Articles | Volume 17, issue 5
https://doi.org/10.5194/acp-17-3357-2017
https://doi.org/10.5194/acp-17-3357-2017
Research article
 | 
08 Mar 2017
Research article |  | 08 Mar 2017

Terpenoid and carbonyl emissions from Norway spruce in Finland during the growing season

Hannele Hakola, Virpi Tarvainen, Arnaud P. Praplan, Kerneels Jaars, Marja Hemmilä, Markku Kulmala, Jaana Bäck, and Heidi Hellén

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Cited articles

Aalto, J., Kolari, P., Hari, P., Kerminen, V.-M., Schiestl-Aalto, P., Aaltonen, H., Levula, J., Siivola, E., Kulmala, M., and Bäck, J.: New foliage growth is a significant, unaccounted source for volatiles in boreal evergreen forests, Biogeosciences, 11, 1331–1344, https://doi.org/10.5194/bg-11-1331-2014, 2014.
Albaladejo, J., Ballesteros, B., Jiménez, E., Martín, P., and Martínez, E.: A PLP-LIF kinetic study of the atmospheric reactivity of a series of C4-C7 saturated and unsaturated aliphatic aldehydes with OH, Atmos. Environ., 36, 3231–3239, 2002.
Atkinson, R., Aschmann, S. M., and Arey, J.: Rate constants for the gas-phase reactions of OH and NO3 radicals and O3 with sabinene and camphene at 296 ± 2 K, Atmos. Environ., 24, 2647–2654, https://doi.org/10.1016/0960-1686(90)90144-C, 1990a.
Atkinson, R., Hasegawa, D., and Aschmann, S. M.: Rate constants for the gas-phase reactions of O3 with a series of monoterpenes and related compounds at 296 ± 2 K, Int. J. Chem. Kinet., 22, 871–887, https://doi.org/10.1002/kin.550220807, 1990b.
Atkinson, R., Arey, J., Aschmann, S. M., Corchnoy, S. B., and Shu, Y.: Rate constants for the gas-phase reactions of cis-3-Hexen-1-ol, cis-3-Hexenylacetate, trans-2-Hexenal, and Linalool with OH and NO3 radicals and O3 at 296 ± 2 K, and OH radical formation yields from the O3 reactions, Int. J. Chem. Kinet., 27, 941–955, https://doi.org/10.1002/kin.550271002, 1995.
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Short summary
We present spring and summer VOC emission rate measurements from Norway spruce using an in situ gas chromatograph. Monoterpene and C4–C10 aldehyde emission rates reached maxima in July. SQT emissions increased at the end of July and in August SQT were the most abundant group. The MT emission pattern varied a lot from tree to tree and therefore emission fluxes on canopy level should be conducted for more representative measurements. However, leaf level measurements produce more reliable SQT data.
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