Articles | Volume 19, issue 11
https://doi.org/10.5194/acp-19-7609-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-7609-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
07 Jun 2019
Research article |
| 07 Jun 2019
Effect of temperature on the formation of highly oxygenated organic molecules (HOMs) from alpha-pinene ozonolysis
Lauriane L. J. Quéléver
CORRESPONDING AUTHOR
Institute for Atmospheric and Earth System Research (INAR/Physics), P.O. Box 64, 00014 University of Helsinki, Finland
Kasper Kristensen
Department of Chemistry, Aarhus University, Langelandsgade 140,
8000 Aarhus C, Denmark
presently at: Department of Engineering, Aarhus University,
Finlandsgade 12, 8200 Aarhus N, Denmark
Louise Normann Jensen
Department of Chemistry, Aarhus University, Langelandsgade 140,
8000 Aarhus C, Denmark
Bernadette Rosati
Department of Chemistry, Aarhus University, Langelandsgade 140,
8000 Aarhus C, Denmark
Department of Physics and Astronomy, Aarhus University, Ny
Munkegade 120, 8000 Aarhus C, Denmark
Ricky Teiwes
Department of Chemistry, Aarhus University, Langelandsgade 140,
8000 Aarhus C, Denmark
Department of Physics and Astronomy, Aarhus University, Ny
Munkegade 120, 8000 Aarhus C, Denmark
Kaspar R. Daellenbach
Institute for Atmospheric and Earth System Research (INAR/Physics), P.O. Box 64, 00014 University of Helsinki, Finland
Otso Peräkylä
Institute for Atmospheric and Earth System Research (INAR/Physics), P.O. Box 64, 00014 University of Helsinki, Finland
Pontus Roldin
Division of Nuclear Physics, Lund University, P.O. Box 118, 22100
Lund, Sweden
Rossana Bossi
Department of Environmental Science, Aarhus University,
Frederiksborgvej 399, 4000 Roskilde, Denmark
Henrik B. Pedersen
Department of Physics and Astronomy, Aarhus University, Ny
Munkegade 120, 8000 Aarhus C, Denmark
Marianne Glasius
Department of Chemistry, Aarhus University, Langelandsgade 140,
8000 Aarhus C, Denmark
Merete Bilde
Department of Chemistry, Aarhus University, Langelandsgade 140,
8000 Aarhus C, Denmark
Institute for Atmospheric and Earth System Research (INAR/Physics), P.O. Box 64, 00014 University of Helsinki, Finland
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- Molecular understanding of new-particle formation from <i>α</i>-pinene between −50 and +25 °C M. Simon et al. 10.5194/acp-20-9183-2020
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40 citations as recorded by crossref.
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
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- Estimation of secondary organic aerosol formation parameters for the volatility basis set combining thermodenuder, isothermal dilution, and yield measurements P. Uruci et al. 10.5194/amt-16-3155-2023
- Gas-to-Particle Partitioning of Products from Ozonolysis of Δ3-Carene and the Effect of Temperature and Relative Humidity L. Li et al. 10.1021/acs.jpca.3c07316
- Kinetics and Products of Heterogeneous Hydroxyl Radical Oxidation of Isoprene Epoxydiol-Derived Secondary Organic Aerosol J. Yan et al. 10.1021/acsearthspacechem.3c00073
- Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison M. Okuljar et al. 10.5194/acp-23-12965-2023
- The Aarhus Chamber Campaign on Highly Oxygenated Organic Molecules and Aerosols (ACCHA): particle formation, organic acids, and dimer esters from <i>α</i>-pinene ozonolysis at different temperatures K. Kristensen et al. 10.5194/acp-20-12549-2020
- Pathogenic Mechanisms of Secondary Organic Aerosols T. Déméautis et al. 10.1021/acs.chemrestox.1c00353
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
- Molecular understanding of new-particle formation from <i>α</i>-pinene between −50 and +25 °C M. Simon et al. 10.5194/acp-20-9183-2020
- CRI-HOM: A novel chemical mechanism for simulating highly oxygenated organic molecules (HOMs) in global chemistry–aerosol–climate models J. Weber et al. 10.5194/acp-20-10889-2020
- Secondary aerosol formation from dimethyl sulfide – improved mechanistic understanding based on smog chamber experiments and modelling R. Wollesen de Jonge et al. 10.5194/acp-21-9955-2021
- Temperature and volatile organic compound concentrations as controlling factors for chemical composition of <i>α</i>-pinene-derived secondary organic aerosol L. Jensen et al. 10.5194/acp-21-11545-2021
- Large Discrepancy in the Formation of Secondary Organic Aerosols from Structurally Similar Monoterpenes D. Thomsen et al. 10.1021/acsearthspacechem.0c00332
- The effect of temperature and relative humidity on secondary organic aerosol formation from ozonolysis of Δ3-carene D. Thomsen et al. 10.1039/D3EA00128H
- Evidence and evolution of Criegee intermediates, hydroperoxides and secondary organic aerosols formedviaozonolysis of α-pinene A. Bagchi et al. 10.1039/C9CP06306D
- Online measurement of highly oxygenated compounds from organic aerosol E. Häkkinen et al. 10.5194/amt-16-1705-2023
- Ozonolysis of α-Pinene and Δ3-Carene Mixtures: Formation of Dimers with Two Precursors D. Thomsen et al. 10.1021/acs.est.2c04786
- Observations of highly oxidized molecules and particle nucleation in the atmosphere of Beijing J. Brean et al. 10.5194/acp-19-14933-2019
- Secondary organic aerosol formation from camphene oxidation: measurements and modeling Q. Li et al. 10.5194/acp-22-3131-2022
- The role of highly oxygenated organic molecules in the Boreal aerosol-cloud-climate system P. Roldin et al. 10.1038/s41467-019-12338-8
- Effect of OH scavengers on the chemical composition of α-pinene secondary organic aerosol D. Bell et al. 10.1039/D2EA00105E
- Nontrivial Impact of Relative Humidity on Organic New Particle Formation from Ozonolysis of cis-3-Hexenyl Acetate A. Flueckiger et al. 10.3390/air1040017
- Particle-Bound Highly Oxidized Organic Molecules Derived from Aromatic Hydrocarbons in an Urban Atmosphere M. Zhu et al. 10.1021/acs.estlett.2c00841
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
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- Reaction Rate Coefficient of OH Radicals with d9-Butanol as a Function of Temperature A. Allani et al. 10.1021/acsomega.1c01942
- Oligomer and highly oxygenated organic molecule formation from oxidation of oxygenated monoterpenes emitted by California sage plants A. Mehra et al. 10.5194/acp-20-10953-2020
- The effect of meteorological conditions and atmospheric composition in the occurrence and development of new particle formation (NPF) events in Europe D. Bousiotis et al. 10.5194/acp-21-3345-2021
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
- Removal of VOCs from wood processing ventilation air by advanced oxidation gas-to-particle prototype system E. Krugly et al. 10.1016/j.psep.2022.03.043
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- Airborne particulate matter R. Harrison 10.1098/rsta.2019.0319
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- Effect of Relative Humidity on the Rate of New Particle Formation for Different VOCs A. Flueckiger & G. Petrucci 10.3390/atmos15040480
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Latest update: 25 Apr 2024
Short summary
Highly oxygenated organic molecules (HOMs) form rapidly in oxidation of monoterpenes and have been shown to be crucial for secondary organic aerosol formation. We studied the formation of HOMs under different temperatures, finding a strong dependence on their yields. As temperatures decrease, the isomerization reactions that allow rapid oxidation by molecular oxygen slow down, and competing reaction pathways can suppress the HOM formation almost completely, especially at high VOC loadings.
Highly oxygenated organic molecules (HOMs) form rapidly in oxidation of monoterpenes and have...
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