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Volume 18, issue 8
Atmos. Chem. Phys., 18, 6095–6120, 2018
https://doi.org/10.5194/acp-18-6095-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 18, 6095–6120, 2018
https://doi.org/10.5194/acp-18-6095-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 02 May 2018

Research article | 02 May 2018

The atmospheric impacts of monoterpene ozonolysis on global stabilised Criegee intermediate budgets and SO2 oxidation: experiment, theory and modelling

Mike J. Newland et al.
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Ahrens, J., Carlsson, P. T. M., Hertl, N., Olzmann, M., Pfeifle, M., Wolf, J. L., and Zeuch, T.: Infrared Detection of Criegee Intermediates Formed during the Ozonolysis of β-pinene and Their Reactivity towards Sulfur Dioxide, Angew. Chem. Int. Edit., 53, 715–719, 2014.
Alam, M. S., Camredon, M., Rickard, A. R., Carr, T., Wyche, K. P., Hornsby, K. E., Monks, P. S., and Bloss, W. J.: Total radical yields from tropospheric ethene ozonolysis, Phys. Chem. Chem. Phys., 13, 11002–11015, 2011.
Alam, M. S., Rickard, A. R., Camredon, M., Wyche, K. P., Carr, T., Hornsby, K. E., Monks, P. S., and Bloss, W. J.: Radical Product Yields from the Ozonolysis of Short Chain Alkenes under Atmospheric Boundary Layer Conditions, J. Phys. Chem. A, 117, 12468–12483, 2013.
Anglada, J. M., Gonzalez, J., and Torrent-Sucarrat, M.: Effects of the substituents on the reactivity of carbonyl oxides. A theoretical study on the reaction of substituted carbonyl oxides with water, Phys. Chem. Chem. Phys., 13, 13034–13045, 2011.
Anglada, M. and Sole, A.: Impact of the water dimer on the atmospheric reactivity of carbonyl oxides, Phys. Chem. Chem. Phys., 18, 17698–17712, 2016.
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Stabilised Criegee intermediates (SCIs) are formed in the reaction of alkenes with ozone, both of which are ubiquitous throughout the troposphere. We determine the fate and global distribution of SCI from monoterpene ozonolysis. One major fate of SCI is reaction with H2O, but for a fraction of SCIs, unimolecular reactions dominate. Concentrations of SCIs are high enough regionally to play a key role in the conversion of sulfur dioxide to aerosol, affecting air quality and climate.
Stabilised Criegee intermediates (SCIs) are formed in the reaction of alkenes with ozone, both...
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