Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Journal topic

Journal metrics

Journal metrics

  • IF value: 5.414 IF 5.414
  • IF 5-year value: 5.958 IF 5-year
    5.958
  • CiteScore value: 9.7 CiteScore
    9.7
  • SNIP value: 1.517 SNIP 1.517
  • IPP value: 5.61 IPP 5.61
  • SJR value: 2.601 SJR 2.601
  • Scimago H <br class='hide-on-tablet hide-on-mobile'>index value: 191 Scimago H
    index 191
  • h5-index value: 89 h5-index 89
ACP | Articles | Volume 20, issue 5
Atmos. Chem. Phys., 20, 2695–2707, 2020
https://doi.org/10.5194/acp-20-2695-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 20, 2695–2707, 2020
https://doi.org/10.5194/acp-20-2695-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 04 Mar 2020

Research article | 04 Mar 2020

Kinetic and mechanistic study of the reaction between methane sulfonamide (CH3S(O)2NH2) and OH

Matias Berasategui et al.

Related authors

A new marine biogenic emission: methane sulfonamide (MSAM), dimethyl sulfide (DMS), and dimethyl sulfone (DMSO2) measured in air over the Arabian Sea
Achim Edtbauer, Christof Stönner, Eva Y. Pfannerstill, Matias Berasategui, David Walter, John N. Crowley, Jos Lelieveld, and Jonathan Williams
Atmos. Chem. Phys., 20, 6081–6094, https://doi.org/10.5194/acp-20-6081-2020,https://doi.org/10.5194/acp-20-6081-2020, 2020
Short summary
Kinetics of the OH + NO2 reaction: effect of water vapour and new parameterization for global modelling
Damien Amedro, Matias Berasategui, Arne J. C. Bunkan, Andrea Pozzer, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 20, 3091–3105, https://doi.org/10.5194/acp-20-3091-2020,https://doi.org/10.5194/acp-20-3091-2020, 2020
Short summary
Kinetics of the OH + NO2 reaction: rate coefficients (217–333 K, 16–1200 mbar) and fall-off parameters for N2 and O2 bath gases
Damien Amedro, Arne J. C. Bunkan, Matias Berasategui, and John N. Crowley
Atmos. Chem. Phys., 19, 10643–10657, https://doi.org/10.5194/acp-19-10643-2019,https://doi.org/10.5194/acp-19-10643-2019, 2019
Short summary

Related subject area

Subject: Gases | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR
Anna Novelli, Luc Vereecken, Birger Bohn, Hans-Peter Dorn, Georgios I. Gkatzelis, Andreas Hofzumahaus, Frank Holland, David Reimer, Franz Rohrer, Simon Rosanka, Domenico Taraborrelli, Ralf Tillmann, Robert Wegener, Zhujun Yu, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs
Atmos. Chem. Phys., 20, 3333–3355, https://doi.org/10.5194/acp-20-3333-2020,https://doi.org/10.5194/acp-20-3333-2020, 2020
Short summary
Kinetics of the OH + NO2 reaction: effect of water vapour and new parameterization for global modelling
Damien Amedro, Matias Berasategui, Arne J. C. Bunkan, Andrea Pozzer, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 20, 3091–3105, https://doi.org/10.5194/acp-20-3091-2020,https://doi.org/10.5194/acp-20-3091-2020, 2020
Short summary
The nitrogen budget of laboratory-simulated western U.S. wildfires during the FIREX 2016 FireLab study
James M. Roberts, Chelsea E. Stockwell, Robert J. Yokelson, Joost de Gouw, Yong Liu, Vanessa Selimovic, Abigail R. Koss, Kanako Sekimoto, Matthew M. Coggon, Bin Yuan, Kyle J. Zarzana, Steven S. Brown, Cristina Santin, Stefan H. Doerr, and Carsten Warneke
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-66,https://doi.org/10.5194/acp-2020-66, 2020
Revised manuscript accepted for ACP
Short summary
Atmospheric fate of two relevant unsaturated ketoethers: kinetics, products and mechanisms for the reaction of hydroxyl radicals with (E)-4-methoxy-3-buten-2-one and 1-(E)-1-methoxy-2-methyl-1-penten-3-one
Rodrigo Gastón Gibilisco, Ian Barnes, Iustinian Gabriel Bejan, and Peter Wiesen
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-867,https://doi.org/10.5194/acp-2019-867, 2020
Revised manuscript accepted for ACP
Dimensionality-reduction techniques for complex mass spectrometric datasets: application to laboratory atmospheric organic oxidation experiments
Abigail R. Koss, Manjula R. Canagaratna, Alexander Zaytsev, Jordan E. Krechmer, Martin Breitenlechner, Kevin J. Nihill, Christopher Y. Lim, James C. Rowe, Joseph R. Roscioli, Frank N. Keutsch, and Jesse H. Kroll
Atmos. Chem. Phys., 20, 1021–1041, https://doi.org/10.5194/acp-20-1021-2020,https://doi.org/10.5194/acp-20-1021-2020, 2020
Short summary

Cited articles

Andreae, M. O.: Ocean-atmosphere interactions in the global biogeochemical sulfur cycle, Mar. Chem., 30, 1–29, https://doi.org/10.1016/0304-4203(90)90059-l, 1990. 
Andreae, M. O. and Crutzen, P. J.: Atmospheric aerosols: Biogeochemical sources and role in atmospheric chemistry, Science, 276, 1052–1058, https://doi.org/10.1126/science.276.5315.1052, 1997. 
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I – gas phase reactions of Ox, HOx, NOx and SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004. 
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., Troe, J., and IUPAC Subcommittee: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species, Atmos. Chem. Phys., 6, 3625–4055, https://doi.org/10.5194/acp-6-3625-2006, 2006. 
Barnes, I., Solignac, G., Mellouki, A., and Becker, K. H.: Aspects of the Atmospheric Chemistry of Amides, Chem. Phys. Chem., 11, 3844–3857, https://doi.org/10.1002/cphc.201000374, 2010. 
Publications Copernicus
Download
Short summary
We have determined the rate coefficient and mechanism for the reaction of the OH radical with methane sulphonamide, a trace gas which has recently been found in the atmosphere. The rate coefficient is 1.4 × 10−13 cm3 molec.−1 s−1, which indicates a tropospheric lifetime of > 2 months. The observation of CO, CO2, SO2, HNO3, HCOOH, and N2O products enabled us to derive a detailed reaction mechanism for the reaction, which proceeds predominantly by H abstraction from the CH3 group.
We have determined the rate coefficient and mechanism for the reaction of the OH radical with...
Citation