Articles | Volume 19, issue 3
https://doi.org/10.5194/acp-19-1555-2019
https://doi.org/10.5194/acp-19-1555-2019
Research article
 | 
06 Feb 2019
Research article |  | 06 Feb 2019

Relative humidity effect on the formation of highly oxidized molecules and new particles during monoterpene oxidation

Xiaoxiao Li, Sabrina Chee, Jiming Hao, Jonathan P. D. Abbatt, Jingkun Jiang, and James N. Smith

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Cited articles

Aschmann, S. M., Arey, J., and Atkinson, R.: OH radical formation from the gas-phase reactions of O3 with a series of terpenes, Atmos Environ, 36, 4347–4355, https://doi.org/10.1016/s1352-2310(02)00355-2, 2002. 
Atkinson, R.: Gas-phase tropospheric chemistry of volatile organic compounds: 1. Alkanes and alkenes, J. Phys. Chem. Ref. Data, 26, 215–290, 1997. 
Atkinson, R. and Arey, J.: Gas-phase tropospheric chemistry of biogenic volatile organic compounds: a review, Atmos. Environ., 37, 197–219, 2003. 
Atkinson, R., Aschmann, S. M., Arey, J., and Shorees, B.: Formation of OH radicals in the gas phase reactions of O3 with a series of terpenes, J. Geophys. Res., 97, 6065–6073, 1992. 
Ball, S. M., Hanson, D. R., Eisele, F. L., and McMurry, P. H.: Laboratory studies of particle nucleation: Initial results for H2SO4, H2O, and NH3 vapors, J Geophys Res-Atmos, 104, 23709–23718, https://doi.org/10.1029/1999jd900411, 1999. 
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Short summary
We performed lab experiments to explore the role of relative humidity, RH, in atmospheric monoterpene oxidation and new particle formation. These studies will provide insights into the most important steps in the process, while also more accurately representing the real atmosphere. We found that the detected compounds did not change with RH, and in fact could mostly be fully explained by the autoxidation of organic peroxy radicals followed by bimolecular reactions with other peroxy radicals.
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