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ACP | Articles | Volume 19, issue 20
Atmos. Chem. Phys., 19, 13037–13052, 2019
https://doi.org/10.5194/acp-19-13037-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 19, 13037–13052, 2019
https://doi.org/10.5194/acp-19-13037-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 22 Oct 2019

Research article | 22 Oct 2019

Carboxylic acids from limonene oxidation by ozone and hydroxyl radicals: insights into mechanisms derived using a FIGAERO-CIMS

Julia Hammes et al.

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Cited articles

Atkinson, R., Aschmann, S. M., Arey, J., and Shorees, B.: Formation of OH radicals in the gas phase reactions of O3 with a series of terpenes, J. Geophys. Res., 97, 6065–6073, https://doi.org/10.1029/92jd00062, 1992. 
Barley, M. H., Topping, D., Lowe, D., Utembe, S., and McFiggans, G.: The sensitivity of secondary organic aerosol (SOA) component partitioning to the predictions of component properties – Part 3: Investigation of condensed compounds generated by a near-explicit model of VOC oxidation, Atmos. Chem. Phys., 11, 13145–13159, https://doi.org/10.5194/acp-11-13145-2011, 2011. 
Bertram, T. H., Kimmel, J. R., Crisp, T. A., Ryder, O. S., Yatavelli, R. L. N., Thornton, J. A., Cubison, M. J., Gonin, M., and Worsnop, D. R.: A field-deployable, chemical ionization time-of-flight mass spectrometer, Atmos. Meas. Tech., 4, 1471–1479, https://doi.org/10.5194/amt-4-1471-2011, 2011. 
Brown, S. K., Sim, M. R., Abramson, M. J., and Gray, C. N.: Concentrations of Volatile Organic-Compounds in Indoor Air – a Review, Indoor Air, 4, 123–134, https://doi.org/10.1111/j.1600-0668.1994.t01-2-00007.x, 1994. 
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Short summary
Identifying the chemical pathways of condensable products such as carboxylic acids is essential for predicting SOA formation. This identification is inherently difficult, as such products reside in both the gas and particulate phases. We measured acids, produced from atmospheric oxidation of limonene, in both phases and scrutinised the mechanistic understanding of their formation. The mechanisms explain nearly 75 % of the gas-phase signal at the lowest concentration (8.4 ppb, 23 % acid yield).
Identifying the chemical pathways of condensable products such as carboxylic acids is essential...
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