Articles | Volume 16, issue 14
https://doi.org/10.5194/acp-16-9349-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-9349-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
28 Jul 2016
Research article |
| 28 Jul 2016
Speciation of OH reactivity above the canopy of an isoprene-dominated forest
J. Kaiser
CORRESPONDING AUTHOR
Department of Chemistry, University of Wisconsin-Madison, Madison, WI,
USA
now at: School of Engineering and Applied Sciences, Harvard University,
Cambridge, MA, USA
K. M. Skog
Department of Chemistry, University of Wisconsin-Madison, Madison, WI,
USA
K. Baumann
Atmospheric Research & Analysis Inc, Cary, NC, USA
S. B. Bertman
Department of Chemistry, Western Michigan University, Kalamazoo, MI,
USA
S. B. Brown
Chemical Sciences Division, NOAA Earth System Research Laboratory,
Boulder, CO, USA
Department of Chemistry, University of Colorado, Boulder, CO, USA
W. H. Brune
Department of Meteorology, Pennsylvania State University, University
Park, PA, USA
J. D. Crounse
Division of Geological and Planetary Sciences, California Institute of
Technology, Pasadena, CA, USA
J. A. de Gouw
Chemical Sciences Division, NOAA Earth System Research Laboratory,
Boulder, CO, USA
Department of Chemistry, University of Colorado, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences,
University of Colorado Boulder, Boulder, CO, USA
E. S. Edgerton
Atmospheric Research & Analysis Inc, Cary, NC, USA
P. A. Feiner
Department of Meteorology, Pennsylvania State University, University
Park, PA, USA
A. H. Goldstein
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, CA, USA
Department of Civil and
Environmental Engineering, University of California, Berkeley, CA, USA
A. Koss
Chemical Sciences Division, NOAA Earth System Research Laboratory,
Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences,
University of Colorado Boulder, Boulder, CO, USA
P. K. Misztal
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, CA, USA
T. B. Nguyen
Division of Geological and Planetary Sciences, California Institute of
Technology, Pasadena, CA, USA
K. F. Olson
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, CA, USA
J. M. St. Clair
Division of Geological and Planetary Sciences, California Institute of
Technology, Pasadena, CA, USA
now at: Joint Center for Earth Systems Technology, University of
Maryland Baltimore County, Baltimore, MD, USA
now at: Atmospheric Chemistry and
Dynamics Laboratory, NASA Goddard Space Flight Center, Greenbelt, MD, USA
A. P. Teng
Division of Geological and Planetary Sciences, California Institute of
Technology, Pasadena, CA, USA
S. Toma
Department of Chemistry, Western Michigan University, Kalamazoo, MI,
USA
P. O. Wennberg
Division of Geological and Planetary Sciences, California Institute of
Technology, Pasadena, CA, USA
Division of Engineering and Applied Science, California Institute of
Technology, Pasadena, CA, USA
R. J. Wild
Chemical Sciences Division, NOAA Earth System Research Laboratory,
Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences,
University of Colorado Boulder, Boulder, CO, USA
L. Zhang
Department of Meteorology, Pennsylvania State University, University
Park, PA, USA
F. N. Keutsch
School of Engineering and Applied Sciences and Department of
Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
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Cited
49 citations as recorded by crossref.
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- Observed versus simulated OH reactivity during KORUS-AQ campaign: Implications for emission inventory and chemical environment in East Asia H. Kim et al. 10.1525/elementa.2022.00030
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- Investigation of atmospheric VOCs sources and ozone formation sensitivity during epidemic closure and control: A case study of Zhengzhou J. Guo et al. 10.1016/j.apr.2023.102035
- Testing Atmospheric Oxidation in an Alabama Forest P. Feiner et al. 10.1175/JAS-D-16-0044.1
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- A new model mechanism for atmospheric oxidation of isoprene: global effects on oxidants, nitrogen oxides, organic products, and secondary organic aerosol K. Bates & D. Jacob 10.5194/acp-19-9613-2019
- Missing OH reactivity in the global marine boundary layer A. Thames et al. 10.5194/acp-20-4013-2020
- Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama A. Hettiyadura et al. 10.5194/acp-17-1343-2017
- Global modelling of the total OH reactivity: investigations on the “missing” OH sink and its atmospheric implications V. Ferracci et al. 10.5194/acp-18-7109-2018
- Measurements of hydroperoxy radicals (HO<sub>2</sub>) at atmospheric concentrations using bromide chemical ionisation mass spectrometry S. Albrecht et al. 10.5194/amt-12-891-2019
- On the sources and sinks of atmospheric VOCs: an integrated analysis of recent aircraft campaigns over North America X. Chen et al. 10.5194/acp-19-9097-2019
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- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
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- Increasing Isoprene Epoxydiol-to-Inorganic Sulfate Aerosol Ratio Results in Extensive Conversion of Inorganic Sulfate to Organosulfur Forms: Implications for Aerosol Physicochemical Properties M. Riva et al. 10.1021/acs.est.9b01019
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- Intercomparison of OH and OH reactivity measurements in a high isoprene and low NO environment during the Southern Oxidant and Aerosol Study (SOAS) D. Sanchez et al. 10.1016/j.atmosenv.2017.10.056
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- Comparison of methods of functional group analysis using results from laboratory and field aerosol measurements M. Claflin et al. 10.1080/02786826.2021.1918325
- Can Isoprene Oxidation Explain High Concentrations of Atmospheric Formic and Acetic Acid over Forests? M. Link et al. 10.1021/acsearthspacechem.0c00010
- Nighttime Chemistry and Morning Isoprene Can Drive Urban Ozone Downwind of a Major Deciduous Forest D. Millet et al. 10.1021/acs.est.5b06367
- The lifetime of nitrogen oxides in an isoprene-dominated forest P. Romer et al. 10.5194/acp-16-7623-2016
47 citations as recorded by crossref.
- Long-term total OH reactivity measurements in a boreal forest A. Praplan et al. 10.5194/acp-19-14431-2019
- A comprehensive organic nitrate chemistry: insights into the lifetime of atmospheric organic nitrates A. Zare et al. 10.5194/acp-18-15419-2018
- Constraining remote oxidation capacity with ATom observations K. Travis et al. 10.5194/acp-20-7753-2020
- Source apportionment of organic carbon in Centreville, AL using organosulfates in organic tracer-based positive matrix factorization A. Hettiyadura et al. 10.1016/j.atmosenv.2018.05.007
- Observing Severe Drought Influences on Ozone Air Pollution in California M. Demetillo et al. 10.1021/acs.est.8b04852
- Observed versus simulated OH reactivity during KORUS-AQ campaign: Implications for emission inventory and chemical environment in East Asia H. Kim et al. 10.1525/elementa.2022.00030
- Policy-Related Gains in Urban Air Quality May Be Offset by Increased Emissions in a Warming Climate C. Cao et al. 10.1021/acs.est.2c05904
- Investigation of atmospheric VOCs sources and ozone formation sensitivity during epidemic closure and control: A case study of Zhengzhou J. Guo et al. 10.1016/j.apr.2023.102035
- Testing Atmospheric Oxidation in an Alabama Forest P. Feiner et al. 10.1175/JAS-D-16-0044.1
- Atmospheric ozone chemistry and control strategies in Hangzhou, China: Application of a 0-D box model Y. Zhao et al. 10.1016/j.atmosres.2020.105109
- A new model mechanism for atmospheric oxidation of isoprene: global effects on oxidants, nitrogen oxides, organic products, and secondary organic aerosol K. Bates & D. Jacob 10.5194/acp-19-9613-2019
- Missing OH reactivity in the global marine boundary layer A. Thames et al. 10.5194/acp-20-4013-2020
- Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama A. Hettiyadura et al. 10.5194/acp-17-1343-2017
- Global modelling of the total OH reactivity: investigations on the “missing” OH sink and its atmospheric implications V. Ferracci et al. 10.5194/acp-18-7109-2018
- Measurements of hydroperoxy radicals (HO<sub>2</sub>) at atmospheric concentrations using bromide chemical ionisation mass spectrometry S. Albrecht et al. 10.5194/amt-12-891-2019
- On the sources and sinks of atmospheric VOCs: an integrated analysis of recent aircraft campaigns over North America X. Chen et al. 10.5194/acp-19-9097-2019
- Field observational constraints on the controllers in glyoxal (CHOCHO) reactive uptake to aerosol D. Kim et al. 10.5194/acp-22-805-2022
- Measurements of Total OH Reactivity During CalNex‐LA R. Hansen et al. 10.1029/2020JD032988
- Summertime OH reactivity from a receptor coastal site in the Mediterranean Basin N. Zannoni et al. 10.5194/acp-17-12645-2017
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- A Review of the Direct Measurement of Total OH Reactivity: Ambient Air and Vehicular Emission X. Yang 10.3390/su152316246
- Isoprene, Methyl Vinyl Ketone and Methacrolein from TROICA-12 Measurements and WRF-CHEM and GEOS-CHEM Simulations in the Far East Region A. Safronov et al. 10.3390/atmos10030152
- Experimental budgets of OH, HO<sub>2</sub>, and RO<sub>2</sub> radicals and implications for ozone formation in the Pearl River Delta in China 2014 Z. Tan et al. 10.5194/acp-19-7129-2019
- Southeast Atmosphere Studies: learning from model-observation syntheses J. Mao et al. 10.5194/acp-18-2615-2018
- OH measurements in the coastal atmosphere of South China: possible missing OH sinks in aged air masses Z. Zou et al. 10.5194/acp-23-7057-2023
- Increasing Isoprene Epoxydiol-to-Inorganic Sulfate Aerosol Ratio Results in Extensive Conversion of Inorganic Sulfate to Organosulfur Forms: Implications for Aerosol Physicochemical Properties M. Riva et al. 10.1021/acs.est.9b01019
- Reconciling Observed and Predicted Tropical Rainforest OH Concentrations D. Jeong et al. 10.1029/2020JD032901
- Continuous Isoprene Measurements in a UK Temperate Forest for a Whole Growing Season: Effects of Drought Stress During the 2018 Heatwave V. Ferracci et al. 10.1029/2020GL088885
- A Review on Laboratory Studies and Field Measurements of Atmospheric Organic Aerosol Hygroscopicity and Its Parameterization Based on Oxidation Levels Y. Kuang et al. 10.1007/s40726-020-00164-2
- Isoprenoid emissions from natural vegetation increased rapidly in eastern China L. Li et al. 10.1016/j.envres.2021.111462
- Intercomparison of OH and OH reactivity measurements in a high isoprene and low NO environment during the Southern Oxidant and Aerosol Study (SOAS) D. Sanchez et al. 10.1016/j.atmosenv.2017.10.056
- Biogenic volatile organic compounds dominated the near-surface ozone generation in Sichuan Basin, China, during fall and wintertime D. Huang et al. 10.1016/j.jes.2023.04.004
- Large unexplained suite of chemically reactive compounds present in ambient air due to biomass fires V. Kumar et al. 10.1038/s41598-017-19139-3
- Ambient Measurements of Highly Oxidized Gas-Phase Molecules during the Southern Oxidant and Aerosol Study (SOAS) 2013 P. Massoli et al. 10.1021/acsearthspacechem.8b00028
- The Interplay Between Ozone and Urban Vegetation—BVOC Emissions, Ozone Deposition, and Tree Ecophysiology A. Fitzky et al. 10.3389/ffgc.2019.00050
- Contributions to OH reactivity from unexplored volatile organic compounds measured by PTR-ToF-MS – a case study in a suburban forest of the Seoul metropolitan area during the Korea–United States Air Quality Study (KORUS-AQ) 2016 D. Sanchez et al. 10.5194/acp-21-6331-2021
- Missing ozone-induced potential aerosol formation in a suburban deciduous forest T. Nakayama et al. 10.1016/j.atmosenv.2017.10.014
- Emissions, chemistry or bidirectional surface transfer? Gas phase formic acid dynamics in the atmosphere Z. Gao et al. 10.1016/j.atmosenv.2022.118995
- Variability of hydroxyl radical (OH) reactivity in the Landes maritime pine forest: results from the LANDEX campaign 2017 S. Bsaibes et al. 10.5194/acp-20-1277-2020
- Atmospheric reactivity of biogenic volatile organic compounds in a maritime pine forest during the LANDEX episode 1 field campaign K. Mermet et al. 10.1016/j.scitotenv.2020.144129
- Influence of Organized Turbulence on OH Reactivity at a Deciduous Forest O. Clifton et al. 10.1029/2022GL102548
- The Framework for 0-D Atmospheric Modeling (F0AM) v3.1 G. Wolfe et al. 10.5194/gmd-9-3309-2016
- Towards a satellite formaldehyde – in situ hybrid estimate for organic aerosol abundance J. Liao et al. 10.5194/acp-19-2765-2019
- Contrasting Reactive Organic Carbon Observations in the Southeast United States (SOAS) and Southern California (CalNex) C. Heald et al. 10.1021/acs.est.0c05027
- Potential Implications of the Sesquiterpene Presence over the Remote Marine Boundary Layer in the Arctic Region K. Park et al. 10.3390/atmos14050823
- Comparison of methods of functional group analysis using results from laboratory and field aerosol measurements M. Claflin et al. 10.1080/02786826.2021.1918325
- Can Isoprene Oxidation Explain High Concentrations of Atmospheric Formic and Acetic Acid over Forests? M. Link et al. 10.1021/acsearthspacechem.0c00010
Saved (preprint)
Latest update: 18 Apr 2024
Short summary
OH reactivity can be used to assess the amount of reactive carbon in an air mass. “Missing” reactivity is commonly found in forested environments and is attributed to either direct emissions of unmeasured volatile organic compounds or to unmeasured/underpredicted oxidation products. Using a box model and measurements from the 2013 SOAS campaign, we find only small discrepancies in measured and calculated reactivity. Our results suggest the discrepancies stem from unmeasured direct emissions.
OH reactivity can be used to assess the amount of reactive carbon in an air mass. “Missing”...
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