Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Atmos. Chem. Phys., 16, 9693-9710, 2016
https://doi.org/10.5194/acp-16-9693-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Research article
02 Aug 2016
On the simultaneous deployment of two single-particle mass spectrometers at an urban background and a roadside site during SAPUSS
Manuel Dall'Osto1,2, David C. S. Beddows3, Eoin J. McGillicuddy4, Johanna K. Esser-Gietl3,a, Roy M. Harrison3,5, and John C. Wenger4 1Institut de Ciències del Mar, Consejo Superior de Investigaciones Científicas (CSIC), Pg Marítim de la Barceloneta 37–49, 08003 Barcelona, Spain
2Institute of Environmental Assessment and Water Research (IDAEA) Consejo Superior de Investigaciones Científicas (CSIC) C/Jordi Girona 18–26 08034 Barcelona, Spain
3National Centre for Atmospheric Science, Division of Environmental Health and Risk Management, School of Geography, Earth and Environmental Sciences, University of Birmingham, Edgbaston, Birmingham, B15 2TT, UK
4Department of Chemistry and Environmental Research Institute, University College Cork, Ireland
5Department of Environmental Sciences/Center of Excellence in Environmental Studies, King Abdulaziz University, Jeddah, 21589, Saudi Arabia
anow at: Deutscher Wetterdienst, Meteorological Observatory Hohenpeißenberg, Hohenpeißenberg, Germany
Abstract. The aerosol time-of-flight mass spectrometer (ATOFMS) provides size-resolved information on the chemical composition of single particles with high time resolution. Within SAPUSS (Solving Aerosol Problems by Using Synergistic Strategies), continuous ATOFMS measurements of ambient particles were made simultaneously at two urban locations: urban background (UB) site and roadside (RS) site in the city of Barcelona (Spain) from 17 September to 18 October 2010. Two different instrumental configurations were used: ATOFMS (TSI 3800) with a converging nozzle inlet (high efficiency at about 800–2000 nm) at the UB site and ATOFMS (TSI 3800-100) with an aerodynamic lens inlet (high efficiency at about 300–700 nm) at the RS site. This is the first time, to our knowledge, that two ATOFMS instruments have been deployed in the same field study. The different instrument configurations had an impact on the observed particle types at the two sites. Nevertheless, 10 particle types were detected at both locations, including local and regional elemental carbon (22.7–58.9 % of total particles), fresh and aged sea salt (1.0–14.6 %), local and regional nitrate-containing aerosols (3–11.6 %), local lead-containing metallic particles (0.1–0.2 %), and transported Fe-nitrate particles (0.8–2.5 %). The ATOFMS at the UB also characterized four particle types: calcium-containing dust (0.9 %), Saharan dust (1.3 %), vanadium-containing particles (0.9 %), and vegetative debris (1.7 %). By contrast, the high statistical counts of fine particles detected at the RS allowed identification of eight particle types. Four of these contained organic nitrogen of primary and secondary origin, which highlights the complex nature of the sources and processes that contribute to this aerosol chemical component. Aminium salts were found related to coarse sulfate-rich particle types, suggesting heterogeneous reaction mechanisms for their formation. The other four particle types mainly containing organic carbon were found spiking at different types of the day, also showing a complex single-particle mixing state relationship between organic carbon and nitrate. This ATOFMS study clearly shows that the composition of atmospheric fine particles in Barcelona, and likely other Mediterranean urban areas, is complex, with a wide range of local and regional sources combining with chemical processing to produce at least 22 different particle types exhibiting different temporal behaviour. The advantage of using two ATOFMS instruments is also demonstrated, with the nozzle-skimmer configuration enabling detection of coarse dust particles and the aerodynamic lens configuration allowing better identification of particles rich in organic carbon and amines. Overall, we find that organic nitrogen is a considerable fraction of the single particles detected, especially at the traffic-dominated RS site. Further studies are needed, especially at high time resolution, to better understand the sources and properties of particulate organic nitrogen.

Citation: Dall'Osto, M., Beddows, D. C. S., McGillicuddy, E. J., Esser-Gietl, J. K., Harrison, R. M., and Wenger, J. C.: On the simultaneous deployment of two single-particle mass spectrometers at an urban background and a roadside site during SAPUSS, Atmos. Chem. Phys., 16, 9693-9710, https://doi.org/10.5194/acp-16-9693-2016, 2016.
Publications Copernicus
Download
Short summary
The aerosol time-of-flight mass spectrometer (ATOFMS) provides size resolved information on the chemical composition of single particles with high time resolution. Within SAPUSS (Solving Aerosol Problems by Using Synergistic Strategies), continuous measurements of ambient particles were made simultaneously at two urban locations in the city of Barcelona (Spain). We find that organic nitrogen is a considerable fraction of the single particles detected, especially at the traffic-dominated site.
The aerosol time-of-flight mass spectrometer (ATOFMS) provides size resolved information on the...
Share