Articles | Volume 19, issue 18
https://doi.org/10.5194/acp-19-11939-2019
https://doi.org/10.5194/acp-19-11939-2019
Research article
 | 
25 Sep 2019
Research article |  | 25 Sep 2019

Trapping of HCl and oxidised organic trace gases in growing ice at temperatures relevant to cirrus clouds

Matthias Kippenberger, Gerhard Schuster, Jos Lelieveld, and John N. Crowley

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Cited articles

Abbatt, J. P. D.: Interactions of atmospheric trace gases with ice surfaces: Adsorption and reaction, Chem. Rev., 103, 4783–4800, 2003. 
Abbatt, J. P. D., Bartels-Rausch, T., Ullerstam, M., and Ye, T. J.: Uptake of acetone, ethanol and benzene to snow and ice: effects of surface area and temperature, Environ. Res. Lett., 3, 045008, https://doi.org/10.1088/1748-9326/3/4/045008, 2008. 
Ayotte, P., Marchand, P., Daschbach, J. L., Smith, R. S., and Kay, B. D.: HCl Adsorption and Ionization on Amorphous and Crystalline H2O Films below 50 K, J. Phys. Chem. A, 115, 6002–6014, https://doi.org/10.1021/jp110398j, 2011. 
Bailey, M. and Hallett, J.: Ice Crystal Linear Growth Rates from −20 degrees to −70 degrees C: Confirmation from Wave Cloud Studies, J. Atmos. Sci., 69, 390–402, https://doi.org/10.1175/jas-d-11-035.1, 2012. 
Becker, H. G. O.: Organikum, 21. edn., Wiley-WCH, Weinheim, 2001. 
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Short summary
We investigated the uptake of several trace gases to growing ice surfaces at temperatures relevant to cirrus clouds. HCl, a strong inorganic acid that ionises at the surface, was efficiently trapped in the growing ice, whereas oxidised organic trace gases, which attach to ice by hydrogen bonding, were not. HCl can be efficiently and rapidly removed from the gas phase in supersaturated ice clouds.
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