Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Atmos. Chem. Phys., 17, 705-720, 2017
https://doi.org/10.5194/acp-17-705-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Research article
16 Jan 2017
Characterization of gas-phase organics using proton transfer reaction time-of-flight mass spectrometry: fresh and aged residential wood combustion emissions
Emily A. Bruns1, Jay G. Slowik1, Imad El Haddad1, Dogushan Kilic1, Felix Klein1, Josef Dommen1, Brice Temime-Roussel2, Nicolas Marchand2, Urs Baltensperger1, and André S. H. Prévôt1 1Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
2Aix Marseille Univ, CNRS, LCE, Laboratoire de Chimie de l'Environnement, UMR7376, 13331, Marseille, France
Abstract. Organic gases emitted during the flaming phase of residential wood combustion are characterized individually and by functionality using proton transfer reaction time-of-flight mass spectrometry. The evolution of the organic gases is monitored during photochemical aging. Primary gaseous emissions are dominated by oxygenated species (e.g., acetic acid, acetaldehyde, phenol and methanol), many of which have deleterious health effects and play an important role in atmospheric processes such as secondary organic aerosol formation and ozone production. Residential wood combustion emissions differ considerably from open biomass burning in both absolute magnitude and relative composition. Ratios of acetonitrile, a potential biomass burning marker, to CO are considerably lower ( ∼  0.09 pptv ppbv−1) than those observed in air masses influenced by open burning ( ∼  1–2 pptv ppbv−1), which may make differentiation from background levels difficult, even in regions heavily impacted by residential wood burning. A considerable amount of formic acid forms during aging ( ∼  200–600 mg kg−1 at an OH exposure of (4.5–5.5)  ×  107 molec cm−3 h), indicating residential wood combustion can be an important local source for this acid, the quantities of which are currently underestimated in models. Phthalic anhydride, a naphthalene oxidation product, is also formed in considerable quantities with aging ( ∼  55–75 mg kg−1 at an OH exposure of (4.5–5.5)  ×  107 molec cm−3 h). Although total NMOG emissions vary by up to a factor of  ∼  9 between burns, SOA formation potential does not scale with total NMOG emissions and is similar in all experiments. This study is the first thorough characterization of both primary and aged organic gases from residential wood combustion and provides a benchmark for comparison of emissions generated under different burn parameters.

Citation: Bruns, E. A., Slowik, J. G., El Haddad, I., Kilic, D., Klein, F., Dommen, J., Temime-Roussel, B., Marchand, N., Baltensperger, U., and Prévôt, A. S. H.: Characterization of gas-phase organics using proton transfer reaction time-of-flight mass spectrometry: fresh and aged residential wood combustion emissions, Atmos. Chem. Phys., 17, 705-720, https://doi.org/10.5194/acp-17-705-2017, 2017.
Publications Copernicus
Download
Short summary
We characterize primary and aged gaseous emissions from residential wood combustion using proton transfer reaction time-of-flight mass spectrometry. This approach allows for improved characterization, particularly of oxygenated gases, which are a considerable fraction of the total gaseous mass emitted during residential wood combustion. This study is the first thorough characterization of organic gases from this source and provides a benchmark for future studies.
We characterize primary and aged gaseous emissions from residential wood combustion using proton...
Share