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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
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Volume 18, issue 17
Atmos. Chem. Phys., 18, 13013–13030, 2018
https://doi.org/10.5194/acp-18-13013-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 18, 13013–13030, 2018
https://doi.org/10.5194/acp-18-13013-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Research article 11 Sep 2018

Research article | 11 Sep 2018

Chlorine oxidation of VOCs at a semi-rural site in Beijing: significant chlorine liberation from ClNO2 and subsequent gas- and particle-phase Cl–VOC production

Michael Le Breton et al.
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Status: closed
Status: closed
AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment
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Peer review completion
AR: Author's response | RR: Referee report | ED: Editor decision
AR by Anna Wenzel on behalf of the Authors (04 May 2018)  Author's response
ED: Referee Nomination & Report Request started (06 May 2018) by Steven Brown
RR by Anonymous Referee #2 (16 May 2018)
RR by Anonymous Referee #1 (21 May 2018)
ED: Reconsider after major revisions (26 May 2018) by Steven Brown
AR by Michael Le breton on behalf of the Authors (04 Aug 2018)  Author's response    Manuscript
ED: Referee Nomination & Report Request started (11 Aug 2018) by Steven Brown
RR by Anonymous Referee #2 (20 Aug 2018)
ED: Publish subject to technical corrections (21 Aug 2018) by Steven Brown
AR by Michael Le breton on behalf of the Authors (24 Aug 2018)  Author's response    Manuscript
Publications Copernicus
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Short summary
We apply state-of-the-art chemical characterization to determine the chloride radical production in Beijing via measurement of inorganic halogens at a semi-rural site. The high concentration of inorganic halogens, namely nitryl chloride, enables the production of chlorinated volatile organic compounds which are measured in both the gas and particle phases simultaneously. This enables the secondary production of aerosols via chlorine oxidation to be directly observed in ambient air.
We apply state-of-the-art chemical characterization to determine the chloride radical production...
Citation