Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Journal topic

Journal metrics

Journal metrics

  • IF value: 5.414 IF 5.414
  • IF 5-year value: 5.958 IF 5-year
    5.958
  • CiteScore value: 9.7 CiteScore
    9.7
  • SNIP value: 1.517 SNIP 1.517
  • IPP value: 5.61 IPP 5.61
  • SJR value: 2.601 SJR 2.601
  • Scimago H <br class='hide-on-tablet hide-on-mobile'>index value: 191 Scimago H
    index 191
  • h5-index value: 89 h5-index 89
ACP | Articles | Volume 20, issue 8
Atmos. Chem. Phys., 20, 5145–5155, 2020
https://doi.org/10.5194/acp-20-5145-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 20, 5145–5155, 2020
https://doi.org/10.5194/acp-20-5145-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 30 Apr 2020

Research article | 30 Apr 2020

Formation of highly oxygenated organic molecules from chlorine-atom-initiated oxidation of alpha-pinene

Yonghong Wang et al.

Related authors

Enhanced growth rate of atmospheric particles from sulfuric acid
Dominik Stolzenburg, Mario Simon, Ananth Ranjithkumar, Andreas Kürten, Katrianne Lehtipalo, Hamish Gordon, Sebastian Ehrhart, Henning Finkenzeller, Lukas Pichelstorfer, Tuomo Nieminen, Xu-Cheng He, Sophia Brilke, Mao Xiao, António Amorim, Rima Baalbaki, Andrea Baccarini, Lisa Beck, Steffen Bräkling, Lucía Caudillo Murillo, Dexian Chen, Biwu Chu, Lubna Dada, António Dias, Josef Dommen, Jonathan Duplissy, Imad El Haddad, Lukas Fischer, Loic Gonzalez Carracedo, Martin Heinritzi, Changhyuk Kim, Theodore K. Koenig, Weimeng Kong, Houssni Lamkaddam, Chuan Ping Lee, Markus Leiminger, Zijun Li, Vladimir Makhmutov, Hanna E. Manninen, Guillaume Marie, Ruby Marten, Tatjana Müller, Wei Nie, Eva Partoll, Tuukka Petäjä, Joschka Pfeifer, Maxim Philippov, Matti P. Rissanen, Birte Rörup, Siegfried Schobesberger, Simone Schuchmann, Jiali Shen, Mikko Sipilä, Gerhard Steiner, Yuri Stozhkov, Christian Tauber, Yee Jun Tham, António Tomé, Miguel Vazquez-Pufleau, Andrea C. Wagner, Mingyi Wang, Yonghong Wang, Stefan K. Weber, Daniela Wimmer, Peter J. Wlasits, Yusheng Wu, Qing Ye, Marcel Zauner-Wieczorek, Urs Baltensperger, Kenneth S. Carslaw, Joachim Curtius, Neil M. Donahue, Richard C. Flagan, Armin Hansel, Markku Kulmala, Jos Lelieveld, Rainer Volkamer, Jasper Kirkby, and Paul M. Winkler
Atmos. Chem. Phys., 20, 7359–7372, https://doi.org/10.5194/acp-20-7359-2020,https://doi.org/10.5194/acp-20-7359-2020, 2020
Short summary
Rapid mass growth and enhanced light extinction of atmospheric aerosols during the heating season haze episodes in Beijing revealed by aerosol-chemistry-radiation-boundary layer interaction
Zhuohui Lin, Yonghong Wang, Feixue Zheng, Ying Zhou, Yishuo Guo, Zemin Feng, Chang Li, Yusheng Zhang, Simo Hakala, Tommy Chan, Chao Yan, Kaspar R. Daellenbach, Biwu Chu, Lubna Dada, Juha Kangasluoma, Lei Yao, Xiaolong Fan, Wei Du, Jing Cai, Runlong Cai, Tom V. Kokkonen, Putian Zhou, Lili Wang, Tuukka Petäjä, Federico Bianchi, Veli-Matti Kerminen, Yongchun Liu, and Markku Kulmala
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-223,https://doi.org/10.5194/acp-2020-223, 2020
Preprint under review for ACP
Size segregated particle number and mass emissions in urban Beijing
Jing Cai, Biwu Chu, Lei Yao, Chao Yan, Liine M. Heikkinen, Feixue Zheng, Chang Li, Xiaolong Fan, Shaojun Zhang, Daoyuan Yang, Yonghong Wang, Tom V. Kokkonen, Tommy Chan, Ying Zhou, Lubna Dada, Yongchun Liu, Hong He, Pauli Paasonen, Joni T. Kujansuu, Tuukka Petäjä, Claudia Mohr, Juha Kangasluoma, Federico Bianchi, Yele Sun, Philip L. Croteau, Douglas R. Worsnop, Veli-Matti Kerminen, Wei Du, Markku Kulmala, and Kaspar R. Daellenbach
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-248,https://doi.org/10.5194/acp-2020-248, 2020
Preprint under review for ACP
Short summary
Formation of Nighttime Sulfuric Acid from the Ozonolysis of Alkenes in Beijing
Yishuo Guo, Chao Yan, Chang Li, Zemin Feng, Ying Zhou, Zhuohui Lin, Lubna Dada, Dominik Stolzenburg, Rujing Yin, Jenni Kontkanen, Kaspar R. Daellenbach, Juha Kangasluoma, Lei Yao, Biwu Chu, Yonghong Wang, Runlong Cai, Federico Bianchi, Yongchun Liu, and Markku Kulmala
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-1111,https://doi.org/10.5194/acp-2019-1111, 2020
Preprint under review for ACP
Short summary
Size-resolved particle number emissions in Beijing determined from measured particle size distributions
Jenni Kontkanen, Chenjuan Deng, Yueyun Fu, Lubna Dada, Ying Zhou, Jing Cai, Kaspar R. Dällenbach, Simo Hakala, Tom V. Kokkonen, Zhuohui Lin, Yongchun Liu, Yonghong Wang, Chao Yan, Tuukka Petäjä, Jingkun Jiang, Markku Kulmala, and Pauli Paasonen
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-215,https://doi.org/10.5194/acp-2020-215, 2020
Revised manuscript under review for ACP
Short summary

Related subject area

Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
An investigation on hygroscopic properties of 15 black carbon (BC)-containing particles from different carbon sources: roles of organic and inorganic components
Minli Wang, Yiqun Chen, Heyun Fu, Xiaolei Qu, Bengang Li, Shu Tao, and Dongqiang Zhu
Atmos. Chem. Phys., 20, 7941–7954, https://doi.org/10.5194/acp-20-7941-2020,https://doi.org/10.5194/acp-20-7941-2020, 2020
Short summary
Deconvolution of FIGAERO–CIMS thermal desorption profiles using positive matrix factorisation to identify chemical and physical processes during particle evaporation
Angela Buchholz, Arttu Ylisirniö, Wei Huang, Claudia Mohr, Manjula Canagaratna, Douglas R. Worsnop, Siegfried Schobesberger, and Annele Virtanen
Atmos. Chem. Phys., 20, 7693–7716, https://doi.org/10.5194/acp-20-7693-2020,https://doi.org/10.5194/acp-20-7693-2020, 2020
Short summary
Mineralogy and geochemistry of Asian dust: dependence on migration path, fractionation, and reactions with polluted air
Gi Young Jeong
Atmos. Chem. Phys., 20, 7411–7428, https://doi.org/10.5194/acp-20-7411-2020,https://doi.org/10.5194/acp-20-7411-2020, 2020
Short summary
Photochemical transformation of residential wood combustion emissions: dependence of organic aerosol composition on OH exposure
Anni Hartikainen, Petri Tiitta, Mika Ihalainen, Pasi Yli-Pirilä, Jürgen Orasche, Hendryk Czech, Miika Kortelainen, Heikki Lamberg, Heikki Suhonen, Hanna Koponen, Liqing Hao, Ralf Zimmermann, Jorma Jokiniemi, Jarkko Tissari, and Olli Sippula
Atmos. Chem. Phys., 20, 6357–6378, https://doi.org/10.5194/acp-20-6357-2020,https://doi.org/10.5194/acp-20-6357-2020, 2020
Short summary
Seawater analysis by ambient mass-spectrometry-based seaomics
Nicolás Zabalegui, Malena Manzi, Antoine Depoorter, Nathalie Hayeck, Marie Roveretto, Chunlin Li, Manuela van Pinxteren, Hartmut Herrmann, Christian George, and María Eugenia Monge
Atmos. Chem. Phys., 20, 6243–6257, https://doi.org/10.5194/acp-20-6243-2020,https://doi.org/10.5194/acp-20-6243-2020, 2020
Short summary

Cited articles

Berndt, T., Richters, S., Jokinen, T., Hyttinen, N., Kurtén, T., Otkjaer, R. V, Kjaergaard, H. G., Stratmann, F., Herrmann, H., Sipilä, M., Kulmala, M., and Ehn, M.: ARTICLE Hydroxyl radical-induced formation of highly oxidized organic compounds, Nat. Commun., 7, 13677, https://doi.org/10.1038/ncomms13677, 2016. 
Bianchi, F., Kurtén, T., Riva, M., Mohr, C., Rissanen, M. P., Roldin, P., Berndt, T., Crounse, J. D., Wennberg, P. O., Mentel, T. F., Wildt, J., Junninen, H., Jokinen, T., Kulmala, M., Worsnop, D. R., Thornton, J. A., Donahue, N., Kjaergaard, H. G., and Ehn, M.: Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol, Chem. Rev., 119, 3472–3509, https://doi.org/10.1021/acs.chemrev.8b00395, 2019. 
Cai, X. and Griffin, R. J.: Secondary aerosol formation from the oxidation of biogenic hydrocarbons by chlorine atoms, J. Geophys. Res.-Atmos., 111, 1–14, https://doi.org/10.1029/2005JD006857, 2006. 
Crounse, J. D., Nielsen, L. B., Jørgensen, S., Kjaergaard, H. G., and Wennberg, P. O.: Autoxidation of organic compounds in the atmosphere, J. Phys. Chem. Lett., 4, 3513–3520, https://doi.org/10.1021/jz4019207, 2013. 
Decarlo, P. F., Kimmel, J. R., Trimborn, A., Northway, M. J., Jayne, J. T., Aiken, A. C., Gonin, M., Fuhrer, K., Horvath, T., Docherty, K. S., Worsnop, D. R., and Jimenez, J. L.: Field-Deployable, High-Resolution, Time-of-Flight Aerosol Mass Spectrometer, Anal. Chem., 78, 8281–8289, https://doi.org/10.1021/ac061249n, 2006. 
Publications Copernicus
Download
Short summary
Chamber experiments were conducted with alpha-pinene and chlorine under low- and high-nitrogen-oxide (NOX) conditions. We estimated the HOM yields from chlorine-initiated oxidation of alpha-pinene under low-NOX conditions to be around 1.8 %, though with a uncertainty range (0.8 %–4 %) due to lack of suitable calibration methods. Our study clearly demonstrates that the chlorine-atom-initiated oxidation of alpha-pinene can produce low-volatility organic compounds.
Chamber experiments were conducted with alpha-pinene and chlorine under low- and...
Citation