Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Atmos. Chem. Phys., 17, 11707-11726, 2017
https://doi.org/10.5194/acp-17-11707-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Research article
05 Oct 2017
Biomass burning at Cape Grim: exploring photochemistry using multi-scale modelling
Sarah J. Lawson1, Martin Cope1, Sunhee Leea,†, Ian E. Galbally1, Zoran Ristovski2, and Melita D. Keywood1 1Commonwealth Scientific and Industrial Research Organisation, Climate Science Centre, Aspendale, Australia
2International Laboratory for Air Quality & Health, Queensland University of Technology, Brisbane, Australia
aformerly at: Commonwealth Scientific and Industrial Research Organisation, Climate Science Centre, Aspendale, Australia
deceased
Abstract. We have tested the ability of a high-resolution chemical transport model (CTM) to reproduce biomass burning (BB) plume strikes and ozone (O3) enhancements observed at Cape Grim in Tasmania, Australia, from the Robbins Island fire. The CTM has also been used to explore the contribution of near-field BB emissions and background sources to O3 observations under conditions of complex meteorology. Using atmospheric observations, we have tested model sensitivity to meteorology, BB emission factors (EFs) corresponding to low, medium, and high modified combustion efficiency (MCE), and spatial variability. The use of two different meteorological models (TAPM–CTM and CCAM–CTM) varied the first (BB1) plume strike time by up to 15 h and the duration of impact between 12 and 36 h, and it varied the second (BB2) plume duration between 50 and 57 h. Meteorology also had a large impact on simulated O3, with one model (TAPM–CTM) simulating four periods of O3 enhancement, while the other model (CCAM) simulating only one period. Varying the BB EFs, which in turn varied the non-methane organic compound (NMOC) ∕ oxides of nitrogen (NOx) ratio, had a strongly non-linear impact on simulated O3 concentration, with either destruction or production of O3 predicted in different simulations. As shown in previous work (Lawson et al., 2015), minor rainfall events have the potential to significantly alter EF due to changes in combustion processes. Models that assume fixed EF for O3 precursor species in an environment with temporally or spatially variable EF may be unable to simulate the behaviour of important species such as O3.

TAPM–CTM is used to further explore the contribution of the Robbins Island fire to the observed O3 enhancements during BB1 and BB2. Overall, TAPM–CTM suggests that the dominant source of O3 observed at Cape Grim was aged urban air (age  = 2 days), with a contribution of O3 formed from local BB emissions.

This work shows the importance of assessing model sensitivity to meteorology and EF and the large impact these variables can have in particular on simulated destruction or production of O3 in regional atmospheric chemistry simulations. This work also shows the importance of using models to elucidate the contribution from different sources to atmospheric composition, where this is difficult using observations alone.


Citation: Lawson, S. J., Cope, M., Lee, S., Galbally, I. E., Ristovski, Z., and Keywood, M. D.: Biomass burning at Cape Grim: exploring photochemistry using multi-scale modelling, Atmos. Chem. Phys., 17, 11707-11726, https://doi.org/10.5194/acp-17-11707-2017, 2017.
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A high-resolution chemical transport model was used to reproduce observed smoke plumes. The model output was highly sensitive to fire emission factors and meteorology, particularly for secondary pollutant ozone. Aged urban air (age = 2 days) was the major source of ozone observed, with minor contributions from the fire. This work highlights the importance of assessing model sensitivity and the use of modelling to determine the contribution from different sources to atmospheric composition.
A high-resolution chemical transport model was used to reproduce observed smoke plumes. The...
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