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Volume 17, issue 16 | Copyright

Special issue: Global and regional assessment of intercontinental transport...

Atmos. Chem. Phys., 17, 9931-9943, 2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 24 Aug 2017

Research article | 24 Aug 2017

Modeling intercontinental transport of ozone in North America with CAMx for the Air Quality Model Evaluation International Initiative (AQMEII) Phase 3

Uarporn Nopmongcol, Zhen Liu, Till Stoeckenius, and Greg Yarwood Uarporn Nopmongcol et al.
  • Ramboll Environ, 773 San Marin Dr., Suite 2115, Novato, CA 94945, USA

Abstract. Intercontinental ozone (O3) transport extends the geographic range of O3 air pollution impacts and makes local air pollution management more difficult. Phase 3 of the Air Quality Modeling Evaluation International Initiative (AQMEII-3) is examining the contribution of intercontinental transport to regional air quality by applying regional-scale atmospheric models jointly with global models. We investigate methods for tracing O3 from global models within regional models. The CAMx photochemical grid model was used to track contributions from boundary condition (BC) O3 over a North American modeling domain for calendar year 2010 using a built-in tracer module called RTCMC. RTCMC can track BC contributions using chemically reactive tracers and also using inert tracers in which deposition is the only sink for O3. Lack of O3 destruction chemistry in the inert tracer approach leads to overestimation biases that can exceed 10ppb. The flexibility of RTCMC also allows tracking O3 contributions made by groups of vertical BC layers. The largest BC contributions to seasonal average daily maximum 8h averages (MDA8) of O3 over the US are found to be from the mid-troposphere (over 40ppb) with small contributions (a few ppb) from the upper troposphere–lower stratosphere. Contributions from the lower troposphere are shown to not penetrate very far inland. Higher contributions in the western than the eastern US, reaching an average of 57ppb in Denver for the 30 days with highest MDA8 O3 in 2010, present a significant challenge to air quality management approaches based solely on local or US-wide emission reductions. The substantial BC contribution to MDA8 O3 in the Intermountain West means regional models are particularly sensitive to any biases and errors in the BCs. A sensitivity simulation with reduced BC O3 in response to 20% lower emissions in Asia found a near-linear relationship between the BC O3 changes and surface O3 changes in the western US in all seasons and across the US in fall and winter. However, the surface O3 decreases are small: below 1ppb in spring and below 0.5ppb in other seasons.

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The CAMx regional model was used to examine contribution of intercontinental transport over North America as part of AQMEII Phase III. Largest boundary condition (BC) contributions to ozone (O3) are from the mid-troposphere. Lower emissions in Asia by 20 % causes a near-linear relationship between the BC O3 changes and surface O3 changes in the western US, but the changes are less than 1 ppb. Using inert tracers leads to high bias over 10 ppb compared to using chemically reactive tracers.
The CAMx regional model was used to examine contribution of intercontinental transport over...