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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Atmos. Chem. Phys., 17, 13801-13818, 2017
https://doi.org/10.5194/acp-17-13801-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Research article
20 Nov 2017
Diagnosing the radiative and chemical contributions to future changes in tropical column ozone with the UM-UKCA chemistry–climate model
James Keeble1, Ewa M. Bednarz1, Antara Banerjee2, N. Luke Abraham1,3, Neil R. P. Harris4, Amanda C. Maycock5, and John A. Pyle1,3 1Department of Chemistry, University of Cambridge, Cambridge, UK
2Department of Applied Physics and Applied Mathematics, Columbia University, New York, NY, USA
3Department of Chemistry, NCAS/University of Cambridge, Cambridge, UK
4Centre for Atmospheric Informatics and Emissions Technology, Cranfield University, Cranfield, UK
5School of Earth and Environment, University of Leeds, Leeds, UK
Abstract. Chemical and dynamical drivers of trends in tropical total-column ozone (TCO3) for the recent past and future periods are explored using the UM-UKCA (Unified Model HadGEM3-A (Hewitt et al., 2011) coupled with the United Kingdom Chemistry and Aerosol scheme) chemistry–climate model. A transient 1960–2100 simulation is analysed which follows the representative concentration pathway 6.0 (RCP6.0) emissions scenario for the future. Tropical averaged (10° S–10° N) TCO3 values decrease from the 1970s, reach a minimum around 2000 and return to their 1980 values around 2040, consistent with the use and emission of halogenated ozone-depleting substances (ODSs), and their later controls under the Montreal Protocol. However, when the ozone column is subdivided into three partial columns (PCO3) that cover the upper stratosphere (PCO3US), lower stratosphere (PCO3LS) and troposphere (PCO3T), significant differences in the temporal behaviour of the partial columns are seen. Modelled PCO3T values under the RCP6.0 emissions scenario increase from 1960 to 2000 before remaining approximately constant throughout the 21st century. PCO3LS values decrease rapidly from 1960 to 2000 and remain constant from 2000 to 2050, before gradually decreasing further from 2050 to 2100 and never returning to their 1980s values. In contrast, PCO3US values decrease from 1960 to 2000, before increasing rapidly throughout the 21st century and returning to 1980s values by  ∼  2020, and reach significantly higher values by 2100. Using a series of idealised UM-UKCA time-slice simulations with concentrations of well-mixed greenhouse gases (GHGs) and halogenated ODS species set to either year 2000 or 2100 levels, we examine the main processes that drive the PCO3 responses in the three regions and assess how these processes change under different emission scenarios. Finally, we present a simple, linearised model to describe the future evolution of tropical stratospheric column ozone values based on terms representing time-dependent abundances of GHG and halogenated ODS.

Citation: Keeble, J., Bednarz, E. M., Banerjee, A., Abraham, N. L., Harris, N. R. P., Maycock, A. C., and Pyle, J. A.: Diagnosing the radiative and chemical contributions to future changes in tropical column ozone with the UM-UKCA chemistry–climate model, Atmos. Chem. Phys., 17, 13801-13818, https://doi.org/10.5194/acp-17-13801-2017, 2017.
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In this study we explore the chemical and transport processes controlling ozone abundances in different altitude regions in the tropics for the present day and how these processes may change in the future in order to determine when total-column ozone values in the tropics will recover to pre-1980s values following the implementation of the Montreal Protocol and its subsequent amendments, which imposed bans on the use and emissions of CFCs.
In this study we explore the chemical and transport processes controlling ozone abundances in...
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