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Volume 17, issue 4 | Copyright

Special issue: Chemistry–Climate Modelling Initiative (CCMI) (ACP/AMT/ESSD/GMD...

Atmos. Chem. Phys., 17, 2943-2970, 2017
https://doi.org/10.5194/acp-17-2943-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 01 Mar 2017

Research article | 01 Mar 2017

US surface ozone trends and extremes from 1980 to 2014: quantifying the roles of rising Asian emissions, domestic controls, wildfires, and climate

Meiyun Lin1,2, Larry W. Horowitz2, Richard Payton3, Arlene M. Fiore4, and Gail Tonnesen3 Meiyun Lin et al.
  • 1Atmospheric and Oceanic Sciences, Princeton University, Princeton, NJ 08540, USA
  • 2NOAA Geophysical Fluid Dynamics Laboratory, Princeton, NJ 08540, USA
  • 3US Environmental Protection Agency, Region 8, Air Program, Denver, CO 80202, USA
  • 4Lamont-Doherty Earth-Observatory and Department of Earth and Environmental Sciences, Columbia University, Palisades, NY 10964, USA

Abstract. US surface O3 responds to varying global-to-regional precursor emissions, climate, and extreme weather, with implications for designing effective air quality control policies. We examine these conjoined processes with observations and global chemistry-climate model (GFDL-AM3) hindcasts over 1980–2014. The model captures the salient features of observed trends in daily maximum 8h average O3: (1) increases over East Asia (up to 2ppbyr−1), (2) springtime increases at western US (WUS) rural sites (0.2–0.5ppbyr−1) with a baseline sampling approach, and (3) summertime decreases, largest at the 95th percentile, and wintertime increases in the 50th to 5th percentiles over the eastern US (EUS). Asian NOx emissions have tripled since 1990, contributing as much as 65% to modeled springtime background O3 increases (0.3–0.5ppbyr−1) over the WUS, outpacing O3 decreases attained via 50% US NOx emission controls. Methane increases over this period contribute only 15% of the WUS background O3 increase. Springtime O3 observed in Denver has increased at a rate similar to remote rural sites. During summer, increasing Asian emissions approximately offset the benefits of US emission reductions, leading to weak or insignificant observed O3 trends at WUS rural sites. Mean springtime WUS O3 is projected to increase by  ∼ 10ppb from 2010 to 2030 under the RCP8.5 global change scenario. While historical wildfire emissions can enhance summertime monthly mean O3 at individual sites by 2–8ppb, high temperatures and the associated buildup of O3 produced from regional anthropogenic emissions contribute most to elevating observed summertime O3 throughout the USA. GFDL-AM3 captures the observed interannual variability of summertime EUS O3. However, O3 deposition sink to vegetation must be reduced by 35% for the model to accurately simulate observed high-O3 anomalies during the severe drought of 1988. Regional NOx reductions alleviated the O3 buildup during the recent heat waves of 2011 and 2012 relative to earlier heat waves (e.g., 1988, 1999). The O3 decreases driven by NOx controls were more pronounced in the southeastern US, where the seasonal onset of biogenic isoprene emissions and NOx-sensitive O3 production occurs earlier than in the northeast. Without emission controls, the 95th percentile summertime O3 in the EUS would have increased by 0.2–0.4ppbyr−1 over 1988–2014 due to more frequent hot extremes and rising biogenic isoprene emissions.

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US ozone pollution responds to varying global-to-regional precursor emissions and climate, with implications for designing effective air quality control policies. Asian anthropogenic emissions of ozone precursors tripled since 1990, contributing 65 % to western US ozone increases in spring, outpacing ozone decreases attained via 50 % US emission controls. In the eastern US, if emissions had not declined, more frequent hot extremes since 1990 would have worsened the highest ozone events in summer.
US ozone pollution responds to varying global-to-regional precursor emissions and climate, with...
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