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ACP | Articles | Volume 18, issue 24
Atmos. Chem. Phys., 18, 17801–17817, 2018
https://doi.org/10.5194/acp-18-17801-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 18, 17801–17817, 2018
https://doi.org/10.5194/acp-18-17801-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 14 Dec 2018

Research article | 14 Dec 2018

Measurements of I/SVOCs in biomass-burning smoke using solid-phase extraction disks and two-dimensional gas chromatography

Lindsay E. Hatch et al.

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Akagi, S. K., Yokelson, R. J., Wiedinmyer, C., Alvarado, M. J., Reid, J. S., Karl, T., Crounse, J. D., and Wennberg, P. O.: Emission factors for open and domestic biomass burning for use in atmospheric models, Atmos. Chem. Phys., 11, 4039–4072, https://doi.org/10.5194/acp-11-4039-2011, 2011. 
Akagi, S. K., Craven, J. S., Taylor, J. W., McMeeking, G. R., Yokelson, R. J., Burling, I. R., Urbanski, S. P., Wold, C. E., Seinfeld, J. H., Coe, H., Alvarado, M. J., and Weise, D. R.: Evolution of trace gases and particles emitted by a chaparral fire in California, Atmos. Chem. Phys., 12, 1397–1421, https://doi.org/10.5194/acp-12-1397-2012, 2012. 
Andreae, M. O. and Merlet, P.: Emission of trace gases and aerosols from biomass burning, Global Biogeochem. Cy., 15, 955–966, 2001. 
Bian, Q., Jathar, S. H., Kodros, J. K., Barsanti, K. C., Hatch, L. E., May, A. A., Kreidenweis, S. M., and Pierce, J. R.: Secondary organic aerosol formation in biomass-burning plumes: theoretical analysis of lab studies and ambient plumes, Atmos. Chem. Phys., 17, 5459–5475, https://doi.org/10.5194/acp-17-5459-2017, 2017. 
Bond, T. C., Streets, D. G., Yarber, K. F., Nelson, S. M., Woo, J. H., and Klimont, Z.: A technology-based global inventory of black and organic carbon emissions from combustion, J. Geophys. Res.-Atmos., 109, D14203, https://doi.org/10.1029/2003jd003697, 2004. 
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We demonstrate the use of solid-phase extraction (SPE) disks for the untargeted analysis of gas-phase intermediate volatility and semi-volatile organic compounds emitted from biomass burning. SPE and Teflon filter samples collected from laboratory fires were analyzed by two-dimensional gas chromatography, with distinct differences in the observed chromatographic profiles as a function of fuel type. Fuel-dependent emissions and volatility differences among benzenediol isomers were captured.
We demonstrate the use of solid-phase extraction (SPE) disks for the untargeted analysis of...
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