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Volume 16, issue 8
Atmos. Chem. Phys., 16, 5139–5157, 2016
https://doi.org/10.5194/acp-16-5139-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 16, 5139–5157, 2016
https://doi.org/10.5194/acp-16-5139-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 25 Apr 2016

Research article | 25 Apr 2016

Investigating the source, transport, and isotope composition of water vapor in the planetary boundary layer

Timothy J. Griffis1, Jeffrey D. Wood1, John M. Baker1,2, Xuhui Lee3,4, Ke Xiao1, Zichong Chen1, Lisa R. Welp5, Natalie M. Schultz3, Galen Gorski1, Ming Chen1, and John Nieber6 Timothy J. Griffis et al.
  • 1Department of Soil, Water, and Climate, University of Minnesota, Saint Paul, MN, USA
  • 2United States Department of Agriculture – Agricultural Research Service, Saint Paul, MN, USA
  • 3School of Forestry and Environmental Studies, Yale University, New Haven, CT, USA
  • 4Yale-NUIST Center on Atmospheric Environment, Nanjing University of Information, Science and Technology, Nanjing, China
  • 5Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, IN, USA
  • 6Department of Bioproducts and Biosystems Engineering, University of Minnesota, Saint Paul, MN, USA

Abstract. Increasing atmospheric humidity and convective precipitation over land provide evidence of intensification of the hydrologic cycle – an expected response to surface warming. The extent to which terrestrial ecosystems modulate these hydrologic factors is important to understand feedbacks in the climate system. We measured the oxygen and hydrogen isotope composition of water vapor at a very tall tower (185 m) in the upper Midwest, United States, to diagnose the sources, transport, and fractionation of water vapor in the planetary boundary layer (PBL) over a 3-year period (2010 to 2012). These measurements represent the first set of annual water vapor isotope observations for this region. Several simple isotope models and cross-wavelet analyses were used to assess the importance of the Rayleigh distillation process, evaporation, and PBL entrainment processes on the isotope composition of water vapor. The vapor isotope composition at this tall tower site showed a large seasonal amplitude (mean monthly δ18Ov ranged from −40.2 to −15.9 ‰ and δ2Hv ranged from −278.7 to −113.0 ‰) and followed the familiar Rayleigh distillation relation with water vapor mixing ratio when considering the entire hourly data set. However, this relation was strongly modulated by evaporation and PBL entrainment processes at timescales ranging from hours to several days. The wavelet coherence spectra indicate that the oxygen isotope ratio and the deuterium excess (dv) of water vapor are sensitive to synoptic and PBL processes. According to the phase of the coherence analyses, we show that evaporation often leads changes in dv, confirming that it is a potential tracer of regional evaporation. Isotope mixing models indicate that on average about 31 % of the growing season PBL water vapor is derived from regional evaporation. However, isoforcing calculations and mixing model analyses for high PBL water vapor mixing ratio events ( >  25 mmol mol−1) indicate that regional evaporation can account for 40 to 60 % of the PBL water vapor. These estimates are in relatively good agreement with that derived from numerical weather model simulations. This relatively large fraction of evaporation-derived water vapor implies that evaporation has an important impact on the precipitation recycling ratio within the region. Based on multiple constraints, we estimate that the summer season recycling fraction is about 30 %, indicating a potentially important link with convective precipitation.

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Increasing atmospheric humidity and convective precipitation over land provide evidence of intensification of the hydrologic cycle. We present the first multi-annual isotope (oxygen and deuterium) water vapor observations from a very tall tower (185 m) in the upper Midwest, United States, to diagnose the sources, transport, and fractionation of water vapor in the atmosphere. The results show a relatively high degree of summertime water recycling within the region (~30 % mean and ~60 % maximum).
Increasing atmospheric humidity and convective precipitation over land provide evidence of...
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