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Volume 17, issue 23 | Copyright
Atmos. Chem. Phys., 17, 14501-14517, 2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 06 Dec 2017

Research article | 06 Dec 2017

Field characterization of the PM2.5 Aerosol Chemical Speciation Monitor: insights into the composition, sources, and processes of fine particles in eastern China

Yunjiang Zhang1,2,3,4, Lili Tang1,2, Philip L. Croteau5, Olivier Favez3, Yele Sun6,7,8, Manjula R. Canagaratna5, Zhuang Wang1, Florian Couvidat3, Alexandre Albinet3, Hongliang Zhang9, Jean Sciare10, André S. H. Prévôt11, John T. Jayne5, and Douglas R. Worsnop5 Yunjiang Zhang et al.
  • 1Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Nanjing University of Information Science and Technology, Nanjing, China
  • 2Jiangsu Environmental Monitoring Center, Nanjing, China
  • 3Institut National de l'Environnement Industriel et des Risques, Verneuil-en-Halatte, France
  • 4Laboratoire des Sciences du Climat et de l'Environnement, CNRS-CEA-UVSQ, Université Paris-Saclay, Gif-sur-Yvette, France
  • 5Aerodyne Research, Inc., Billerica, MA, USA
  • 6State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, China
  • 7Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen, China
  • 8University of Chinese Academy of Sciences, Beijing, China
  • 9Nanjing Handa Environmental Science and Technology Limited, Nanjing, China
  • 10The Cyprus Institute, Environment Energy and Water Research Center, Nicosia, Cyprus
  • 11Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen PSI, Switzerland

Abstract. A PM2.5-capable aerosol chemical speciation monitor (Q-ACSM) was deployed in urban Nanjing, China, for the first time to measure in situ non-refractory fine particle (NR-PM2.5) composition from 20 October to 19 November 2015, along with parallel measurements of submicron aerosol (PM1) species by a standard Q-ACSM. Our results show that the NR-PM2.5 species (organics, sulfate, nitrate, and ammonium) measured by the PM2.5-Q-ACSM are highly correlated (r2 > 0.9) with those measured by a Sunset Lab OC/EC analyzer and a Monitor for AeRosols and GAses (MARGA). The comparisons between the two Q-ACSMs illustrated similar temporal variations in all NR species between PM1 and PM2.5, yet substantial mass fractions of aerosol species were observed in the size range of 1–2.5µm. On average, NR-PM1−2.5 contributed 53% of the total NR-PM2.5, with sulfate and secondary organic aerosols (SOAs) being the two largest contributors (26 and 27%, respectively). Positive matrix factorization of organic aerosol showed similar temporal variations in both primary and secondary OAs between PM1 and PM2.5, although the mass spectra were slightly different due to more thermal decomposition on the capture vaporizer of the PM2.5-Q-ACSM. We observed an enhancement of SOA under high relative humidity conditions, which is associated with simultaneous increases in aerosol pH, gas-phase species (NO2, SO2, and NH3) concentrations and aerosol water content driven by secondary inorganic aerosols. These results likely indicate an enhanced reactive uptake of SOA precursors upon aqueous particles. Therefore, reducing anthropogenic NOx, SO2, and NH3 emissions might not only reduce secondary inorganic aerosols but also the SOA burden during haze episodes in China.

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We conducted the first field measurements of non-refractory fine aerosols (NR-PM2.5) in a megacity of eastern China using a PM2.5-ACSM along with a PM1-ACSM measurement. Inter-comparisons demonstrated that the NR-PM2.5 components can be characterized. Substantial mass fractions of aerosol species were observed in the size range of 1–2.5 μm, with sulfate and SOA being the two largest contributors. The impacts of aerosol water driven by secondary inorganic aerosols on SOA formation were explored.
We conducted the first field measurements of non-refractory fine aerosols (NR-PM2.5) in a...