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Volume 18, issue 4
Atmos. Chem. Phys., 18, 2381–2394, 2018
https://doi.org/10.5194/acp-18-2381-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 18, 2381–2394, 2018
https://doi.org/10.5194/acp-18-2381-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 19 Feb 2018

Research article | 19 Feb 2018

Temperature-(208–318 K) and pressure-(18–696 Torr) dependent rate coefficients for the reaction between OH and HNO3

Katrin Dulitz et al.

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Cited articles

Aloisio, S. and Francisco, J. S.: Structure and energetics of hydrogen bonded HOX-HNO3 complexes, J. Phys. Chem. A, 103, 6049–6053, 1999.
Atkinson, R., Baulch, D. L., Cox, R. A., Crowley, J. N., Hampson, R. F., Hynes, R. G., Jenkin, M. E., Rossi, M. J., and Troe, J.: Evaluated kinetic and photochemical data for atmospheric chemistry: volume I – gas phase reactions of Ox, HOx, NOxand SOx species, Atmos. Chem. Phys., 4, 1461–1738, https://doi.org/10.5194/acp-4-1461-2004, 2004.
Biaume, F.: Nitric acid vapour absorption cross-section spectrum and its photodissociation in the stratosphere, J. Photochem., 2, 139–149, 1973–1974.
Bogumil, K., Orphal, J., Homann, T., Voigt, S., Spietz, P., Fleischmann, O. C., Vogel, A., Hartmann, M., Kromminga, H., Bovensmann, H., Frerick, J., and Burrows, J. P.: Measurements of molecular absorption spectra with the SCIAMACHY pre-flight model: instrument characterization and reference data for atmospheric remote-sensing in the 230–2380 nm region, J. Photochem. Photobiol. A, 157, 167–184, https://doi.org/10.1016/s1010-6030(03)00062-5, 2003.
Brown, S. S., Talukdar, R. K., and Ravishankara, A. R.: Reconsideration of the rate constant for the reaction of hydroxyl radicals with nitric acid, J. Phys. Chem.-US, 103, 3031–3037, 1999.
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The reaction between the OH radical and HNO3 represents an important route for the release of NOx (NO and NO2) from HNO3, the most important NOx reservoir in many parts of the atmosphere. In our laboratory study, we have generated an extensive, high-quality set of rate coefficients for this reaction at different temperatures and pressures and used these to derive a new parameterisation of the rate coefficient for atmospheric modelling.
The reaction between the OH radical and HNO3 represents an important route for the release of...
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