Articles | Volume 18, issue 5
https://doi.org/10.5194/acp-18-3299-2018
https://doi.org/10.5194/acp-18-3299-2018
Research article
 | 
07 Mar 2018
Research article |  | 07 Mar 2018

Non-methane organic gas emissions from biomass burning: identification, quantification, and emission factors from PTR-ToF during the FIREX 2016 laboratory experiment

Abigail R. Koss, Kanako Sekimoto, Jessica B. Gilman, Vanessa Selimovic, Matthew M. Coggon, Kyle J. Zarzana, Bin Yuan, Brian M. Lerner, Steven S. Brown, Jose L. Jimenez, Jordan Krechmer, James M. Roberts, Carsten Warneke, Robert J. Yokelson, and Joost de Gouw

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Cited articles

Akagi, S. K., Yokelson, R. J., Wiedinmyer, C., Alvarado, M. J., Reid, J. S., Karl, T., Crounse, J. D., and Wennberg, P. O.: Emission factors for open and domestic biomass burning for use in atmospheric models, Atmos. Chem. Phys., 11, 4039–4072, https://doi.org/10.5194/acp-11-4039-2011, 2011. 
Alvarado, M. J., Wang, C., and Prinn, R. G.: Formation of ozone and growth of aerosols in young smoke plumes from biomass burning: 2. Three-dimensional Eulerian studies, J. Geophys. Res., 114, D09307, https://doi.org/10.1029/2008jd011186, 2009. 
Alvarado, M. J., Lonsdale, C. R., Yokelson, R. J., Akagi, S. K., Coe, H., Craven, J. S., Fischer, E. V., McMeeking, G. R., Seinfeld, J. H., Soni, T., Taylor, J. W., Weise, D. R., and Wold, C. E.: Investigating the links between ozone and organic aerosol chemistry in a biomass burning plume from a prescribed fire in California chaparral, Atmos. Chem. Phys., 15, 6667–6688, https://doi.org/10.5194/acp-15-6667-2015, 2015. 
Breitenlechner, M., Fischer, L., Hainer, M., Heinritzi, M., Curtius, J., and Hansel, A.: PTR3: an instrument for studying the lifecycle of reactive organic carbon in the atmosphere, Anal. Chem., 89, 5824–5831, https://doi.org/10.1021/acs.analchem.6b05110, 2017. 
Brilli, F., Gioli, B., Ciccioli, P., Zona, D., Loreto, F., Janssens, I. A., and Ceulemans, R.: Proton Transfer Reaction Time-of-Flight Mass Spectrometric (PTR-TOF-MS) determination of volatile organic compounds (VOCs) emitted from a biomass fire developed under stable nocturnal conditions, Atmos. Environ., 97, 54–67, https://doi.org/10.1016/j.atmosenv.2014.08.007, 2014. 
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Short summary
Non-methane organic gases (NMOGs) were detected by proton-transfer-reaction mass spectrometry (PTR-ToF) during an extensive laboratory characterization of wildfire emissions. Identifications for PTR-ToF ion masses are proposed and supported by a combination of techniques. Overall excellent agreement with other instrumentation is shown. Scalable emission factors and ratios are reported for many newly reported reactive species. An analysis of chemical characteristics is presented.
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