Articles | Volume 18, issue 21
https://doi.org/10.5194/acp-18-15903-2018
https://doi.org/10.5194/acp-18-15903-2018
Research article
 | 
07 Nov 2018
Research article |  | 07 Nov 2018

The influence of HCl on the evaporation rates of H2O over water ice in the range 188 to 210 K at small average concentrations

Christophe Delval and Michel J. Rossi

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Cited articles

Abbatt, J. P. D.: Interaction of HNO3 with water-ice surface at temperatures of the free troposphere, Geophys Res. Lett., 24, 1479–1482, 1997. 
Abbatt, J. P. D.: Interactions of atmospheric trace gases with ice surfaces: Adsorption and reactions, Chem. Rev., 103, 4783–4800, 2003. 
Abbatt, J. P. D., Beyer, K. D., Fucaloro, A. F., McMahon, J. R., Wooldridge, P. J., Zhang, R., and Molina, M. J.: Interaction of HCl vapor with water ice: implications for the stratosphere, J. Geophys. Res., 97, 15819–15826, 1992. 
Banham, S. F., Horn, A. B., Koch, T. G., and Sodeau, J. R.: Ionisation and solvation of stratospherically relevant molecules on ice films, Faraday Discuss., 100, 321–332, 1995. 
Biermann, U., Crowley, J. N., Huthwelker, T., Moortgat, G. K., Crutzen, P. J., and Peter, T.: FTIR studies on lifetime prolongation of stratospheric ice particles due to NAT coating, Geophys. Res. Lett., 25, 3939–3942, 1998. 
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Short summary
Evaporation rates of H2O and HCl were observed from a thin film condensate at low temperature at an average HCl mole fraction of 10(−5)–10(−3) in order to probe the evaporative lifetime of ice particles of the upper troposphere and lower stratosphere. The results show a decrease in the H2O evaporation rate with increasing mass loss of the condensate under conditions where the saturation vapor pressure corresponded to pure ice. This supports gas–surface reactions of HCl-doped ice particles.
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