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Volume 18, issue 3
Atmos. Chem. Phys., 18, 1909–1921, 2018
https://doi.org/10.5194/acp-18-1909-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 18, 1909–1921, 2018
https://doi.org/10.5194/acp-18-1909-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 09 Feb 2018

Research article | 09 Feb 2018

Formation of highly oxygenated organic molecules from aromatic compounds

Ugo Molteni et al.

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Cited articles

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Baltaretu, C. O., Lichtman, E. I., Hadler, A. B., and Elrod, M. J.: Primary atmospheric oxidation mechanism for toluene, J. Phys. Chem. A, 113, 221–230, https://doi.org/10.1021/jp806841t, 2009.
Barmet, P., Dommen, J., DeCarlo, P. F., Tritscher, T., Praplan, A. P., Platt, S. M., Prévôt, A. S. H., Donahue, N. M., and Baltensperger, U.: OH clock determination by proton transfer reaction mass spectrometry at an environmental chamber, Atmos. Meas. Tech., 5, 647–656, https://doi.org/10.5194/amt-5-647-2012, 2012.
Bartels-Rausch, T., Ulrich, T., Huthwelker, T., and Ammann, M.: A novel synthesis of the N-13 labeled atmospheric trace gas peroxynitric acid, Radiochim. Acta, 99, 285–292, https://doi.org/10.1524/ract.2011.1830, 2011.
Berndt, T., Richters, S., Kaethner, R., Voigtländer, J., Stratmann, F., Sipilä, M., Kulmala, M., and Herrmann, H.: Gas-phase ozonolysis of cycloalkenes: formation of highly oxidized RO2 radicals and their reactions with NO, NO2, SO2 and other RO2 radicals, J. Phys. Chem. A, 119, 10336–10348, https://doi.org/10.1021/acs.jpca.5b07295, 2015.
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Anthropogenic volatile organic compounds often dominate the urban atmosphere and consist to a large degree of aromatics. These compounds are already known as important precursors for the formation of secondary organic aerosol. This study shows how the oxidation of aromatics with an OH radical leads to subsequent autoxidation chain reactions forming highly oxygenated molecules. We hypothesize that these may contribute substantially to new particle formation events detected in urban areas.
Anthropogenic volatile organic compounds often dominate the urban atmosphere and consist to a...
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