Articles | Volume 17, issue 21
https://doi.org/10.5194/acp-17-13037-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-13037-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
06 Nov 2017
Research article |
| 06 Nov 2017
Mixing times of organic molecules within secondary organic aerosol particles: a global planetary boundary layer perspective
Adrian M. Maclean
Department of Chemistry, University of British Columbia,
Vancouver, BC, V6T 1Z1, Canada
Christopher L. Butenhoff
Dept. of Physics, Portland State University, Portland,
Oregon, USA
James W. Grayson
Department of Chemistry, University of British Columbia,
Vancouver, BC, V6T 1Z1, Canada
Kelley Barsanti
Department of Chemical and Environmental Engineering and
Center for Environmental Research and Technology, University of
California, Riverside, CA, USA
Jose L. Jimenez
CORRESPONDING AUTHOR
Cooperative Institute for Research in the Environmental
Sciences and Department of Chemistry and Biochemistry, University of
Colorado, Boulder, CO, USA
Department of Chemistry, University of British Columbia,
Vancouver, BC, V6T 1Z1, Canada
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31 citations as recorded by crossref.
- Amorphous phase state diagrams and viscosity of ternary aqueous organic/organic and inorganic/organic mixtures A. Marsh et al. 10.1039/C8CP00760H
- Volatility and Viscosity Are Correlated in Terpene Secondary Organic Aerosol Formed in a Flow Reactor W. Champion et al. 10.1021/acs.estlett.9b00412
- Direct measurements of semi-volatile organic compound dynamics show near-unity mass accommodation coefficients for diverse aerosols X. Liu et al. 10.1038/s42004-019-0200-x
- Heterogeneous ice nucleation properties of natural desert dust particles coated with a surrogate of secondary organic aerosol Z. Kanji et al. 10.5194/acp-19-5091-2019
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- Insect Infestation Increases Viscosity of Biogenic Secondary Organic Aerosol N. Smith et al. 10.1021/acsearthspacechem.3c00007
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- Evaluation of Biogenic Organic Aerosols in the Amazon Rainforest Using WRF‐Chem With MOSAIC J. Mao et al. 10.1029/2021JD034913
- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. 10.1021/acsearthspacechem.1c00317
- Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations E. Evoy et al. 10.5194/acp-19-10073-2019
- Modelling the effect of condensed-phase diffusion on the homogeneous nucleation of ice in ultra-viscous particles K. Fowler et al. 10.5194/acp-20-683-2020
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- A predictive group-contribution model for the viscosity of aqueous organic aerosol N. Gervasi et al. 10.5194/acp-20-2987-2020
- Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material M. Petters & S. Kasparoglu 10.1038/s41598-020-71490-0
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. 10.1021/acsearthspacechem.1c00296
- Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors M. Song et al. 10.5194/acp-19-12515-2019
- Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition W. DeRieux et al. 10.5194/acp-18-6331-2018
- Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model R. Schmedding et al. 10.5194/acp-20-8201-2020
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- Estimating viscosity of individual substrate-deposited particles from measurements of their height-to-width ratios F. Rivera-Adorno et al. 10.1080/02786826.2023.2270503
- Highly Viscous States Affect the Browning of Atmospheric Organic Particulate Matter P. Liu et al. 10.1021/acscentsci.7b00452
- Constraining nucleation, condensation, and chemistry in oxidation flow reactors using size-distribution measurements and aerosol microphysical modeling A. Hodshire et al. 10.5194/acp-18-12433-2018
- Physical state of 2-methylbutane-1,2,3,4-tetraol in pure and internally mixed aerosols J. Lessmeier et al. 10.5194/acp-18-15841-2018
- The viscosity of atmospherically relevant organic particles J. Reid et al. 10.1038/s41467-018-03027-z
- Timescales of secondary organic aerosols to reach equilibrium at various temperatures and relative humidities Y. Li & M. Shiraiwa 10.5194/acp-19-5959-2019
- Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation D. Ullmann et al. 10.5194/acp-19-1491-2019
- Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts V. Baboomian et al. 10.1073/pnas.2208121119
- Accurate Prediction of Organic Aerosol Evaporation Using Kinetic Multilayer Modeling and the Stokes–Einstein Equation S. Ingram et al. 10.1021/acs.jpca.1c00986
- Mass accommodation and gas–particle partitioning in secondary organic aerosols: dependence on diffusivity, volatility, particle-phase reactions, and penetration depth M. Shiraiwa & U. Pöschl 10.5194/acp-21-1565-2021
- ClNO2 Yields From Aircraft Measurements During the 2015 WINTER Campaign and Critical Evaluation of the Current Parameterization E. McDuffie et al. 10.1029/2018JD029358
- Characterising the evaporation kinetics of water and semi-volatile organic compounds from viscous multicomponent organic aerosol particles S. Ingram et al. 10.1039/C7CP05172G
30 citations as recorded by crossref.
- Amorphous phase state diagrams and viscosity of ternary aqueous organic/organic and inorganic/organic mixtures A. Marsh et al. 10.1039/C8CP00760H
- Volatility and Viscosity Are Correlated in Terpene Secondary Organic Aerosol Formed in a Flow Reactor W. Champion et al. 10.1021/acs.estlett.9b00412
- Direct measurements of semi-volatile organic compound dynamics show near-unity mass accommodation coefficients for diverse aerosols X. Liu et al. 10.1038/s42004-019-0200-x
- Heterogeneous ice nucleation properties of natural desert dust particles coated with a surrogate of secondary organic aerosol Z. Kanji et al. 10.5194/acp-19-5091-2019
- Unified Description of Diffusion Coefficients from Small to Large Molecules in Organic–Water Mixtures E. Evoy et al. 10.1021/acs.jpca.9b11271
- Insect Infestation Increases Viscosity of Biogenic Secondary Organic Aerosol N. Smith et al. 10.1021/acsearthspacechem.3c00007
- Organic aerosol volatility and viscosity in the North China Plain: contrast between summer and winter W. Xu et al. 10.5194/acp-21-5463-2021
- Evaluation of Biogenic Organic Aerosols in the Amazon Rainforest Using WRF‐Chem With MOSAIC J. Mao et al. 10.1029/2021JD034913
- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. 10.1021/acsearthspacechem.1c00317
- Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations E. Evoy et al. 10.5194/acp-19-10073-2019
- Modelling the effect of condensed-phase diffusion on the homogeneous nucleation of ice in ultra-viscous particles K. Fowler et al. 10.5194/acp-20-683-2020
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- A predictive group-contribution model for the viscosity of aqueous organic aerosol N. Gervasi et al. 10.5194/acp-20-2987-2020
- Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material M. Petters & S. Kasparoglu 10.1038/s41598-020-71490-0
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. 10.1021/acsearthspacechem.1c00296
- Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors M. Song et al. 10.5194/acp-19-12515-2019
- Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition W. DeRieux et al. 10.5194/acp-18-6331-2018
- Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model R. Schmedding et al. 10.5194/acp-20-8201-2020
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- Estimating viscosity of individual substrate-deposited particles from measurements of their height-to-width ratios F. Rivera-Adorno et al. 10.1080/02786826.2023.2270503
- Highly Viscous States Affect the Browning of Atmospheric Organic Particulate Matter P. Liu et al. 10.1021/acscentsci.7b00452
- Constraining nucleation, condensation, and chemistry in oxidation flow reactors using size-distribution measurements and aerosol microphysical modeling A. Hodshire et al. 10.5194/acp-18-12433-2018
- Physical state of 2-methylbutane-1,2,3,4-tetraol in pure and internally mixed aerosols J. Lessmeier et al. 10.5194/acp-18-15841-2018
- The viscosity of atmospherically relevant organic particles J. Reid et al. 10.1038/s41467-018-03027-z
- Timescales of secondary organic aerosols to reach equilibrium at various temperatures and relative humidities Y. Li & M. Shiraiwa 10.5194/acp-19-5959-2019
- Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation D. Ullmann et al. 10.5194/acp-19-1491-2019
- Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts V. Baboomian et al. 10.1073/pnas.2208121119
- Accurate Prediction of Organic Aerosol Evaporation Using Kinetic Multilayer Modeling and the Stokes–Einstein Equation S. Ingram et al. 10.1021/acs.jpca.1c00986
- Mass accommodation and gas–particle partitioning in secondary organic aerosols: dependence on diffusivity, volatility, particle-phase reactions, and penetration depth M. Shiraiwa & U. Pöschl 10.5194/acp-21-1565-2021
- ClNO2 Yields From Aircraft Measurements During the 2015 WINTER Campaign and Critical Evaluation of the Current Parameterization E. McDuffie et al. 10.1029/2018JD029358
Latest update: 18 Apr 2024
Short summary
Using laboratory data, meteorological fields and a chemical transport model, we investigated how often mixing times are < 1 h within SOA in the planetary boundary layer (PBL). Based on viscosity data for alpha-pinene SOA generated using mass concentrations of ~1000 µg m −3, mixing times in biogenic SOA are < 1h most of the time.
Using laboratory data, meteorological fields and a chemical transport model, we investigated how...
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