Articles | Volume 18, issue 5
https://doi.org/10.5194/acp-18-3799-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-3799-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
15 Mar 2018
Research article |
| 15 Mar 2018
| 15 Mar 2018
Direct measurement of NO3 radical reactivity in a boreal forest
Jonathan Liebmann
Division of Atmospheric Chemistry, Max Planck Institut für Chemie, 55128, Mainz, Germany
Einar Karu
Division of Atmospheric Chemistry, Max Planck Institut für Chemie, 55128, Mainz, Germany
Nicolas Sobanski
Division of Atmospheric Chemistry, Max Planck Institut für Chemie, 55128, Mainz, Germany
Jan Schuladen
Division of Atmospheric Chemistry, Max Planck Institut für Chemie, 55128, Mainz, Germany
Mikael Ehn
Department of Physics, University of Helsinki, 00140, Helsinki, Finland
Simon Schallhart
Department of Physics, University of Helsinki, 00140, Helsinki, Finland
Lauriane Quéléver
Department of Physics, University of Helsinki, 00140, Helsinki, Finland
Heidi Hellen
Finnish Meteorological Institute, 00560, Helsinki, Finland
Hannele Hakola
Finnish Meteorological Institute, 00560, Helsinki, Finland
Thorsten Hoffmann
Johannes Gutenberg University, 55128, Mainz, Germany
Jonathan Williams
Division of Atmospheric Chemistry, Max Planck Institut für Chemie, 55128, Mainz, Germany
Horst Fischer
Division of Atmospheric Chemistry, Max Planck Institut für Chemie, 55128, Mainz, Germany
Jos Lelieveld
Division of Atmospheric Chemistry, Max Planck Institut für Chemie, 55128, Mainz, Germany
Division of Atmospheric Chemistry, Max Planck Institut für Chemie, 55128, Mainz, Germany
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39 citations as recorded by crossref.
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- Impact of temperature-dependent non-PAN peroxynitrate formation, RO2NO2, on nighttime atmospheric chemistry M. Färber et al. 10.1039/D3CP04163H
- A modelling study of OH, NO3 and H2SO4 in 2007–2018 at SMEAR II, Finland: analysis of long-term trends D. Chen et al. 10.1039/D1EA00020A
- Long-term total OH reactivity measurements in a boreal forest A. Praplan et al. 10.5194/acp-19-14431-2019
- NO3 reactivity measurements in an indoor environment: a pilot study P. Dewald et al. 10.1039/D3EA00137G
- Simulation model of Reactive Nitrogen Species in an Urban Atmosphere using a Deep Neural Network: RNDv1.0 J. Gil et al. 10.5194/gmd-16-5251-2023
- Budgets of Organic Carbon Composition and Oxidation in Indoor Air D. Price et al. 10.1021/acs.est.9b04689
- Observation and modeling of organic nitrates on a suburban site in southwest China C. Li et al. 10.1016/j.scitotenv.2022.160287
- Long-term measurements of volatile organic compounds highlight the importance of sesquiterpenes for the atmospheric chemistry of a boreal forest H. Hellén et al. 10.5194/acp-18-13839-2018
- Oxidation of Catechols at the Air–Water Interface by Nitrate Radicals M. Rana & M. Guzman 10.1021/acs.est.2c05640
- Investigation of Isoprene Dynamics During the Day‐to‐Night Transition Period D. Wei et al. 10.1029/2020JD032784
- Foliar behaviour of biogenic semi-volatiles: potential applications in sustainable pest management A. Mofikoya et al. 10.1007/s11829-019-09676-1
- Low levels of nitryl chloride at ground level: nocturnal nitrogen oxides in the Lower Fraser Valley of British Columbia H. Osthoff et al. 10.5194/acp-18-6293-2018
- Insights into HO<sub><i>x</i></sub> and RO<sub><i>x</i></sub> chemistry in the boreal forest via measurement of peroxyacetic acid, peroxyacetic nitric anhydride (PAN) and hydrogen peroxide J. Crowley et al. 10.5194/acp-18-13457-2018
- Importance of secondary organic aerosol formation of <i>α</i>-pinene, limonene, and <i>m</i>-cresol comparing day- and nighttime radical chemistry A. Mutzel et al. 10.5194/acp-21-8479-2021
- Emission of volatile organic compounds from residential biomass burning and their rapid chemical transformations M. Desservettaz et al. 10.1016/j.scitotenv.2023.166592
- Pyruvic acid in the boreal forest: gas-phase mixing ratios and impact on radical chemistry P. Eger et al. 10.5194/acp-20-3697-2020
- Impact of pyruvic acid photolysis on acetaldehyde and peroxy radical formation in the boreal forest: theoretical calculations and model results P. Eger et al. 10.5194/acp-21-14333-2021
- Vertically increased NO3 radical in the nocturnal boundary layer Y. Yan et al. 10.1016/j.scitotenv.2020.142969
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- Atmospheric reactivity and oxidation capacity during summer at a suburban site between Beijing and Tianjin Y. Yang et al. 10.5194/acp-20-8181-2020
- Abundance of NO3 Derived Organo-Nitrates and Their Importance in the Atmosphere A. Foulds et al. 10.3390/atmos12111381
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- Semi-volatile and highly oxygenated gaseous and particulate organic compounds observed above a boreal forest canopy B. Lee et al. 10.5194/acp-18-11547-2018
- Chemical ionization quadrupole mass spectrometer with an electrical discharge ion source for atmospheric trace gas measurement P. Eger et al. 10.5194/amt-12-1935-2019
- Sesquiterpenes dominate monoterpenes in northern wetland emissions H. Hellén et al. 10.5194/acp-20-7021-2020
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- Evolution of NO<sub>3</sub> reactivity during the oxidation of isoprene P. Dewald et al. 10.5194/acp-20-10459-2020
- Experimental budgets of OH, HO<sub>2</sub>, and RO<sub>2</sub> radicals and implications for ozone formation in the Pearl River Delta in China 2014 Z. Tan et al. 10.5194/acp-19-7129-2019
- Reactive quenching of electronically excited NO<sub>2</sub><sup>∗</sup> and NO<sub>3</sub><sup>∗</sup> by H<sub>2</sub>O as potential sources of atmospheric HO<sub><i>x</i></sub> radicals T. Dillon & J. Crowley 10.5194/acp-18-14005-2018
- Measurements of total ozone reactivity in a suburban forest in Japan J. Matsumoto 10.1016/j.atmosenv.2020.117990
- Detecting and Characterizing Particulate Organic Nitrates with an Aerodyne Long-ToF Aerosol Mass Spectrometer F. Graeffe et al. 10.1021/acsearthspacechem.2c00314
- Theoretical and experimental study of peroxy and alkoxy radicals in the NO3-initiated oxidation of isoprene L. Vereecken et al. 10.1039/D0CP06267G
- Evaluation of the Environmental Fate of a Semivolatile Transformation Product of Ibuprofen Based on a Simple Two-Media Fate Model C. Arsene et al. 10.1021/acs.est.2c04867
- Measurement report: Atmospheric nitrate radical chemistry in the South China Sea influenced by the urban outflow of the Pearl River Delta J. Wang et al. 10.5194/acp-24-977-2024
- Atomic emission detector with gas chromatographic separation and cryogenic pre-concentration (CryoTrap–GC–AED) for atmospheric trace gas measurements E. Karu et al. 10.5194/amt-14-1817-2021
- Variation and trend of nitrate radical reactivity towards volatile organic compounds in Beijing, China H. Hu et al. 10.5194/acp-23-8211-2023
- Insights into atmospheric oxidation processes by performing factor analyses on subranges of mass spectra Y. Zhang et al. 10.5194/acp-20-5945-2020
39 citations as recorded by crossref.
- On the fate of oxygenated organic molecules in atmospheric aerosol particles V. Pospisilova et al. 10.1126/sciadv.aax8922
- Characterizing nitrate radical budget trends in Beijing during 2013–2019 H. Wang et al. 10.1016/j.scitotenv.2021.148869
- Impact of temperature-dependent non-PAN peroxynitrate formation, RO2NO2, on nighttime atmospheric chemistry M. Färber et al. 10.1039/D3CP04163H
- A modelling study of OH, NO3 and H2SO4 in 2007–2018 at SMEAR II, Finland: analysis of long-term trends D. Chen et al. 10.1039/D1EA00020A
- Long-term total OH reactivity measurements in a boreal forest A. Praplan et al. 10.5194/acp-19-14431-2019
- NO3 reactivity measurements in an indoor environment: a pilot study P. Dewald et al. 10.1039/D3EA00137G
- Simulation model of Reactive Nitrogen Species in an Urban Atmosphere using a Deep Neural Network: RNDv1.0 J. Gil et al. 10.5194/gmd-16-5251-2023
- Budgets of Organic Carbon Composition and Oxidation in Indoor Air D. Price et al. 10.1021/acs.est.9b04689
- Observation and modeling of organic nitrates on a suburban site in southwest China C. Li et al. 10.1016/j.scitotenv.2022.160287
- Long-term measurements of volatile organic compounds highlight the importance of sesquiterpenes for the atmospheric chemistry of a boreal forest H. Hellén et al. 10.5194/acp-18-13839-2018
- Oxidation of Catechols at the Air–Water Interface by Nitrate Radicals M. Rana & M. Guzman 10.1021/acs.est.2c05640
- Investigation of Isoprene Dynamics During the Day‐to‐Night Transition Period D. Wei et al. 10.1029/2020JD032784
- Foliar behaviour of biogenic semi-volatiles: potential applications in sustainable pest management A. Mofikoya et al. 10.1007/s11829-019-09676-1
- Low levels of nitryl chloride at ground level: nocturnal nitrogen oxides in the Lower Fraser Valley of British Columbia H. Osthoff et al. 10.5194/acp-18-6293-2018
- Insights into HO<sub><i>x</i></sub> and RO<sub><i>x</i></sub> chemistry in the boreal forest via measurement of peroxyacetic acid, peroxyacetic nitric anhydride (PAN) and hydrogen peroxide J. Crowley et al. 10.5194/acp-18-13457-2018
- Importance of secondary organic aerosol formation of <i>α</i>-pinene, limonene, and <i>m</i>-cresol comparing day- and nighttime radical chemistry A. Mutzel et al. 10.5194/acp-21-8479-2021
- Emission of volatile organic compounds from residential biomass burning and their rapid chemical transformations M. Desservettaz et al. 10.1016/j.scitotenv.2023.166592
- Pyruvic acid in the boreal forest: gas-phase mixing ratios and impact on radical chemistry P. Eger et al. 10.5194/acp-20-3697-2020
- Impact of pyruvic acid photolysis on acetaldehyde and peroxy radical formation in the boreal forest: theoretical calculations and model results P. Eger et al. 10.5194/acp-21-14333-2021
- Vertically increased NO3 radical in the nocturnal boundary layer Y. Yan et al. 10.1016/j.scitotenv.2020.142969
- Fate of the nitrate radical at the summit of a semi-rural mountain site in Germany assessed with direct reactivity measurements P. Dewald et al. 10.5194/acp-22-7051-2022
- Atmospheric reactivity and oxidation capacity during summer at a suburban site between Beijing and Tianjin Y. Yang et al. 10.5194/acp-20-8181-2020
- Abundance of NO3 Derived Organo-Nitrates and Their Importance in the Atmosphere A. Foulds et al. 10.3390/atmos12111381
- Alkyl nitrates in the boreal forest: formation via the NO<sub>3</sub>-, OH- and O<sub>3</sub>-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Semi-volatile and highly oxygenated gaseous and particulate organic compounds observed above a boreal forest canopy B. Lee et al. 10.5194/acp-18-11547-2018
- Chemical ionization quadrupole mass spectrometer with an electrical discharge ion source for atmospheric trace gas measurement P. Eger et al. 10.5194/amt-12-1935-2019
- Sesquiterpenes dominate monoterpenes in northern wetland emissions H. Hellén et al. 10.5194/acp-20-7021-2020
- Direct measurements of NO<sub>3</sub> reactivity in and above the boundary layer of a mountaintop site: identification of reactive trace gases and comparison with OH reactivity J. Liebmann et al. 10.5194/acp-18-12045-2018
- Evolution of NO<sub>3</sub> reactivity during the oxidation of isoprene P. Dewald et al. 10.5194/acp-20-10459-2020
- Experimental budgets of OH, HO<sub>2</sub>, and RO<sub>2</sub> radicals and implications for ozone formation in the Pearl River Delta in China 2014 Z. Tan et al. 10.5194/acp-19-7129-2019
- Reactive quenching of electronically excited NO<sub>2</sub><sup>∗</sup> and NO<sub>3</sub><sup>∗</sup> by H<sub>2</sub>O as potential sources of atmospheric HO<sub><i>x</i></sub> radicals T. Dillon & J. Crowley 10.5194/acp-18-14005-2018
- Measurements of total ozone reactivity in a suburban forest in Japan J. Matsumoto 10.1016/j.atmosenv.2020.117990
- Detecting and Characterizing Particulate Organic Nitrates with an Aerodyne Long-ToF Aerosol Mass Spectrometer F. Graeffe et al. 10.1021/acsearthspacechem.2c00314
- Theoretical and experimental study of peroxy and alkoxy radicals in the NO3-initiated oxidation of isoprene L. Vereecken et al. 10.1039/D0CP06267G
- Evaluation of the Environmental Fate of a Semivolatile Transformation Product of Ibuprofen Based on a Simple Two-Media Fate Model C. Arsene et al. 10.1021/acs.est.2c04867
- Measurement report: Atmospheric nitrate radical chemistry in the South China Sea influenced by the urban outflow of the Pearl River Delta J. Wang et al. 10.5194/acp-24-977-2024
- Atomic emission detector with gas chromatographic separation and cryogenic pre-concentration (CryoTrap–GC–AED) for atmospheric trace gas measurements E. Karu et al. 10.5194/amt-14-1817-2021
- Variation and trend of nitrate radical reactivity towards volatile organic compounds in Beijing, China H. Hu et al. 10.5194/acp-23-8211-2023
- Insights into atmospheric oxidation processes by performing factor analyses on subranges of mass spectra Y. Zhang et al. 10.5194/acp-20-5945-2020
Latest update: 19 Apr 2024
Short summary
Using a newly developed experimental setup, we have made the first direct measurements (during autumn 2016) of NO3 reactivity in the Finnish boreal forest. The NO3 reactivity was generally very high (maximum value of 0.94/s) so that daytime reaction with organics was a substantial fraction of the NO3 loss. Observations of biogenic hydrocarbons (BVOCs) suggested a dominant role for monoterpenes in determining the NO3 reactivity, which displayed a strong vertical gradient between 8.5 and 25 m.
Using a newly developed experimental setup, we have made the first direct measurements (during...
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