Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Journal topic

Journal metrics

Journal metrics

  • IF value: 5.414 IF 5.414
  • IF 5-year value: 5.958 IF 5-year
    5.958
  • CiteScore value: 9.7 CiteScore
    9.7
  • SNIP value: 1.517 SNIP 1.517
  • IPP value: 5.61 IPP 5.61
  • SJR value: 2.601 SJR 2.601
  • Scimago H <br class='hide-on-tablet hide-on-mobile'>index value: 191 Scimago H
    index 191
  • h5-index value: 89 h5-index 89
Volume 17, issue 14
Atmos. Chem. Phys., 17, 8635–8650, 2017
https://doi.org/10.5194/acp-17-8635-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 17, 8635–8650, 2017
https://doi.org/10.5194/acp-17-8635-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 17 Jul 2017

Research article | 17 Jul 2017

Nitrate radical oxidation of γ-terpinene: hydroxy nitrate, total organic nitrate, and secondary organic aerosol yields

Jonathan H. Slade et al.

Related authors

The acid-catalyzed hydrolysis of an α-pinene-derived organic nitrate: kinetics, products, reaction mechanisms, and atmospheric impact
Joel D. Rindelaub, Carlos H. Borca, Matthew A. Hostetler, Jonathan H. Slade, Mark A. Lipton, Lyudmila V. Slipchenko, and Paul B. Shepson
Atmos. Chem. Phys., 16, 15425–15432, https://doi.org/10.5194/acp-16-15425-2016,https://doi.org/10.5194/acp-16-15425-2016, 2016
Short summary
Chemical aging of single and multicomponent biomass burning aerosol surrogate particles by OH: implications for cloud condensation nucleus activity
J. H. Slade, R. Thalman, J. Wang, and D. A. Knopf
Atmos. Chem. Phys., 15, 10183–10201, https://doi.org/10.5194/acp-15-10183-2015,https://doi.org/10.5194/acp-15-10183-2015, 2015
Short summary

Related subject area

Subject: Gases | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR
Anna Novelli, Luc Vereecken, Birger Bohn, Hans-Peter Dorn, Georgios I. Gkatzelis, Andreas Hofzumahaus, Frank Holland, David Reimer, Franz Rohrer, Simon Rosanka, Domenico Taraborrelli, Ralf Tillmann, Robert Wegener, Zhujun Yu, Astrid Kiendler-Scharr, Andreas Wahner, and Hendrik Fuchs
Atmos. Chem. Phys., 20, 3333–3355, https://doi.org/10.5194/acp-20-3333-2020,https://doi.org/10.5194/acp-20-3333-2020, 2020
Short summary
Kinetics of the OH + NO2 reaction: effect of water vapour and new parameterization for global modelling
Damien Amedro, Matias Berasategui, Arne J. C. Bunkan, Andrea Pozzer, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 20, 3091–3105, https://doi.org/10.5194/acp-20-3091-2020,https://doi.org/10.5194/acp-20-3091-2020, 2020
Short summary
Kinetic and mechanistic study of the reaction between methane sulfonamide (CH3S(O)2NH2) and OH
Matias Berasategui, Damien Amedro, Achim Edtbauer, Jonathan Williams, Jos Lelieveld, and John N. Crowley
Atmos. Chem. Phys., 20, 2695–2707, https://doi.org/10.5194/acp-20-2695-2020,https://doi.org/10.5194/acp-20-2695-2020, 2020
Short summary
The nitrogen budget of laboratory-simulated western U.S. wildfires during the FIREX 2016 FireLab study
James M. Roberts, Chelsea E. Stockwell, Robert J. Yokelson, Joost de Gouw, Yong Liu, Vanessa Selimovic, Abigail R. Koss, Kanako Sekimoto, Matthew M. Coggon, Bin Yuan, Kyle J. Zarzana, Steven S. Brown, Cristina Santin, Stefan H. Doerr, and Carsten Warneke
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2020-66,https://doi.org/10.5194/acp-2020-66, 2020
Revised manuscript accepted for ACP
Short summary
Atmospheric fate of two relevant unsaturated ketoethers: kinetics, products and mechanisms for the reaction of hydroxyl radicals with (E)-4-methoxy-3-buten-2-one and 1-(E)-1-methoxy-2-methyl-1-penten-3-one
Rodrigo Gastón Gibilisco, Ian Barnes, Iustinian Gabriel Bejan, and Peter Wiesen
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-867,https://doi.org/10.5194/acp-2019-867, 2020
Revised manuscript accepted for ACP

Cited articles

Abbatt, J. P. D., Lee, A. K. Y., and Thornton, J. A.: Quantifying trace gas uptake to tropospheric aerosol: recent advances and remaining challenges, Chem. Soc. Rev., 41, 6555–6581, https://doi.org/10.1039/C2cs35052a, 2012.
Atkinson, R., Aschmann, S. M., Carter, W. P. L., Winer, A. M., and Pitts, J. N.: Alkyl Nitrate Formation from the Nox-Air Photooxidations of C2–C8 N-Alkanes, J. Phys. Chem., 86, 4563–4569, https://doi.org/10.1021/j100220a022, 1982.
Beaver, M. R., Clair, J. M. St., Paulot, F., Spencer, K. M., Crounse, J. D., LaFranchi, B. W., Min, K. E., Pusede, S. E., Wooldridge, P. J., Schade, G. W., Park, C., Cohen, R. C., and Wennberg, P. O.: Importance of biogenic precursors to the budget of organic nitrates: observations of multifunctional organic nitrates by CIMS and TD-LIF during BEARPEX 2009, Atmos. Chem. Phys., 12, 5773–5785, https://doi.org/10.5194/acp-12-5773-2012, 2012.
Berkemeier, T., Ammann, M., Mentel, T. F., Pöschl, U., and Shiraiwa, M.: Organic nitrate contribution to new particle formation and growth in secondary organic aerosols from alpha-pinene ozonolysis, Environ. Sci. Technol., 50, 6334–6342, https://doi.org/10.1021/acs.est.6b00961, 2016.
Publications Copernicus
Download
Short summary
This study provides new insight into the oxidation of polyolefinic monoterpenes and the dependence of the formation and yields of organic nitrates (ON) and secondary organic aerosol (SOA) on hydrocarbon structure. Here we have elucidated the ON, hydroxy nitrate, and SOA yields from the NO3 oxidation of γ-terpinene, a potentially relevant nighttime ON precursor in the Midwestern US. The results advance our understanding of the chemistry that influences NOx, O3 production, and aerosol formation.
This study provides new insight into the oxidation of polyolefinic monoterpenes and the...
Citation