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Volume 18, issue 8 | Copyright
Atmos. Chem. Phys., 18, 5371-5389, 2018
https://doi.org/10.5194/acp-18-5371-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 20 Apr 2018

Research article | 20 Apr 2018

Vertical distribution of aerosol optical properties in the Po Valley during the 2012 summer campaigns

Silvia Bucci1,2, Paolo Cristofanelli3, Stefano Decesari3, Angela Marinoni3, Silvia Sandrini3, Johannes Größ4, Alfred Wiedensohler4, Chiara F. Di Marco5, Eiko Nemitz5, Francesco Cairo1, Luca Di Liberto1, and Federico Fierli1 Silvia Bucci et al.
  • 1Institute for Atmospheric Sciences and Climate of the National Research Council, (ISAC-CNR), Rome, Italy
  • 2Sc Dept. of Physics, Ferrara University, Ferrara, Italy
  • 3Institute for Atmospheric Sciences and Climate of the National Research Council, (ISAC-CNR), Bologna, Italy
  • 4Leibniz Institute for Tropospheric Research, Leipzig, Germany
  • 5Natural Environment Research Council, Centre for Ecology & Hydrology, Penicuik, UK

Abstract. Studying the vertical distribution of aerosol particle physical and chemical properties in the troposphere is essential to understand the relative importance of local emission processes vs. long-range transport for column-integrated aerosol properties (e.g. the aerosol optical depth, AOD, affecting regional climate) as well as for the aerosol burden and its impacts on air quality at the ground. The main objective of this paper is to investigate the transport of desert dust in the middle troposphere and its intrusion into the planetary boundary layer (PBL) over the Po Valley (Italy), a region considered one of the greatest European pollution hotspots for the frequency that particulate matter (PM) limit values are exceeded. Events of mineral aerosol uplift from local (soil) sources and phenomena of hygroscopic growth at the ground are also investigated, possibly affecting the PM concentration in the region as well. During the PEGASOS 2012 field campaign, an integrated observing–modelling system was set up based on near-surface measurements (particle concentration and chemistry), vertical profiling (backscatter coefficient profiles from lidar and radiosoundings) and Lagrangian air mass transport simulations by FLEXPART model. Measurements were taken at the San Pietro Capofiume supersite (44°39′N, 11°37′E; 11ma.s.l.), located in a rural area relatively close to some major urban and industrial emissive areas in the Po Valley. Mt. Cimone (44°12′N, 10°42′E; 2165ma.s.l.) WMO/GAW station observations are also included in the study to characterize regional-scale variability. Results show that, in the Po Valley, aerosol is detected mainly below 2000ma.s.l. with a prevalent occurrence of non-depolarizing particles ( > 50% throughout the campaign) and a vertical distribution modulated by the PBL daily evolution. Two intense events of mineral dust transport from northern Africa (19–21 and 29 June to 2 July) are observed, with layers advected mainly above 2000m, but subsequently sinking and mixing in the PBL. As a consequence, a non-negligible occurrence of mineral dust is observed close to the ground ( ∼ 7% of occurrence during a 1-month campaign). The observations unambiguously show Saharan dust layers intruding the Po Valley mixing layer and directly affecting the aerosol concentrations near the surface. Finally, lidar observations also indicate strong variability in aerosol on shorter timescales (hourly). Firstly, these highlight events of hygroscopic growth of anthropogenic aerosol, visible as shallow layers of low depolarization near the ground. Such events are identified during early morning hours at high relative humidity (RH) conditions (RH > 80%). The process is observed concurrently with high PM1 nitrate concentration (up to 15µgcm−3) and hence mainly explicable by deliquescence of fine anthropogenic particles, and during mineral dust intrusion episodes, when water condensation on dust particles could instead represent the dominant contribution. Secondly, lidar images show frequent events (mean daily occurrence of  ∼ 22% during the whole campaign) of rapid uplift of mineral depolarizing particles in afternoon–evening hours up to 2000ma.s.l. height. The origin of such particles cannot be directly related to long-range transport events, being instead likely linked to processes of soil particle resuspension from agricultural lands.

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This paper analyses some of the processes affecting PM levels over the Po Valley, one of the most polluted regions of Europe, during the 2012 summer campaigns. Under conditions of air transport from the Sahara, data show that desert dust can rapidly penetrate into the lower atmosphere, directly affecting the PM concentration at the ground. Processes of particles growth in high relative humidity and uplift of local soil particles, potentially affecting PM level, are also analysed.
This paper analyses some of the processes affecting PM levels over the Po Valley, one of the...
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