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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
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Volume 16, issue 5
Atmos. Chem. Phys., 16, 3061-3076, 2016
https://doi.org/10.5194/acp-16-3061-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Special issue: Data collection, analysis and application of speciated atmospheric...

Atmos. Chem. Phys., 16, 3061-3076, 2016
https://doi.org/10.5194/acp-16-3061-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Review article 09 Mar 2016

Review article | 09 Mar 2016

Passive air sampling of gaseous elemental mercury: a critical review

David S. McLagan, Maxwell E. E. Mazur, Carl P. J. Mitchell, and Frank Wania David S. McLagan et al.
  • Department of Physical and Environmental Sciences, University of Toronto Scarborough, Toronto, Ontario, Canada

Abstract. Because gaseous elemental mercury (GEM) is distributed globally through the atmosphere, reliable means of measuring its concentrations in air are important. Passive air samplers (PASs), designed to be cheap, simple to operate, and to work without electricity, could provide an alternative to established active sampling techniques in applications such as (1) long-term monitoring of atmospheric GEM levels in remote regions and in developing countries, (2) atmospheric mercury source identification and characterization through finely resolved spatial mapping, and (3) the recording of personal exposure to GEM. An effective GEM PAS requires a tightly constrained sampling rate, a large and stable uptake capacity, and a sensitive analytical technique. None of the GEM PASs developed to date achieve levels of accuracy and precision sufficient for the reliable determination of background concentrations over extended deployments. This is due to (1) sampling rates that vary due to meteorological factors and manufacturing inconsistencies, and/or (2) an often low, irreproducible and/or unstable uptake capacity of the employed sorbents. While we identify shortcomings of existing GEM PAS, we also reveal potential routes to overcome those difficulties. Activated carbon and nanostructured metal surfaces hold promise as effective sorbents. Sampler designs incorporating diffusive barriers should be able to notably reduce the influence of wind on sampling rates.

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For more than 20 years, scientists and engineers have tried to design simple sampling devices that can collect gaseous elemental mercury from the atmosphere without the use of a pump. A thorough review of the sampler designs that have been presented so far suggests that while some may be suitable for measuring higher air concentrations close to sources, none of them have the accuracy and precision required to record the low atmospheric mercury concentrations prevalent in background regions.
For more than 20 years, scientists and engineers have tried to design simple sampling devices...
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