Articles | Volume 18, issue 9
https://doi.org/10.5194/acp-18-6381-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-6381-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
04 May 2018
Research article |
| 04 May 2018
| 04 May 2018
Triple oxygen isotopes indicate urbanization affects sources of nitrate in wet and dry atmospheric deposition
David M. Nelson
CORRESPONDING AUTHOR
University of Maryland Center for Environmental Science,
Appalachian Laboratory, Frostburg, MD 21532, USA
Nagoya University, Graduate School of Environmental Studies, Nagoya,
464-8601, Japan
Urumu Tsunogai
Nagoya University, Graduate School of Environmental Studies, Nagoya,
464-8601, Japan
Dong Ding
Nagoya University, Graduate School of Environmental Studies, Nagoya,
464-8601, Japan
Takuya Ohyama
Nagoya University, Graduate School of Environmental Studies, Nagoya,
464-8601, Japan
Daisuke D. Komatsu
Nagoya University, Graduate School of Environmental Studies, Nagoya,
464-8601, Japan
present address: Tokai University, Department of Marine and Earth
Science, Tokai, Japan
Fumiko Nakagawa
Nagoya University, Graduate School of Environmental Studies, Nagoya,
464-8601, Japan
Izumi Noguchi
Hokkaido Research Organization, Department of Environmental and
Geological Research, Institute of Environmental Sciences, Sapporo, 060-0819,
Japan
Takashi Yamaguchi
Hokkaido Research Organization, Department of Environmental and
Geological Research, Institute of Environmental Sciences, Sapporo, 060-0819,
Japan
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Cited
23 citations as recorded by crossref.
- Ambient urban N deposition drives increased biomass and total plant N in two native prairie grass species in the U.S. Southern Great Plains A. Ponette-González et al. 10.1371/journal.pone.0251089
- Vertical Changes in the Flux of Atmospheric Nitrate From a Forest Canopy to the Surface Soil Based on Δ17O Values T. Inoue et al. 10.1029/2020JG005876
- Tracing the source of nitrate in a forested stream showing elevated concentrations during storm events W. Ding et al. 10.5194/bg-19-3247-2022
- Atmospheric Δ<sup>17</sup>O(NO<sub>3</sub><sup>−</sup>) reveals nocturnal chemistry dominates nitrate production in Beijing haze P. He et al. 10.5194/acp-18-14465-2018
- Vertical measurements of stable nitrogen and oxygen isotope composition of fine particulate nitrate aerosol in Guangzhou city: Source apportionment and oxidation pathway Y. Wang et al. 10.1016/j.scitotenv.2022.161239
- The observation of isotopic compositions of atmospheric nitrate in Shanghai China and its implication for reactive nitrogen chemistry P. He et al. 10.1016/j.scitotenv.2020.136727
- Atmospheric nitrate formation pathways in urban and rural atmosphere of Northeast China: Implications for complicated anthropogenic effects Z. Li et al. 10.1016/j.envpol.2021.118752
- A Study of Chemical Processes of Nitrate in Atmospheric Aerosol and Snow Based on Stable Isotopes M. Chen et al. 10.3390/atmos15010059
- New Constraints on Isotopic Effects and Major Sources of Nitrate in Atmospheric Particulates by Combining δ15N and Δ17O Signatures W. Song et al. 10.1029/2020JD034168
- Substantial contribution of tree canopy nitrifiers to nitrogen fluxes in European forests R. Guerrieri et al. 10.1038/s41561-023-01364-3
- Export flux of unprocessed atmospheric nitrate from temperate forested catchments: a possible new index for nitrogen saturation F. Nakagawa et al. 10.5194/bg-15-7025-2018
- Nitrogen Isotope Differences between Major Atmospheric NOy Species: Implications for Transformation and Deposition Processes X. Liu et al. 10.1021/acs.estlett.0c00105
- Oxidation pathways and emission sources of atmospheric particulate nitrate in Seoul: based on <i>δ</i><sup>15</sup>N and Δ<sup>17</sup>O measurements S. Lim et al. 10.5194/acp-22-5099-2022
- Isotopic evidence that recent agriculture overprints climate variability in nitrogen deposition to the Tibetan Plateau Z. Li et al. 10.1016/j.envint.2020.105614
- Downpour dynamics: outsized impacts of storm events on unprocessed atmospheric nitrate export in an urban watershed J. Bostic et al. 10.5194/bg-20-2485-2023
- Characterization and sources of water-soluble organic species in PM2.5 in a remote mountain environment in Southeastern China J. Tao et al. 10.1016/j.atmosenv.2023.120057
- Isotopic constraints on the formation pathways and sources of atmospheric nitrate in the Mt. Everest region K. Wang et al. 10.1016/j.envpol.2020.115274
- Determination of the triple oxygen isotopic composition of tropospheric ozone in terminal positions using a multistep nitrite‐coated filter‐pack system H. Xu et al. 10.1002/rcm.9124
- Stable isotope ratio of atmospheric and seawater nitrate in the East Sea in the northwestern Pacific ocean H. Kim et al. 10.1016/j.marpolbul.2019.110610
- Triple oxygen isotopic evidence for atmospheric nitrate and its application in source identification for river systems in the Qinghai-Tibetan Plateau X. Xia et al. 10.1016/j.scitotenv.2019.06.204
- Estimating the nitrogen source apportionment of Sophora japonica in roadside green spaces using stable isotope C. Gong et al. 10.1016/j.scitotenv.2019.06.408
- Stable isotopic evidence for the excess leaching of unprocessed atmospheric nitrate from forested catchments under high nitrogen saturation W. Ding et al. 10.5194/bg-20-753-2023
- Terrestrial Nitrogen Inputs Affect the Export of Unprocessed Atmospheric Nitrate to Surface Waters: Insights from Triple Oxygen Isotopes of Nitrate J. Bostic et al. 10.1007/s10021-021-00722-9
23 citations as recorded by crossref.
- Ambient urban N deposition drives increased biomass and total plant N in two native prairie grass species in the U.S. Southern Great Plains A. Ponette-González et al. 10.1371/journal.pone.0251089
- Vertical Changes in the Flux of Atmospheric Nitrate From a Forest Canopy to the Surface Soil Based on Δ17O Values T. Inoue et al. 10.1029/2020JG005876
- Tracing the source of nitrate in a forested stream showing elevated concentrations during storm events W. Ding et al. 10.5194/bg-19-3247-2022
- Atmospheric Δ<sup>17</sup>O(NO<sub>3</sub><sup>−</sup>) reveals nocturnal chemistry dominates nitrate production in Beijing haze P. He et al. 10.5194/acp-18-14465-2018
- Vertical measurements of stable nitrogen and oxygen isotope composition of fine particulate nitrate aerosol in Guangzhou city: Source apportionment and oxidation pathway Y. Wang et al. 10.1016/j.scitotenv.2022.161239
- The observation of isotopic compositions of atmospheric nitrate in Shanghai China and its implication for reactive nitrogen chemistry P. He et al. 10.1016/j.scitotenv.2020.136727
- Atmospheric nitrate formation pathways in urban and rural atmosphere of Northeast China: Implications for complicated anthropogenic effects Z. Li et al. 10.1016/j.envpol.2021.118752
- A Study of Chemical Processes of Nitrate in Atmospheric Aerosol and Snow Based on Stable Isotopes M. Chen et al. 10.3390/atmos15010059
- New Constraints on Isotopic Effects and Major Sources of Nitrate in Atmospheric Particulates by Combining δ15N and Δ17O Signatures W. Song et al. 10.1029/2020JD034168
- Substantial contribution of tree canopy nitrifiers to nitrogen fluxes in European forests R. Guerrieri et al. 10.1038/s41561-023-01364-3
- Export flux of unprocessed atmospheric nitrate from temperate forested catchments: a possible new index for nitrogen saturation F. Nakagawa et al. 10.5194/bg-15-7025-2018
- Nitrogen Isotope Differences between Major Atmospheric NOy Species: Implications for Transformation and Deposition Processes X. Liu et al. 10.1021/acs.estlett.0c00105
- Oxidation pathways and emission sources of atmospheric particulate nitrate in Seoul: based on <i>δ</i><sup>15</sup>N and Δ<sup>17</sup>O measurements S. Lim et al. 10.5194/acp-22-5099-2022
- Isotopic evidence that recent agriculture overprints climate variability in nitrogen deposition to the Tibetan Plateau Z. Li et al. 10.1016/j.envint.2020.105614
- Downpour dynamics: outsized impacts of storm events on unprocessed atmospheric nitrate export in an urban watershed J. Bostic et al. 10.5194/bg-20-2485-2023
- Characterization and sources of water-soluble organic species in PM2.5 in a remote mountain environment in Southeastern China J. Tao et al. 10.1016/j.atmosenv.2023.120057
- Isotopic constraints on the formation pathways and sources of atmospheric nitrate in the Mt. Everest region K. Wang et al. 10.1016/j.envpol.2020.115274
- Determination of the triple oxygen isotopic composition of tropospheric ozone in terminal positions using a multistep nitrite‐coated filter‐pack system H. Xu et al. 10.1002/rcm.9124
- Stable isotope ratio of atmospheric and seawater nitrate in the East Sea in the northwestern Pacific ocean H. Kim et al. 10.1016/j.marpolbul.2019.110610
- Triple oxygen isotopic evidence for atmospheric nitrate and its application in source identification for river systems in the Qinghai-Tibetan Plateau X. Xia et al. 10.1016/j.scitotenv.2019.06.204
- Estimating the nitrogen source apportionment of Sophora japonica in roadside green spaces using stable isotope C. Gong et al. 10.1016/j.scitotenv.2019.06.408
- Stable isotopic evidence for the excess leaching of unprocessed atmospheric nitrate from forested catchments under high nitrogen saturation W. Ding et al. 10.5194/bg-20-753-2023
- Terrestrial Nitrogen Inputs Affect the Export of Unprocessed Atmospheric Nitrate to Surface Waters: Insights from Triple Oxygen Isotopes of Nitrate J. Bostic et al. 10.1007/s10021-021-00722-9
Latest update: 25 Apr 2024
Short summary
Atmospheric nitrate may be produced locally and/or come from upwind regions. To address this issue we measured oxygen and nitrogen isotopes of wet and dry nitrate deposition at nearby urban and rural sites. Our results suggest that, relative to nitrate in wet deposition in urban environments and wet and dry deposition in rural environments, nitrate in dry deposition in urban environments results from local NOx emissions more so than wet deposition, which is transported longer distances.
Atmospheric nitrate may be produced locally and/or come from upwind regions. To address this...
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