Articles | Volume 18, issue 4
https://doi.org/10.5194/acp-18-2381-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-2381-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
19 Feb 2018
Research article |
| 19 Feb 2018
| 19 Feb 2018
Temperature-(208–318 K) and pressure-(18–696 Torr) dependent rate coefficients for the reaction between OH and HNO3
Katrin Dulitz
CORRESPONDING AUTHOR
Division of Atmospheric Chemistry, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
now at: Institute of Physics, University of Freiburg, 79104 Freiburg, Germany
Damien Amedro
Division of Atmospheric Chemistry, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
Terry J. Dillon
Division of Atmospheric Chemistry, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
now at: Department of Chemistry, University of York, York, UK
Andrea Pozzer
Division of Atmospheric Chemistry, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
John N. Crowley
Division of Atmospheric Chemistry, Max-Planck-Institut für Chemie, 55128 Mainz, Germany
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Cited
16 citations as recorded by crossref.
- Quantification of nitric acid using photolysis induced fluorescence for use in chemical kinetic studies F. Winiberg et al. 10.1016/j.cpletx.2019.100029
- Kinetics of the OH + NO<sub>2</sub> reaction: rate coefficients (217–333 K, 16–1200 mbar) and fall-off parameters for N<sub>2</sub> and O<sub>2</sub> bath gases D. Amedro et al. 10.5194/acp-19-10643-2019
- Reactivity of Undissociated Molecular Nitric Acid at the Air–Water Interface J. Anglada et al. 10.1021/jacs.0c11841
- Background nitrogen dioxide (NO2) over the United States and its implications for satellite observations and trends: effects of nitrate photolysis, aircraft, and open fires R. Dang et al. 10.5194/acp-23-6271-2023
- Iodide CIMS and <i>m</i>∕<i>z</i> 62: the detection of HNO<sub>3</sub> as NO<sub>3</sub><sup>−</sup> in the presence of PAN, peroxyacetic acid and ozone R. Dörich et al. 10.5194/amt-14-5319-2021
- Reactive quenching of electronically excited NO<sub>2</sub><sup>∗</sup> and NO<sub>3</sub><sup>∗</sup> by H<sub>2</sub>O as potential sources of atmospheric HO<sub><i>x</i></sub> radicals T. Dillon & J. Crowley 10.5194/acp-18-14005-2018
- Kinetics of the OH + NO<sub>2</sub> reaction: effect of water vapour and new parameterization for global modelling D. Amedro et al. 10.5194/acp-20-3091-2020
- Measurement of NO<sub><i>x</i></sub> and NO<sub><i>y</i></sub> with a thermal dissociation cavity ring-down spectrometer (TD-CRDS): instrument characterisation and first deployment N. Friedrich et al. 10.5194/amt-13-5739-2020
- Constraints on Aerosol Nitrate Photolysis as a Potential Source of HONO and NOx P. Romer et al. 10.1021/acs.est.8b03861
- Disproportionation Channel of the Self-reaction of Hydroxyl Radical, OH + OH → H2O + O, Revisited X. Zhang et al. 10.1021/acs.jpca.0c00624
- Impacts of updated reaction kinetics on the global GEOS-Chem simulation of atmospheric chemistry K. Bates et al. 10.5194/gmd-17-1511-2024
- Pressure-Dependent Rate Constant Caused by Tunneling Effects: OH + HNO3 as an Example T. Nguyen & J. Stanton 10.1021/acs.jpclett.0c00733
- Characterization of two photon excited fragment spectroscopy (TPEFS) for HNO3detection in gas-phase kinetic experiments D. Amedro et al. 10.1039/D1CP00297J
- Kinetics and pressure-dependent HOx yields of the reaction between the Criegee intermediate CH2OO and HNO3 P. Luo 10.1039/D2CP03660F
- Kinetics of OH + SO<sub>2</sub> + M: temperature-dependent rate coefficients in the fall-off regime and the influence of water vapour W. Sun et al. 10.5194/acp-22-4969-2022
- Reaction kinetics of OH + HNO3 under conditions relevant to the upper troposphere/lower stratosphere F. Winiberg et al. 10.1039/C8CP04193H
15 citations as recorded by crossref.
- Quantification of nitric acid using photolysis induced fluorescence for use in chemical kinetic studies F. Winiberg et al. 10.1016/j.cpletx.2019.100029
- Kinetics of the OH + NO<sub>2</sub> reaction: rate coefficients (217–333 K, 16–1200 mbar) and fall-off parameters for N<sub>2</sub> and O<sub>2</sub> bath gases D. Amedro et al. 10.5194/acp-19-10643-2019
- Reactivity of Undissociated Molecular Nitric Acid at the Air–Water Interface J. Anglada et al. 10.1021/jacs.0c11841
- Background nitrogen dioxide (NO2) over the United States and its implications for satellite observations and trends: effects of nitrate photolysis, aircraft, and open fires R. Dang et al. 10.5194/acp-23-6271-2023
- Iodide CIMS and <i>m</i>∕<i>z</i> 62: the detection of HNO<sub>3</sub> as NO<sub>3</sub><sup>−</sup> in the presence of PAN, peroxyacetic acid and ozone R. Dörich et al. 10.5194/amt-14-5319-2021
- Reactive quenching of electronically excited NO<sub>2</sub><sup>∗</sup> and NO<sub>3</sub><sup>∗</sup> by H<sub>2</sub>O as potential sources of atmospheric HO<sub><i>x</i></sub> radicals T. Dillon & J. Crowley 10.5194/acp-18-14005-2018
- Kinetics of the OH + NO<sub>2</sub> reaction: effect of water vapour and new parameterization for global modelling D. Amedro et al. 10.5194/acp-20-3091-2020
- Measurement of NO<sub><i>x</i></sub> and NO<sub><i>y</i></sub> with a thermal dissociation cavity ring-down spectrometer (TD-CRDS): instrument characterisation and first deployment N. Friedrich et al. 10.5194/amt-13-5739-2020
- Constraints on Aerosol Nitrate Photolysis as a Potential Source of HONO and NOx P. Romer et al. 10.1021/acs.est.8b03861
- Disproportionation Channel of the Self-reaction of Hydroxyl Radical, OH + OH → H2O + O, Revisited X. Zhang et al. 10.1021/acs.jpca.0c00624
- Impacts of updated reaction kinetics on the global GEOS-Chem simulation of atmospheric chemistry K. Bates et al. 10.5194/gmd-17-1511-2024
- Pressure-Dependent Rate Constant Caused by Tunneling Effects: OH + HNO3 as an Example T. Nguyen & J. Stanton 10.1021/acs.jpclett.0c00733
- Characterization of two photon excited fragment spectroscopy (TPEFS) for HNO3detection in gas-phase kinetic experiments D. Amedro et al. 10.1039/D1CP00297J
- Kinetics and pressure-dependent HOx yields of the reaction between the Criegee intermediate CH2OO and HNO3 P. Luo 10.1039/D2CP03660F
- Kinetics of OH + SO<sub>2</sub> + M: temperature-dependent rate coefficients in the fall-off regime and the influence of water vapour W. Sun et al. 10.5194/acp-22-4969-2022
1 citations as recorded by crossref.
Latest update: 07 May 2024
Short summary
The reaction between the OH radical and HNO3 represents an important route for the release of NOx (NO and NO2) from HNO3, the most important NOx reservoir in many parts of the atmosphere. In our laboratory study, we have generated an extensive, high-quality set of rate coefficients for this reaction at different temperatures and pressures and used these to derive a new parameterisation of the rate coefficient for atmospheric modelling.
The reaction between the OH radical and HNO3 represents an important route for the release of...
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