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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
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ACP | Articles | Volume 19, issue 20
Atmos. Chem. Phys., 19, 13037–13052, 2019
https://doi.org/10.5194/acp-19-13037-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 19, 13037–13052, 2019
https://doi.org/10.5194/acp-19-13037-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 22 Oct 2019

Research article | 22 Oct 2019

Carboxylic acids from limonene oxidation by ozone and hydroxyl radicals: insights into mechanisms derived using a FIGAERO-CIMS

Julia Hammes et al.

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Short summary
Identifying the chemical pathways of condensable products such as carboxylic acids is essential for predicting SOA formation. This identification is inherently difficult, as such products reside in both the gas and particulate phases. We measured acids, produced from atmospheric oxidation of limonene, in both phases and scrutinised the mechanistic understanding of their formation. The mechanisms explain nearly 75 % of the gas-phase signal at the lowest concentration (8.4 ppb, 23 % acid yield).
Identifying the chemical pathways of condensable products such as carboxylic acids is essential...
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