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Volume 18, issue 8 | Copyright

Special issue: Quadrennial Ozone Symposium 2016 – Status and trends...

Atmos. Chem. Phys., 18, 5415-5453, 2018
https://doi.org/10.5194/acp-18-5415-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 20 Apr 2018

Research article | 20 Apr 2018

Climatology and long-term evolution of ozone and carbon monoxide in the upper troposphere–lower stratosphere (UTLS) at northern midlatitudes, as seen by IAGOS from 1995 to 2013

Yann Cohen1,2, Hervé Petetin1, Valérie Thouret1, Virginie Marécal2, Béatrice Josse2, Hannah Clark1, Bastien Sauvage1, Alain Fontaine1, Gilles Athier1, Romain Blot1, Damien Boulanger3, Jean-Marc Cousin1, and Philippe Nédélec1 Yann Cohen et al.
  • 1Laboratoire d'Aérologie, Université de Toulouse, CNRS, UPS, France
  • 2Centre National de Recherches Météorologiques, CNRS-Météo-France, UMR 3589, Toulouse, France
  • 3Observatoire Midi-Pyrénées, Toulouse, France

Abstract. In situ measurements in the upper troposphere–lower stratosphere (UTLS) have been performed in the framework of the European research infrastructure IAGOS (In-service Aircraft for a Global Observing System) for ozone since 1994 and for carbon monoxide (CO) since 2002. The flight tracks cover a wide range of longitudes in the northern extratropics, extending from the North American western coast (125°W) to the eastern Asian coast (135°E) and more recently over the northern Pacific Ocean. Several tropical regions are also sampled frequently, such as the Brazilian coast, central and southern Africa, southeastern Asia, and the western half of the Maritime Continent. As a result, a new set of climatologies for O3 (August 1994–December 2013) and CO (December 2001–December 2013) in the upper troposphere (UT), tropopause layer, and lower stratosphere (LS) are made available, including gridded horizontal distributions on a semi-global scale and seasonal cycles over eight well-sampled regions of interest in the northern extratropics. The seasonal cycles generally show a summertime maximum in O3 and a springtime maximum in CO in the UT, in contrast to the systematic springtime maximum in O3 and the quasi-absence of a seasonal cycle of CO in the LS. This study highlights some regional variabilities in the UT, notably (i) a west–east difference of O3 in boreal summer with up to 15ppb more O3 over central Russia compared with northeast America, (ii) a systematic west–east gradient of CO from 60 to 140°E, especially noticeable in spring and summer with about 5ppb by 10 degrees longitude, (iii) a broad spring/summer maximum of CO over northeast Asia, and (iv) a spring maximum of O3 over western North America. Thanks to almost 20 years of O3 and 12 years of CO measurements, the IAGOS database is a unique data set to derive trends in the UTLS at northern midlatitudes. Trends in O3 in the UT are positive and statistically significant in most regions, ranging from +0.25 to +0.45ppbyr−1, characterized by the significant increase in the lowest values of the distribution. No significant trends of O3 are detected in the LS. Trends of CO in the UT, tropopause, and LS are almost all negative and statistically significant. The estimated slopes range from −1.37 to −0.59ppbyr−1, with a nearly homogeneous decrease in the lowest values of the monthly distribution (5th percentile) contrasting with the high interregional variability in the decrease in the highest values (95th percentile).

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Measurements of ozone and carbon monoxide were performed during 1994–2013 around the tropopause on board commercial aircraft. Seasonal cycles and trends were calculated above eight well-sampled regions in Northern Hemisphere midlatitudes. CO shows decreasing concentrations over the last 10 years, thus reflecting the impact of the legislation on anthropogenic emissions. Ozone amounts increased over the 20 years in the upper troposphere during different seasons, depending on the longitudes.
Measurements of ozone and carbon monoxide were performed during 1994–2013 around the tropopause...
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