Articles | Volume 16, issue 4
https://doi.org/10.5194/acp-16-2255-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-2255-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
26 Feb 2016
Research article |
| 26 Feb 2016
Role of methyl group number on SOA formation from monocyclic aromatic hydrocarbons photooxidation under low-NOx conditions
L. Li
University of California, Riverside, Department of Chemical and Environmental Engineering, Riverside, CA 92507, USA
College of Engineering-Center for Environmental Research and Technology (CE-CERT), Riverside, CA 92507, USA
P. Tang
University of California, Riverside, Department of Chemical and Environmental Engineering, Riverside, CA 92507, USA
College of Engineering-Center for Environmental Research and Technology (CE-CERT), Riverside, CA 92507, USA
University of California, Riverside, Department of Chemical and Environmental Engineering, Riverside, CA 92507, USA
College of Engineering-Center for Environmental Research and Technology (CE-CERT), Riverside, CA 92507, USA
currently at: Clarkson University, Department of Chemical and Biomolecular Engineering, Potsdam, NY 13699, USA
C.-L. Chen
University of California, Riverside, Department of Chemical and Environmental Engineering, Riverside, CA 92507, USA
College of Engineering-Center for Environmental Research and Technology (CE-CERT), Riverside, CA 92507, USA
currently at: Scripps Institution of Oceanography, University of California, La Jolla, CA, USA
D. R. Cocker III
CORRESPONDING AUTHOR
University of California, Riverside, Department of Chemical and Environmental Engineering, Riverside, CA 92507, USA
College of Engineering-Center for Environmental Research and Technology (CE-CERT), Riverside, CA 92507, USA
Viewed
Total article views: 3,179 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 06 Nov 2015)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 1,842 | 1,255 | 82 | 3,179 | 465 | 60 | 94 |
- HTML: 1,842
- PDF: 1,255
- XML: 82
- Total: 3,179
- Supplement: 465
- BibTeX: 60
- EndNote: 94
Total article views: 2,597 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 26 Feb 2016)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 1,531 | 1,001 | 65 | 2,597 | 290 | 46 | 78 |
- HTML: 1,531
- PDF: 1,001
- XML: 65
- Total: 2,597
- Supplement: 290
- BibTeX: 46
- EndNote: 78
Total article views: 582 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 06 Nov 2015)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 311 | 254 | 17 | 582 | 175 | 14 | 16 |
- HTML: 311
- PDF: 254
- XML: 17
- Total: 582
- Supplement: 175
- BibTeX: 14
- EndNote: 16
Cited
30 citations as recorded by crossref.
- SOA formation from photooxidation of naphthalene and methylnaphthalenes with m-xylene and surrogate mixtures C. Chen et al. 10.1016/j.atmosenv.2018.02.051
- Reactor characterization and primary application of a state of art dual-reactor chamber in the investigation of atmospheric photochemical processes H. Luo et al. 10.1016/j.jes.2020.05.021
- Formation of secondary organic aerosols from anthropogenic precursors in laboratory studies D. Srivastava et al. 10.1038/s41612-022-00238-6
- Important role of aromatic hydrocarbons in SOA formation from unburned gasoline vapor T. Chen et al. 10.1016/j.atmosenv.2019.01.001
- Effect of relative humidity on SOA formation from aromatic hydrocarbons: Implications from the evolution of gas- and particle-phase species T. Chen et al. 10.1016/j.scitotenv.2021.145015
- Differences of the oxidation process and secondary organic aerosol formation at low and high precursor concentrations T. Chen et al. 10.1016/j.jes.2018.11.011
- Formation of oxidized organic compounds from Cl-initiated oxidation of toluene S. Dhulipala et al. 10.1016/j.atmosenv.2018.11.002
- The effects of humidity and ammonia on the chemical composition of secondary aerosols from toluene/NOx photo-oxidation L. Chen et al. 10.1016/j.scitotenv.2020.138671
- Synergistic generation mechanisms of SOA and ozone from the photochemical oxidation of 1,3,5-trimethylbenzene: Influence of precursors ratio, temperature and radiation intensity H. Zhang et al. 10.1016/j.atmosres.2023.106924
- Impact of molecular structure on secondary organic aerosol formation from aromatic hydrocarbon photooxidation under low-NO<sub><i>x</i></sub> conditions L. Li et al. 10.5194/acp-16-10793-2016
- The underappreciated role of monocarbonyl-dicarbonyl interconversion in secondary organic aerosol formation during photochemical oxidation of m-xylene J. Chen et al. 10.1016/j.scitotenv.2021.152575
- Particle-Bound Highly Oxidized Organic Molecules Derived from Aromatic Hydrocarbons in an Urban Atmosphere M. Zhu et al. 10.1021/acs.estlett.2c00841
- Gas-phase composition and secondary organic aerosol formation from standard and particle filter-retrofitted gasoline direct injection vehicles investigated in a batch and flow reactor S. Pieber et al. 10.5194/acp-18-9929-2018
- Secondary organic aerosol formation from mixed volatile organic compounds: Effect of RO2 chemistry and precursor concentration T. Chen et al. 10.1038/s41612-022-00321-y
- Effects of NO and SO2 on the secondary organic aerosol formation from the photooxidation of 1,3,5-trimethylbenzene: A new source of organosulfates Z. Yang et al. 10.1016/j.envpol.2020.114742
- Novel Approach for Evaluating Secondary Organic Aerosol from Aromatic Hydrocarbons: Unified Method for Predicting Aerosol Composition and Formation L. Li et al. 10.1021/acs.est.5b05778
- Secondary organic aerosol formation from photooxidation of γ-butyro and γ-valero-lactone: A combined experimental and theoretical study M. Tajuelo et al. 10.1016/j.atmosenv.2022.119051
- Characterization of products formed from the oxidation of toluene and m-xylene with varying NOx and OH exposure D. Srivastava et al. 10.1016/j.chemosphere.2023.139002
- Comparison of secondary organic aerosol (SOA) formation during o-, m-, and p-xylene photooxidation P. Zhang et al. 10.1016/j.envpol.2018.10.118
- Nitrogen-Containing Compounds Enhance Light Absorption of Aromatic-Derived Brown Carbon Z. Yang et al. 10.1021/acs.est.1c08794
- Oxygenated organic molecules produced by low-NOx photooxidation of aromatic compounds: contributions to secondary organic aerosol and steric hindrance X. Cheng et al. 10.5194/acp-24-2099-2024
- Molecular structure impacts on secondary organic aerosol formation from glycol ethers L. Li & D. Cocker 10.1016/j.atmosenv.2017.12.025
- Secondary organic aerosol formed by condensing anthropogenic vapours over China’s megacities W. Nie et al. 10.1038/s41561-022-00922-5
- Smog Chamber Study on the Role of NOxin SOA and O3Formation from Aromatic Hydrocarbons T. Chen et al. 10.1021/acs.est.2c04022
- Effect of Titanium Dioxide on Secondary Organic Aerosol Formation Y. Chen et al. 10.1021/acs.est.8b02466
- Insight into the crucial reason causing the difference in secondary organic aerosol yields of monocyclic aromatic hydrocarbons with different methyl substituent numbers Z. Yu et al. 10.1016/j.scitotenv.2023.166353
- Formation kinetics and mechanisms of ozone and secondary organic aerosols from photochemical oxidation of different aromatic hydrocarbons: dependence on NO<sub><i>x</i></sub> and organic substituents H. Luo et al. 10.5194/acp-21-7567-2021
- Contribution of methyl group to secondary organic aerosol formation from aromatic hydrocarbon photooxidation L. Li et al. 10.1016/j.atmosenv.2016.11.064
- Underestimated Contribution of Heavy Aromatics to Secondary Organic Aerosol Revealed by Comparative Assessments Using New and Traditional Methods L. Tian et al. 10.1021/acsearthspacechem.2c00252
- Indoor terpene emissions from cooking with herbs and pepper and their secondary organic aerosol production potential F. Klein et al. 10.1038/srep36623
29 citations as recorded by crossref.
- SOA formation from photooxidation of naphthalene and methylnaphthalenes with m-xylene and surrogate mixtures C. Chen et al. 10.1016/j.atmosenv.2018.02.051
- Reactor characterization and primary application of a state of art dual-reactor chamber in the investigation of atmospheric photochemical processes H. Luo et al. 10.1016/j.jes.2020.05.021
- Formation of secondary organic aerosols from anthropogenic precursors in laboratory studies D. Srivastava et al. 10.1038/s41612-022-00238-6
- Important role of aromatic hydrocarbons in SOA formation from unburned gasoline vapor T. Chen et al. 10.1016/j.atmosenv.2019.01.001
- Effect of relative humidity on SOA formation from aromatic hydrocarbons: Implications from the evolution of gas- and particle-phase species T. Chen et al. 10.1016/j.scitotenv.2021.145015
- Differences of the oxidation process and secondary organic aerosol formation at low and high precursor concentrations T. Chen et al. 10.1016/j.jes.2018.11.011
- Formation of oxidized organic compounds from Cl-initiated oxidation of toluene S. Dhulipala et al. 10.1016/j.atmosenv.2018.11.002
- The effects of humidity and ammonia on the chemical composition of secondary aerosols from toluene/NOx photo-oxidation L. Chen et al. 10.1016/j.scitotenv.2020.138671
- Synergistic generation mechanisms of SOA and ozone from the photochemical oxidation of 1,3,5-trimethylbenzene: Influence of precursors ratio, temperature and radiation intensity H. Zhang et al. 10.1016/j.atmosres.2023.106924
- Impact of molecular structure on secondary organic aerosol formation from aromatic hydrocarbon photooxidation under low-NO<sub><i>x</i></sub> conditions L. Li et al. 10.5194/acp-16-10793-2016
- The underappreciated role of monocarbonyl-dicarbonyl interconversion in secondary organic aerosol formation during photochemical oxidation of m-xylene J. Chen et al. 10.1016/j.scitotenv.2021.152575
- Particle-Bound Highly Oxidized Organic Molecules Derived from Aromatic Hydrocarbons in an Urban Atmosphere M. Zhu et al. 10.1021/acs.estlett.2c00841
- Gas-phase composition and secondary organic aerosol formation from standard and particle filter-retrofitted gasoline direct injection vehicles investigated in a batch and flow reactor S. Pieber et al. 10.5194/acp-18-9929-2018
- Secondary organic aerosol formation from mixed volatile organic compounds: Effect of RO2 chemistry and precursor concentration T. Chen et al. 10.1038/s41612-022-00321-y
- Effects of NO and SO2 on the secondary organic aerosol formation from the photooxidation of 1,3,5-trimethylbenzene: A new source of organosulfates Z. Yang et al. 10.1016/j.envpol.2020.114742
- Novel Approach for Evaluating Secondary Organic Aerosol from Aromatic Hydrocarbons: Unified Method for Predicting Aerosol Composition and Formation L. Li et al. 10.1021/acs.est.5b05778
- Secondary organic aerosol formation from photooxidation of γ-butyro and γ-valero-lactone: A combined experimental and theoretical study M. Tajuelo et al. 10.1016/j.atmosenv.2022.119051
- Characterization of products formed from the oxidation of toluene and m-xylene with varying NOx and OH exposure D. Srivastava et al. 10.1016/j.chemosphere.2023.139002
- Comparison of secondary organic aerosol (SOA) formation during o-, m-, and p-xylene photooxidation P. Zhang et al. 10.1016/j.envpol.2018.10.118
- Nitrogen-Containing Compounds Enhance Light Absorption of Aromatic-Derived Brown Carbon Z. Yang et al. 10.1021/acs.est.1c08794
- Oxygenated organic molecules produced by low-NOx photooxidation of aromatic compounds: contributions to secondary organic aerosol and steric hindrance X. Cheng et al. 10.5194/acp-24-2099-2024
- Molecular structure impacts on secondary organic aerosol formation from glycol ethers L. Li & D. Cocker 10.1016/j.atmosenv.2017.12.025
- Secondary organic aerosol formed by condensing anthropogenic vapours over China’s megacities W. Nie et al. 10.1038/s41561-022-00922-5
- Smog Chamber Study on the Role of NOxin SOA and O3Formation from Aromatic Hydrocarbons T. Chen et al. 10.1021/acs.est.2c04022
- Effect of Titanium Dioxide on Secondary Organic Aerosol Formation Y. Chen et al. 10.1021/acs.est.8b02466
- Insight into the crucial reason causing the difference in secondary organic aerosol yields of monocyclic aromatic hydrocarbons with different methyl substituent numbers Z. Yu et al. 10.1016/j.scitotenv.2023.166353
- Formation kinetics and mechanisms of ozone and secondary organic aerosols from photochemical oxidation of different aromatic hydrocarbons: dependence on NO<sub><i>x</i></sub> and organic substituents H. Luo et al. 10.5194/acp-21-7567-2021
- Contribution of methyl group to secondary organic aerosol formation from aromatic hydrocarbon photooxidation L. Li et al. 10.1016/j.atmosenv.2016.11.064
- Underestimated Contribution of Heavy Aromatics to Secondary Organic Aerosol Revealed by Comparative Assessments Using New and Traditional Methods L. Tian et al. 10.1021/acsearthspacechem.2c00252
Saved (preprint)
Latest update: 23 Apr 2024
Short summary
Substitution of methyl groups onto the aromatic ring determines the SOA formation from the aromatic hydrocarbon precursor. This study links the number of methyl groups on the aromatic ring to SOA formation from aromatic hydrocarbons photooxidation under low-NOx conditions (HC / NO > 10 ppbC : ppb). Aromatics are determined to be less oxidized per mass/carbon as the number of methyl groups on aromatic ring increases based on SOA yield, SOA chemical composition and SOA physical characteristics.
Substitution of methyl groups onto the aromatic ring determines the SOA formation from the...
Altmetrics
Final-revised paper
Preprint