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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
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Volume 16, issue 7 | Copyright
Atmos. Chem. Phys., 16, 4439-4449, 2016
https://doi.org/10.5194/acp-16-4439-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 11 Apr 2016

Research article | 11 Apr 2016

Kinetic isotope effects of 12CH3D  + OH and 13CH3D  + OH from 278 to 313 K

L. M. T. Joelsson et al.
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A compilation of kinetics data on gas-phase reactions National Institute of Standards and Technology Chemical Kinetics Database http://kinetics.nist.gov

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Short summary
We present experimental kinetic isotope effects (KIE) for the OH oxidation of CH3D and 13CH3D and their temperature dependence. Our determination of the 13CH3D + OH KIE is novel and we find no "clumped" isotope effect within the experimental uncertainty.
We present experimental kinetic isotope effects (KIE) for the OH oxidation of CH3D and 13CH3D...
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