, Aya Sakaguchi, Yoshiaki Yamakawa, Chihiro Miyamoto, Minako Kurisu, and Yoshio Takahashi
Atmos. Chem. Phys., 23, 9815–9836, https://doi.org/10.5194/acp-23-9815-2023, https://doi.org/10.5194/acp-23-9815-2023, 2023
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Anthropogenic iron is the dominant source of dissolved Fe in aerosol particles, but its contribution to dissolved Fe in aerosol particles has not been quantitatively evaluated. We established the molar concentration ratio of dissolved Fe to dissolved Al as a new indicator to evaluate the contribution of anthropogenic iron. As a result, about 10 % of dissolved Fe in aerosol particles was derived from anthropogenic iron when aerosol particles were transported from East Asia to the Pacific Ocean.
Li Li, Qiyuan Wang, Jie Tian, Huikun Liu, Yong Zhang, Steven Sai Hang Ho, Weikang Ran, and Junji Cao
Atmos. Chem. Phys., 23, 9597–9612, https://doi.org/10.5194/acp-23-9597-2023, https://doi.org/10.5194/acp-23-9597-2023, 2023
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The Tibetan Plateau has a unique geographical location, but there is a lack of detailed research on the real-time characteristics of full aerosol composition. This study elaborates the changes in chemical characteristics between transport and local fine particles during the pre-monsoon, reveals the size distribution and the mixing states of different individual particles, and highlights the contributions of photooxidation and aqueous reaction to the formation of the secondary species.
Erin K. Boedicker, Elisabeth Andrews, Patrick J. Sheridan, and Patricia K. Quinn
Atmos. Chem. Phys., 23, 9525–9547, https://doi.org/10.5194/acp-23-9525-2023, https://doi.org/10.5194/acp-23-9525-2023, 2023
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We present 15 years of measurements from a marine site on the northern California coast and characterize the seasonal trends of aerosol ion composition and optical properties at the site. We investigate the relationship between the chemical and optical properties and show that they both support similar seasonal variations in aerosol sources at the site. Additionally, we show through comparisons to other marine aerosol observations that the site is representative of a clean marine environment.
Qian Li, Dantong Liu, Xiaotong Jiang, Ping Tian, Yangzhou Wu, Siyuan Li, Kang Hu, Quan Liu, Mengyu Huang, Ruijie Li, Kai Bi, Shaofei Kong, Deping Ding, and Chenjie Yu
Atmos. Chem. Phys., 23, 9439–9453, https://doi.org/10.5194/acp-23-9439-2023, https://doi.org/10.5194/acp-23-9439-2023, 2023
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By attributing the shortwave absorption from black carbon, primary organic aerosol and secondary organic aerosol in a suburban environment, we firstly observed that the photochemically produced nitrogen-containing secondary organic aerosol may contribute to the enhancement of brown carbon absorption, partly compensating for some bleaching effect on the absorption of primary organic aerosol, hereby exerting radiative impacts.
Cited articles
Andreae, M. O. and Crutzen, P. J.: Atmospheric Aerosols: Biogeochemical
Sources and Role in Atmospheric Chemistry, Science, 276, 1052–1058,
https://doi.org/10.1126/science.276.5315.1052, 1997.
Andreae, M. O., Ferek, R. J., Bermond, F., Byrd, K. P., Engstrom, R. T.,
Hardin, S., Houmere, P. D., LeMarrec, F., Raemdonck, H., and Chatfield, R.
B.: Dimethyl sulfide in the marine atmosphere, J. Geophys. Res., 90,
12891–12900, https://doi.org/10.1029/JD090iD07p12891, 1985.
Arrigo, K. R. and van Dijken, G. L.: Phytoplankton dynamics within 37
Antarctic coastal polynya systems, J. Geophys. Res., 108, 3271,
https://doi.org/10.1029/2002JC001739, 2003.
Arrigo, K. R., Worthen, D. L., and Robinson, D. H.: A coupled ocean-ecosystem
model of the Ross Sea: 2. Iron regulation of phytoplankton taxonomic
variability and primary production, J. Geophys. Res., 108, 3231,
https://doi.org/10.1029/2001JC000856, 2003.
Arrigo, K. R., Lowry, K. E., and van Dijken, G. L.: Annual changes in sea ice
and phytoplankton in polynyas of the Amundsen Sea, Antarctica, Deep-Sea Res. Pt. II, 71, 5–15, https://doi.org/10.1016/j.dsr2.2012.03.006, 2012.
Ayers, G. P., Ivey, J. P., and Gillett, R. W.: Coherence between seasonal
cycles of dimethyl sulphide, methanesulphonate and sulphate in marine air,
Nature, 349, 404–406, https://doi.org/10.1038/349404a0, 1991.
Bates, T. S., Calhoun, J. A., and Quinn, P. K.: Variations in the
methanesulfonate to sulfate molar ratio in submicrometer marine aerosol
particles over the South Pacific Ocean, J. Geophys. Res.-Atmos., 97,
9859–9865, https://doi.org/10.1029/92JD00411, 1992.
Benner, R., Pakulski, J. D., McCarthy, M., Hedges, J. I., and Hatcher, P. G.:
Bulk chemical characteristics of dissolved organic matter in the ocean,
Science, 255, 1561–1564, https://doi.org/10.1126/science.255.5051.1561, 1992.
Berresheim, H., Andreae, M. O., Ayers, G. P., Gillett, R. W., Merrill, J.
T., Davis, V. J. and Chameides, W. L.: Airborne measurements of
dimethylsulfide, sulfur dioxide, and aerosol ions over the Southern Ocean
South of Australia, J. Atmos. Chem., 10, 341–370,
https://doi.org/10.1007/BF00053868, 1990.
Biersmith, A. and Benner, R.: Carbohydrates in phytoplankton and freshly
produced dissolved organic matter, Mar. Chem., 63, 131–144,
https://doi.org/10.1016/S0304-4203(98)00057-7, 1998.
Birch, M. E. And Cary, R. A.: Elemental carbon-based method for monitoring
occupational exposures to particulate diesel exhaust, Aerosol. Sci.
Technol., 25, 221–241, 1996.
Boreddy, S. K. R., Haque, M. M., and Kawamura, K.: Long-term (2001–2012) trends of carbonaceous aerosols from a remote island in the western North Pacific: an outflow region of Asian pollutants, Atmos. Chem. Phys., 18, 1291–1306, https://doi.org/10.5194/acp-18-1291-2018, 2018.
Bromwich, D. H., Nicolas, J. P., Monaghan, A. J., Lazzara, M. A., Keller, L.
M., Weidner, G. A., and Wilson, A. B.: Central West Antarctica among the most
rapidly warming regions on Earth, Nat. Geosci., 6, 1–8,
https://doi.org/10.1038/ngeo1671, 2013.
Ceburnis, D., O'Dowd, C. D., Jennings, G. S., Facchini, M. C., Emblico, L.,
Decesari, S., Fuzzi, S., and Sakalys, J.: Marine aerosol chemistry gradients:
Elucidating primary and secondary processes and fluxes, Geophys. Res. Lett.,
35, L07804, https://doi.org/10.1029/2008GL033462, 2008.
Ceburnis, D., Rinaldi, M., Ovadnevaite, J., Martucci, G., Giulianelli, L., and O'Dowd, C. D.: Marine submicron aerosol gradients, sources and sinks, Atmos. Chem. Phys., 16, 12425–12439, https://doi.org/10.5194/acp-16-12425-2016, 2016.
Charlson, R. J., Lovelock, J. E., Andreae, M. O., and Warren, S. G.: Oceanic
phytoplankton, atmospheric sulfur, cloud albedo and climate, Nature,
326, 655–661, https://doi.org/10.1038/326655a0, 1987.
Chen, L., Wang, J., Gao, Y., Xu, G., Yang, X., Lin, Q., and Zhang, Y.:
Latitudinal distributions of atmospheric MSA and MSA ∕ nss-
ratios in summer over the high latitude regions of the Southern and Northern
Hemispheres, J. Geophys. Res., 117, D10306, https://doi.org/10.1029/2011JD016559,
2012.
Chen, M., Price, R. M., Yamashita, Y., and Jaffé, R.: Comparative study
of dissolved organic matter from groundwater and surface water in the
Florida coastal Everglades using multi-dimensional spectrofluorometry
combined with multivariate statistics, Appl. Geochem., 25, 872–880,
https://doi.org/10.1016/j.apgeochem.2010.03.005, 2010.
Chen, M., Jung, J., Lee, Y. K., and Hur, J.: Surface accumulation of low
molecular weight dissolved organic matter in surface waters and horizontal
off-shelf spreading of nutrients and humic-like fluorescence in the Chukchi
Sea of the Arctic Ocean, Sci. Total Environ., 639, 624–632,
https://doi.org/10.1016/j.scitotenv.2018.05.205, 2018.
Chen, M., Kim, J.-H., Choi, J., Lee, Y. K., and Hur, J.: Biological early
diagenesis and insolation-paced paleoproductivity signified in deep core
sediment organic matter, Sci. Rep., 7, 1–11, https://doi.org/10.1038/s41598-017-01759-4,
2017.
Coble, P. G.: Characterization of marine and terrestrial DOM in seawater
using excitation-emission matrix spectroscopy, Mar. Chem., 51, 325–346,
https://doi.org/10.1016/0304-4203(95)00062-3, 1996.
Coble, P. G.: Marine optical biogeochemistry: The chemistry of ocean color,
Chem. Rev., 107, 402–418, https://doi.org/10.1021/cr050350+, 2007.
Coble, P. G., Del Castillo, C. E., and Avril, B.: Distribution and optical
properties of CDOM in the Arabian Sea during the 1995 Southwest Monsoon,
Deep-Sea Res. Pt. II, 45, 2195–2223,
https://doi.org/10.1016/S0967-0645(98)00068-X, 1998.
Covert, D. S., Kapustin, V. N., Quinn, P. K., and Bates, T. S.: New particle
formation in the marine boundary layer, J. Geophys. Res., 97,
20581–20589, 1992.
Criscitiello, A. S., Das, S. B., Evans, M. J., Frey, K. E., Conway, H.,
Joughin, I., Medley, B., and Steig, E. J.: Ice sheet record of recent sea-ice
behavior and polynya variability in the Amundsen Sea, West Antarctica, J.
Geophys. Res.-Oceans, 118, 118–130, https://doi.org/10.1029/2012JC008077, 2013.
Dall'Osto, M., Ovadnevaite, J., Paglione, M., Beddows, D. C. S., Ceburnis,
D., Cree, C., Cortes, P., Zamanillo, M., Nunes, S. O., Perez, G. L.,
Ortega-Retuerta, E., Emelianov, M., Vaque, D., Marrase, C., Estrada, M.,
Sala, M. M., Vidal, M., Fitzsimons, M. F., Beale, R., Airs, R., Rinaldi, M.,
Decesari, S., Facchini, M. C., Harrison, R. M., O'Dowd, C. and Simo, R.:
Antarctic sea ice region as a source of biogenic organic nitrogen in
aerosols, Sci. Rep., 7, 1–10, https://doi.org/10.1038/s41598-017-06188-x, 2017.
de Leeuw, G., Andreas, E. L., Anguelova, M. D., Fairall, C. W., Lewis, E.
R., O'Dowd, C., Schulz, M., and Schwartz, S. E.: Production flux of sea spray
aerosol, Rev. Geophys., 49, RG2001, https://doi.org/10.1029/2010RG000349, 2011.
Dutrieux, P., De Rydt, J., Jenkins, A., Holland, P. R., Ha, H. K., Lee, S.
H., Steig, E. J., Ding, Q., Abrahamsen, E. P., and Schröder, M.: Strong
sensitivity of Pine Island ice-shelf melting to climatic variability,
Science, 343, 174–178, https://doi.org/10.1126/science.1244341, 2014.
Fu, P., Kawamura, K., Chen, J., Qin, M., Ren, L., Sun, Y., Wang, Z., Barrie,
L. A., Tachibana, E., Ding, A., and Yamashita, Y.: Fluorescent water-soluble
organic aerosols in the High Arctic atmosphere, Sci. Rep., 5, 1053–1058,
https://doi.org/10.1038/srep09845, 2015.
Furutani, H., Dall'osto, M., Roberts, G. C., and Prather, K.: Assessment of
the relative importance of atmospheric aging on CCN activity derived from
field observations, Atmos. Environ., 42, 3130–3142,
https://doi.org/10.1016/j.atmosenv.2007.09.024, 2008.
Facchini, M. C., Mircea, M., Fuzzi, S., and Charlson, R.: Cloud albedo
enhancement by surface-active organic solutes in growing droplets, Nature,
401, 257–259, 1999.
Facchini, M. C., Rinaldi, M., Decesari, S., Carbone, C., Finessi, E.,
Mircea, M., Fuzzi, S., Ceburnis, D., Flanagan, R., Nilsson, E. D., de Leeuw,
G., Martino, M., Woeltjen, J., and O'Dowd, C. D.: Primary submicron marine
aerosol dominated by insoluble organic colloids and aggregates, Geophys.
Res. Lett., 35, 396, https://doi.org/10.1029/2008GL034210, 2008a.
Facchini, M. C., Decesari, S., Rinaldi, M., Carbone, C., Finessi, E.,
Mircea, M., Fuzzi, S., Moretti, F., Tagliavini, E., Ceburnis, D., and O'Dowd,
C. D.: Important source of marine secondary organic aerosol from biogenic
amines, Environ. Sci. Technol., 42, 9116–9121, https://doi.org/10.1021/es8018385,
2008b.
Gantt, B. and Meskhidze, N.: The physical and chemical characteristics of marine primary organic aerosol: a review, Atmos. Chem. Phys., 13, 3979–3996, https://doi.org/10.5194/acp-13-3979-2013, 2013.
Gantt, B., Meskhidze, N., Facchini, M. C., Rinaldi, M., Ceburnis, D., and O'Dowd, C. D.: Wind speed dependent size-resolved parameterization for the organic mass fraction of sea spray aerosol, Atmos. Chem. Phys., 11, 8777–8790, https://doi.org/10.5194/acp-11-8777-2011, 2011.
Giordano, M. R., Kalnajs, L. E., Avery, A., Goetz, J. D., Davis, S. M., and DeCarlo, P. F.: A missing source of aerosols in Antarctica – beyond long-range transport, phytoplankton, and photochemistry, Atmos. Chem. Phys., 17, 1–20, https://doi.org/10.5194/acp-17-1-2017, 2017.
Gondwe, M., Krol, M., Klaassen, W., Gieskes, W., and de Baar, H.: Comparison
of modeled versus measured MSA:nss SO ratios: A global analysis,
Global Biogeochem. Cy., 18, GB2006, https://doi.org/10.1029/2003GB002144, 2004.
Gras, J. L. and Keywood, M.: Cloud condensation nuclei over the Southern Ocean: wind dependence and seasonal cycles, Atmos. Chem. Phys., 17, 4419–4432, https://doi.org/10.5194/acp-17-4419-2017, 2017.
Hahm, D., Rhee, T. S., Kim, H.-C., Park, J., Kim, Y. N., Shin, H. C., and
Lee, S.: Spatial and temporal variation of net community production and its
regulating factors in the Amundsen Sea, Antarctica, J. Geophys. Res.-Oceans,
119, 2815–2826, https://doi.org/10.1002/2013JC009762, 2014.
Hegg, D. A., Ferek, R. J., Hobbs, P. V., and Radke, L. F.: Dimethyl sulfide
and cloud condensation nucleus correlations in the Northeast Pacific Ocean,
J. Geophys. Res.-Atmos., 96, 13189–13191, https://doi.org/10.1029/91JD01309, 1991.
Hong, S.-B., Lee, K., Hur, S.-D., Hong, S., Soyol-Erdene, T.-O., Kim, S.-M., Chung, J.-W., Jun, S.-J., and Kang, C.-H.: Development of Melting
System for Measurement of Trace Elements and Ions in Ice Core, Bull. Korean
Chem. Soc., 36, 1069–1081, https://doi.org/10.1002/bkcs.10198, 2015.
Huguet, A., Vacher, L., Relexans, S., Saubusse, S., Froidefond, J. M., and
Parlanti, E.: Properties of fluorescent dissolved organic matter in the
Gironde Estuary, Org. Geochem., 40, 706–719,
https://doi.org/10.1016/j.orggeochem.2009.03.002, 2009.
Jung, J., Furutani, H., Uematsu, M., Kim, S., and Yoon, S.: Atmospheric inorganic nitrogen input via dry, wet, and sea fog deposition to the subarctic western North Pacific Ocean, Atmos. Chem. Phys., 13, 411–428, https://doi.org/10.5194/acp-13-411-2013, 2013.
Jung, J., Furutani, H., Uematsu, M., and Park, J.: Distributions of
atmospheric non-sea-salt sulfate and methanesulfonic acid over the Pacific
Ocean between 48∘ N and 55∘ S during summer, Atmos.
Environ., 99, 374–384, https://doi.org/10.1016/j.atmosenv.2014.10.009, 2014.
Kanakidou, M., Seinfeld, J. H., Pandis, S. N., Barnes, I., Dentener, F. J.,
Facchini, M. C., Van Dingenen, R., Ervens, B., Nenes, A., Nielsen, C. J.,
Swietlicki, E., Putaud, J. P., Balkanski, Y., Fuzzi, S., Horth, J.,
Moortgat, G. K., Winterhalter, R., Myhre, C., Tsigaridis, K., Vignati, E.,
Stephanou, E. G., and Wilson, J.: Organic aerosol and global climate
modelling: a review, J. Atmos. Chem., 5, 1053–1123, 2005.
Kawamura, K., Kasukabe, H., and Barrie, L. A.: Secondary formation of
water-soluble organic acids and α-dicarbonyls and their
contributions to total carbon and water-soluble organic carbon:
Photochemical aging of organic aerosols in the Arctic spring, J. Geophys.
Res., 115, D21306, https://doi.org/10.1029/2010JD014299, 2010.
Kawamura, K., Seméré, R., Imai, Y., Fujii, Y., and Hayashi, M.: Water
soluble dicarboxylic acids and related compounds in Antarctic aerosols, J.
Geophys. Res., 101, 18721–18728, https://doi.org/10.1029/96JD01541, 1996.
Kim, I., Hahm, D., Park, K., Lee, Y., Choi, J.-O., Zhang, M., Chen, L.,
Kim, H.-C., and Lee, S.: Characteristics of the horizontal and vertical
distributions of dimethyl sulfide throughout the Amundsen Sea Polynya, Sci.
Total Environ., 584, 154–163, https://doi.org/10.1016/j.scitotenv.2017.01.165,
2017.
Kloster, S., Feichter, J., Maier-Reimer, E., Six, K. D., Stier, P., and Wetzel, P.: DMS cycle in the marine ocean-atmosphere system – a global model study, Biogeosciences, 3, 29–51, https://doi.org/10.5194/bg-3-29-2006, 2006.
Korhonen, H., Carslaw, K. S., Spracklen, D. V., Mann, G. W., and Woodhouse,
M. T.: Influence of oceanic dimethyl sulfide emissions on cloud condensation
nuclei concentrations and seasonality over the remote Southern Hemisphere
oceans: A global model study, J. Geophys. Res., 113, D15204,
https://doi.org/10.1029/2007JD009718, 2008.
Lawaetz, A. J. and Stedmon, C. A.: Fluorescence Intensity Calibration Using
the Raman Scatter Peak of Water, Appl. Spectrosc., 63, 936–940,
https://doi.org/10.1366/000370209788964548, 2009.
Lee, Y., Yang, E. J., Park, J., Jung, J., Kim, T. W., and Lee, S.:
Physical-biological coupling in the Amundsen Sea, Antarctica: Influence of
physical factors on phytoplankton community structure and biomass, Deep-Sea
Res. Pt. I, 117, 51–60, https://doi.org/10.1016/j.dsr.2016.10.001, 2016.
Legrand, M. and Pasteur, E. C.: Methane sulfonic acid to non-sea-salt
sulfate ratio in coastal Antarctic aerosol and surface snow, J. Geophys.
Res., 103, 10991–11006, 1998.
Liss, P. S., Malin, G., Turner, S. M., and Holligan, P. M.: Dimethyl sulphide
and Phaeocystics: A review, J. Mar. Syst., 5, 41–53, 1994.
McKnight, D. M., Boyer, E. W., Westerhoff, P. K., Doran, P. T., Kulbe, T.
and Andersen, D. T.: Spectrofluorometric characterization of dissolved
organic matter for indication of precursor organic material and aromaticity,
Limnol. Oceanogr., 46, 38–48, https://doi.org/10.4319/lo.2001.46.1.0038, 2001.
McGillis, W. R., Dacey, J., Frew, N. M., Bock, E. J., and Nelson, R. K.:
Water-air flux of dimethylsulfide, J. Geophys. Res.-Oceans, 105,
1187–1193, https://doi.org/10.1029/1999JC900243, 2000.
Meskhidze, N. and Nenes, A.: Effects of ocean ecosystem on marine
aerosol-cloud interaction, Adv. Meteorol., 4923, 1–13,
https://doi.org/10.1155/2010/239808, 2010.
Millero, F. J. and Sohn, M. L.: Chemical Oceanography, CRC Press, Boca
Raton, FL, 521 pp., 1992.
Minikin, A., Legrand, M., Hall, J., Wagenbach, D., Kleefeld, C., Wolff, E.,
Pasteur, E. C., and Ducroz, F.: Sulfur-containing species (sulfate and
methanesulfonate) in coastal Antarctic aerosol and precipitation, J.
Geophys. Res., 103, 10975–10990, https://doi.org/10.1029/98JD00249, 1998.
Miyazaki, Y., Kawamura, K., Jung, J., Furutani, H., and Uematsu, M.: Latitudinal distributions of organic nitrogen and organic carbon in marine aerosols over the western North Pacific, Atmos. Chem. Phys., 11, 3037–3049, https://doi.org/10.5194/acp-11-3037-2011, 2011.
Miyazaki, Y., Coburn, S., Ono, K., Ho, D. T., Pierce, R. B., Kawamura, K., and Volkamer, R.: Contribution of dissolved organic matter to submicron water-soluble organic aerosols in the marine boundary layer over the eastern equatorial Pacific, Atmos. Chem. Phys., 16, 7695–7707, https://doi.org/10.5194/acp-16-7695-2016, 2016.
Miyazaki, Y., Yamashita, Y., Kawana, K., Tachibana, E., Kagami, S., Mochida,
M., Suzuki, K., and Nishioka, J.: Chemical transfer of dissolved organic
matter from surface seawater to sea spray water-soluble organic aerosol in
the marine atmosphere, Sci. Rep., 8, 2593,
https://doi.org/10.1038/s41598-018-32864-7, 2018.
Mochida, M., Kitamori, Y., Kawamura, K., Nojiri, Y., and Suzuki, K.: Fatty
acids in the marine atmosphere: Factors governing their concentrations and
evaluation of organic films on sea-salt particles, J. Geophys. Res.-Atmos.,
107, 1–10, https://doi.org/10.1029/2001JD001278, 2002.
Mochida, M., Nishita-Hara, C., Furutani, H., Miyazaki, Y., Jung, J.,
Kawamura, K., and Uematsu, M.: Hygroscopicity and cloud condensation nucleus
activity of marine aerosol particles over the western North Pacific, J.
Geophys. Res., 116, 6920–16, https://doi.org/10.1029/2010JD014759, 2011.
Monahan, E. C. and O'Muircheartaigh, I. G.: Whitecaps and the Passive
Remote-Sensing of the Ocean Surface, Int. J. Remote Sens., 7, 627–642,
https://doi.org/10.1080/01431168608954716, 1986.
Nightingale, P. D., Malin, G., Law, C. S., Watson, A. J., Liss, P. S.,
Liddicoat, M. I., Boutin, J., and Upstill-Goddard, R. C.: In situ evaluation
of air-sea gas exchange parameterizations using novel conservative and
volatile tracers, Global Biogeochem. Cy., 14, 373–387,
https://doi.org/10.1029/1999GB900091, 2000.
Niu, Z., Zhang, F., Kong, X., Chen, J., Yin, L., and Xu, L.: One-year
measurement of organic and elemental carbon in size-segregated atmospheric
aerosol at a coastal and suburban site in Southeast China, J. Environ.
Monit., 14, 2961–2967, https://doi.org/10.1039/c2em30337j, 2012.
Niu, Z., Zhang, F., Chen, J., Yin, L., Wang, S., and Xu, L.: Carbonaceous
species in PM2.5 in the coastal urban agglomeration in the Western Taiwan
Strait Region, China, Atmos. Res., 122, 102–110,
https://doi.org/10.1016/j.atmosres.2012.11.002, 2013.
O'Dowd, C. D., Lowe, J. A., Smith, M. H., Davison, B., Hewitt, N., and
Harrison, R. M.: Biogenic sulphur emissions and inferred
non-sea-salt-sulphate cloud condensation nuclei in and around Antarctica, J.
Geophys. Res.-Atmos., 102, 12839–12854, 1997.
O'Dowd, C. D., Facchini, M. C., Cavalli, F., Ceburnis, D., Mircea, M.,
Decesari, S., Fuzzi, S., Yoon, Y.-J., and Putaud, J.-P.: Biogenically driven
organic contribution to marine aerosol, Nature, 431, 676–680,
https://doi.org/10.1038/nature02959, 2004.
O'Dowd, C. D., Langmann, B., Varghese, S., Scannell, C., Ceburnis, D., and
Facchini, M. C.: A combined organic-inorganic sea-spray source function,
Geophys. Res. Lett., 35, L01801, https://doi.org/10.1029/2007GL030331, 2008.
Park, J., Kuzminov, F. I., Bailleul, B., Yang, E. J., Lee, S., Falkowski, P.
G., and Gorbunov, M. Y.: Light availability rather than Fe controls the
magnitude of massive phytoplankton bloom in the Amundsen Sea polynyas,
Antarctica, Limnol. Oceanogr., 62, 2260–2276, https://doi.org/10.1002/lno.10565,
2017.
Quinn, P. K. and Bates, T. S.: The case against climate regulation via
oceanic phytoplankton sulphur emissions, Nature, 480, 51–56,
https://doi.org/10.1038/nature10580, 2011.
Quinn, P. K., Bates, T. S., Schulz, K. S., Coffman, D. J., Frossard, A. A.,
Russell, L. M., Keene, W. C., and Kieber, D. J.: Contribution of sea surface
carbon pool to organic matter enrichment in sea spray aerosol, Nat.
Geosci., 7, 228–232, https://doi.org/10.1038/NGEO2092, 2014.
Read, K. A., Lewis, A. C., Bauguitte, S., Rankin, A. M., Salmon, R. A., Wolff, E. W., Saiz-Lopez, A., Bloss, W. J., Heard, D. E., Lee, J. D., and Plane, J. M. C.: DMS and MSA measurements in the Antarctic Boundary Layer: impact of BrO on MSA production, Atmos. Chem. Phys., 8, 2985–2997, https://doi.org/10.5194/acp-8-2985-2008, 2008.
Retelletti Brogi, S., Ha, S.-Y., Kim, K., Derrien, M., Lee, Y. K., and Hur,
J.: Optical and molecular characterization of dissolved organic matter (DOM)
in the Arctic ice core and the underlying seawater (Cambridge Bay, Canada):
Implication for increased autochthonous DOM during ice melting, Sci. Total
Environ., 627, 802–811, https://doi.org/10.1016/j.scitotenv.2018.01.251, 2018.
Rignot, E., Bamber, J. L., van den Broeke, M. R., Davis, C., Li, Y., van de
Berg, W. J., and van Meijgaard, E.: Recent Antarctic ice mass loss from
radar interferometry and regional climate modelling, Nat. Geosci., 1,
106–110, https://doi.org/10.1038/ngeo102, 2008.
Roberts, D., Craven, M., Cai, M., Allison, I., and Nash, G.: Protists in the
marine ice of the Amery Ice Shelf, East Antarctica, Polar Biol., 30,
143–153, 2007.
Romakkaniemi, S., Kokkola, H., Smith, J. N., Prisle, N. L., Schwier, A. N.,
McNeill, V. F., and Laaksonen, A.: Partitioning of semivolatile
surface-active compounds between bulk, surface and gas phase, Geophys. Res.
Lett., 38, L03807, https://doi.org/10.1029/2010GL046147, 2011.
Russell, L. M., Hawkins, L. N., Frossard, A. A., Quinn, P. K., and Bates, T.
S.: Carbohydrate-like composition of submicron atmospheric particles and
their production from ocean bubble bursting, P. Natl. Acad. Sci. USA,
107, 6652–6657, https://doi.org/10.1073/pnas.0908905107, 2010.
Sanchez, K. J., Chen, C.-L., Russell, L. M., Betha, R., Liu, J., Price, D.
J., Massoli, P., Ziemba, L. D., Crosbie, E. C., Moore, R. H., Mueller, M.,
Schiller, S. A., Wisthaler, A., Lee, A. K. Y., Quinn, P. K., Bates, T. S.,
Porter, J., Bell, T. G., Saltzman, E. S., Vaillancourt, R. D., and
Behrenfeld, M. J.: Substantial seasonal contribution of observed biogenic
sulfate particles to cloud condensation nuclei, Sci. Rep., 8,
https://doi.org/10.1038/s41598-018-21590-9, 2018.
Savoie, D. L., Prospero, J. M., Larsen, R. J., Huang, F., Izaguirre, M. A.,
Huang, R., Snowdon, T. H., Custals, L., and Sanderson C. G.: Nitrogen and
sulfur species in Antarctic aerosols at Mawson, Palmer Station, and Marsh
(King George Island), J. Atmos. Chem., 17, 95–122, 1993.
Savoie, D. L., Prospero, J. M., Arimoto, R., and Duce, R. A.: Non-sea-salt
sulfate and methanesulfonate at American Samoa, J. Geophys. Res., 99,
3587–3596, https://doi.org/10.1029/93JD03337, 1994.
Sciare, J., Favez, O., Sarda-Estève, R., Oikonomou, K., Cachier, H., and
Kazan, V.: Long-term observations of carbonaceous aerosols in the Austral
Ocean atmosphere: Evidence of a biogenic marine organic source, J. Geophys.
Res., 114, 1253, https://doi.org/10.1029/2009JD011998, 2009.
Schoemann, V., Becquevort, S., Stefels, J., Rousseau, V., and Lancelot, C.:
Phaeocystis blooms in the global ocean and their controlling mechanisms: a review, J.
Sea Res., 53, 43–66, https://doi.org/10.1016/j.seares.2004.01.008, 2005.
Sherrell, R. M., Lagerström, M. E., Forsch, K. O., Stammerjohn, S. E.,
and Yager, P. L.: Dynamics of dissolved iron and other bioactive trace
metals (Mn, Ni, Cu, Zn) in the Amundsen Sea Polynya, Antarctica, Elem. Sci.
Anth., 3, 71–27, https://doi.org/10.12952/journal.elementa.000071, 2015.
Smith, M. J., Walker, C. F., Bell, T. G., Harvey, M. J., Saltzman, E. S., and Law, C. S.: Gradient flux measurements of sea-air DMS transfer during the Surface Ocean Aerosol Production (SOAP) experiment, Atmos. Chem. Phys., 18, 5861–5877, https://doi.org/10.5194/acp-18-5861-2018, 2018.
Spreen, G., Kaleschke, L., and Heygster, G.: Sea ice remote sensing using
AMSR-E 89-GHz channels, J. Geophys. Res., 113, C02S03,
https://doi.org/10.1029/2005JC003384, 2008.
Stammerjohn, S., Massom, R., Rind, D., and Martinson, D.: Regions of rapid
sea ice change: An inter-hemispheric seasonal comparison, Geophys. Res.
Lett., 39, L06501, https://doi.org/10.1029/2012GL050874, 2012.
Stedmon, C. A., Markager, S., and Bro, R.: Tracing dissolved organic matter
in aquatic environments using a new approach to fluorescence spectroscopy,
Mar. Chem., 82, 239–254, https://doi.org/10.1016/S0304-4203(03)00072-0, 2003.
Stedmon, C. A., Thomas, D. N., Granskog, M., Kaartokallio, H.,
Papadimitriou, S., and Kuosa, H.: Characteristics of dissolved organic matter
in Baltic coastal sea ice: Allochthonous or autochthonous origins?, Environ.
Sci. Technol., 41, 7273–7279, https://doi.org/10.1021/es071210f, 2007.
Stedmon, C. A., Thomas, D. N., Papadimitriou, S., Granskog, M. A., and
Dieckmann, G. S.: Using fluorescence to characterize dissolved organic
matter in Antarctic sea ice brines, J. Geophys. Res., 116, G03027,
https://doi.org/10.1029/2011JG001716, 2011.
Sun, J. M. and Ariya, P. A.: Atmospheric organic and bio-aerosols as cloud
condensation nuclei (CCN): A review, Atmos. Environ., 40, 795–820,
https://doi.org/10.1016/j.atmosenv.2005.05.052, 2006.
Tortell, P. D., Long, M. C., Payne, C. D., Alderkamp, A.-C., Dutrieux, P.,
and Arrigo, K. R.: Spatial distribution of pCO2, ΔO2/Ar
and dimethylsulfide (DMS) in polynya waters and the sea ice zone of the
Amundsen Sea, Antarctica, Deep-Sea Res. Pt. II, 71, 77–93,
https://doi.org/10.1016/j.dsr2.2012.03.010, 2012.
Vallina, S. M., Simó, R., and Gassó, S.: What controls CCN
seasonality in the Southern Ocean?, A statistical analysis based on
satellite-derived chlorophyll and CCN and model-estimated OH radical and
rainfall, Global Biogeochem. Cy., 20, GB1014, https://doi.org/10.1029/2005GB002597,
2006.
Wanninkhof, R.: Relationship between wind-speed and gas-exchange over the
ocean, J. Geophys. Res., 97, 7373–7382, https://doi.org/10.1029/92JC00188, 1992.
Wanninkhof, R.: Relationship between wind speed and gas exchange over the
ocean revisited, Limnol. Oceanogr. Methods, 12, 351–362,
https://doi.org/10.4319/lom.2014.12.351, 2014.
Wanninkhof, R. and McGillis, W. R.: A cubic relationship between air-sea
CO2 exchange and wind speed, Geophys. Res. Lett., 26, 1889–1892,
https://doi.org/10.1029/1999GL900363, 1999.
Wilson, T. W., Ladino, L. A., Alpert, P. A., Breckels, M. N., Brooks, I. M.,
Browse, J., Burrows, S. M., Carslaw, K. S., Huffman, J. A., Judd, C.,
Kilthau, W. P., Mason, R. H., McFiggans, G., Miller, L. A., Nájera, J.
J., Polishchuk, E., Rae, S., Schiller, C. L., Si, M., Temprado, J. V.,
Whale, T. F., Wong, J. P. S., Wurl, O., Yakobi-Hancock, J. D., Abbatt, J. P.
D., Aller, J. Y., Bertram, A. K., Knopf, D. A., and Murray, B. J.: A marine
biogenic source of atmospheric ice-nucleating particles, Nature, 525,
234–238, https://doi.org/10.1038/nature14986, 2015.
Woodhouse, M. T., Carslaw, K. S., Mann, G. W., Vallina, S. M., Vogt, M., Halloran, P. R., and Boucher, O.: Low sensitivity of cloud condensation nuclei to changes in the sea-air flux of dimethyl-sulphide, Atmos. Chem. Phys., 10, 7545–7559, https://doi.org/10.5194/acp-10-7545-2010, 2010.
Wright, S. W., van den Enden, R. L., Pearce, I., Davidson, A. T., Scott, F.
J., and Westwood, K. J.: Phytoplankton community structure and stocks in the
Southern Ocean (30–80∘ E) determined by CHEMTAX analysis of
HPLC pigment signatures, Deep-Sea Res. Pt. II, 57, 758–778,
https://doi.org/10.1016/j.dsr2.2009.06.015, 2010.
Yager, P., Sherrell, R., Stammerjohn, S., Alderkamp, A.-C., Schofield, O.,
Abrahamsen, P., Arrigo, K., Bertilsson, S., Garay, L., Guerrero, R., Lowry,
K., Moksnes, P.-O., Ndungo, K., Post, A., Randall-Goodwin, E., Riemann, L.,
Severmann, S., Thatje, S., van Dijken, G., and Wilson, S.: ASPIRE: The
Amundsen Sea Polynya International Research Expedition, Oceanogr., 25,
40–53, https://doi.org/10.5670/oceanog.2012.73, 2012.
Yager, P. L., Sherrell, R. M., Stammerjohn, S. E., Ducklow, H. W.,
Schofield, O., Ingall, E. D., Wilson, S. E., Lowry, K. E., Williams, C. M.,
Riemann, L., Bertilsson, S., Alderkamp, A. C., Dinasquet, J., Logares, R.,
Richert, I., Sipler, R. E., Melara, A. J., Mu, L., Newstead, R. G., Post, A.
F., Swalethorp, R. and van Dijken, G. L.: A carbon budget for the Amundsen
Sea Polynya, Antarctica: Estimating net community production and export in a
highly productive polar ecosystem, Elem. Sci. Anth., 4, p. 140,
https://doi.org/10.12952/journal.elementa.000140, 2016..
Yamashita, Y., Panton, A., Mahaffey, C., and Jaffé, R.: Assessing the
spatial and temporal variability of dissolved organic matter in Liverpool
Bay using excitation – emission matrix fluorescence and parallel factor
analysis, Ocean Dynam., 61, 569–579, https://doi.org/10.1007/s10236-010-0365-4, 2011.
Yamashita, Y. and Tanoue, E.: Chemical characterization of protein-like
fluorophores in DOM in relation to aromatic amino acids, Mar. Chem.,
82, 255–271, https://doi.org/10.1016/S0304-4203(03)00073-2, 2003.
Yang, L., Chen, W., Zhuang, W.-E., Cheng, Q., Li, W., Wang, H., Guo, W.,
Chen, C.-T. A., and Liu, M.: Characterization and bioavailability of
rainwater dissolved organic matter at the southeast coast of China using
absorption spectroscopy and fluorescence EEM-PARAFAC, Eastuar. Coast. Shelf S., 217, 45–55, https://doi.org/10.1016/j.ecss.2018.11.002, 2019.
Zapata, M., Rodríguez, F., and Garrido, J. L.: Separation of
chlorophylls and carotenoids from marine phytoplankton: a new HPLC method
using a reversed phase C8 column and pyridine-containing mobile phases,
Mar. Ecol. Prog. Ser., 195, 29–45, https://doi.org/10.3354/meps195029, 2000.
Short summary
Characteristics of atmospheric sulfur and organic carbon species in marine aerosols and the environmental factors influencing their distributions were investigated over the Southern Ocean and the Amundsen Sea, Antarctica, during austral summer. The simultaneous measurements of chemical species in aerosols as well as the chemical and biological properties of seawater in the Amundsen Sea allowed for a better understanding of the effect of the ocean ecosystem on marine aerosols.
Characteristics of atmospheric sulfur and organic carbon species in marine aerosols and the...
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