Articles | Volume 18, issue 8
https://doi.org/10.5194/acp-18-5467-2018
https://doi.org/10.5194/acp-18-5467-2018
Research article
 | 
20 Apr 2018
Research article |  | 20 Apr 2018

Characterization of organic nitrate constituents of secondary organic aerosol (SOA) from nitrate-radical-initiated oxidation of limonene using high-resolution chemical ionization mass spectrometry

Cameron Faxon, Julia Hammes, Michael Le Breton, Ravi Kant Pathak, and Mattias Hallquist

Related authors

Carboxylic acids from limonene oxidation by ozone and hydroxyl radicals: insights into mechanisms derived using a FIGAERO-CIMS
Julia Hammes, Anna Lutz, Thomas Mentel, Cameron Faxon, and Mattias Hallquist
Atmos. Chem. Phys., 19, 13037–13052, https://doi.org/10.5194/acp-19-13037-2019,https://doi.org/10.5194/acp-19-13037-2019, 2019
Short summary

Related subject area

Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Molecular analysis of secondary organic aerosol and brown carbon from the oxidation of indole
Feng Jiang, Kyla Siemens, Claudia Linke, Yanxia Li, Yiwei Gong, Thomas Leisner, Alexander Laskin, and Harald Saathoff
Atmos. Chem. Phys., 24, 2639–2649, https://doi.org/10.5194/acp-24-2639-2024,https://doi.org/10.5194/acp-24-2639-2024, 2024
Short summary
Secondary organic aerosol formed by Euro 5 gasoline vehicle emissions: chemical composition and gas-to-particle phase partitioning
Evangelia Kostenidou, Baptiste Marques, Brice Temime-Roussel, Yao Liu, Boris Vansevenant, Karine Sartelet, and Barbara D'Anna
Atmos. Chem. Phys., 24, 2705–2729, https://doi.org/10.5194/acp-24-2705-2024,https://doi.org/10.5194/acp-24-2705-2024, 2024
Short summary
Assessment of the contribution of residential waste burning to ambient PM10 concentrations in Hungary and Romania
András Hoffer, Aida Meiramova, Ádám Tóth, Beatrix Jancsek-Turóczi, Gyula Kiss, Ágnes Rostási, Erika Andrea Levei, Luminita Marmureanu, Attila Machon, and András Gelencsér
Atmos. Chem. Phys., 24, 1659–1671, https://doi.org/10.5194/acp-24-1659-2024,https://doi.org/10.5194/acp-24-1659-2024, 2024
Short summary
Source differences in the components and cytotoxicity of PM2.5 from automobile exhaust, coal combustion, and biomass burning contributing to urban aerosol toxicity
Xiao-San Luo, Weijie Huang, Guofeng Shen, Yuting Pang, Mingwei Tang, Weijun Li, Zhen Zhao, Hanhan Li, Yaqian Wei, Longjiao Xie, and Tariq Mehmood
Atmos. Chem. Phys., 24, 1345–1360, https://doi.org/10.5194/acp-24-1345-2024,https://doi.org/10.5194/acp-24-1345-2024, 2024
Short summary
Chamber studies of OH + dimethyl sulfoxide and dimethyl disulfide: insights into the dimethyl sulfide oxidation mechanism
Matthew B. Goss and Jesse H. Kroll
Atmos. Chem. Phys., 24, 1299–1314, https://doi.org/10.5194/acp-24-1299-2024,https://doi.org/10.5194/acp-24-1299-2024, 2024
Short summary

Cited articles

Arthur, D. and Vassilvitskii, S.: k-means + + : The advantages of careful seeding, ACM-SIAM Symp. Discret. algorithms, 8, 1027–1035, 2007.
Atkinson, R., Aschmann, S. M., and Pitts, J. N. J.: Rate constants for the gas-phase reactions of the OH radical with a series of monoterpenes at 294 K, Atmos. Environ., 29, 2311–2316
Baptista, L., Pfeifer, R., Da Silva, E. C., and Arbilla, G.: Kinetics and thermodynamics of limonene ozonolysis, J. Phys. Chem. A, 115, 10911–10919, https://doi.org/10.1021/jp205734h, 2011.
Beaver, M. R., Clair, J. M. St., Paulot, F., Spencer, K. M., Crounse, J. D., LaFranchi, B. W., Min, K. E., Pusede, S. E., Wooldridge, P. J., Schade, G. W., Park, C., Cohen, R. C., and Wennberg, P. O.: Importance of biogenic precursors to the budget of organic nitrates: Observations of multifunctional organic nitrates by CIMS and TD-LIF during BEARPEX 2009, Atmos. Chem. Phys., 12, 5773–5785, https://doi.org/10.5194/acp-12-5773-2012, 2012.
Download
Short summary
Nighttime oxidation of organic compounds emitted from vegetation produce aerosol particles affecting climate and human health. Here we apply state-of the-art chemical characterization for a detailed study on the oxidation of limonene initiated by the nitrate radical. We now have the identity of major nitrated products and their thermal properties. Including a cluster analysis, through this study, new knowledge supporting modeling and field observations of organic nitrates is gained.
Altmetrics
Final-revised paper
Preprint