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Volume 16, issue 1 | Copyright
Atmos. Chem. Phys., 16, 195-214, 2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 18 Jan 2016

Research article | 18 Jan 2016

Can we explain the observed methane variability after the Mount Pinatubo eruption?

N. Bândă1,2, M. Krol3,4,1, M. van Weele2, T. van Noije2, P. Le Sager2, and T. Röckmann1 N. Bândă et al.
  • 1Institute for Marine and Atmospheric Research Utrecht, Utrecht University, Utrecht, The Netherlands
  • 2Royal Netherlands Meteorological Institute (KNMI), De Bilt, The Netherlands
  • 3Meteorology and Air Quality, Wageningen University and Research Center, Wageningen, The Netherlands
  • 4Netherlands Institute for Space Research (SRON), Utrecht, The Netherlands

Abstract. The CH4 growth rate in the atmosphere showed large variations after the Pinatubo eruption in June 1991. A decrease of more than 10ppbyr−1 in the growth rate over the course of 1992 was reported, and a partial recovery in the following year. Although several reasons have been proposed to explain the evolution of CH4 after the eruption, their contributions to the observed variations are not yet resolved. CH4 is removed from the atmosphere by the reaction with tropospheric OH, which in turn is produced by O3 photolysis under UV radiation. The CH4 removal after the Pinatubo eruption might have been affected by changes in tropospheric UV levels due to the presence of stratospheric SO2 and sulfate aerosols, and due to enhanced ozone depletion on Pinatubo aerosols. The perturbed climate after the eruption also altered both sources and sinks of atmospheric CH4. Furthermore, CH4 concentrations were influenced by other factors of natural variability in that period, such as El Niño–Southern Oscillation (ENSO) and biomass burning events. Emissions of CO, NOX and non-methane volatile organic compounds (NMVOCs) also affected CH4 concentrations indirectly by influencing tropospheric OH levels.

Potential drivers of CH4 variability are investigated using the TM5 global chemistry model. The contribution that each driver had to the global CH4 variability during the period 1990 to 1995 is quantified. We find that a decrease of 8–10ppbyr−1 CH4 is explained by a combination of the above processes. However, the timing of the minimum growth rate is found 6&nash;9 months later than observed. The long-term decrease in CH4 growth rate over the period 1990 to 1995 is well captured and can be attributed to an increase in OH concentrations over this time period. Potential uncertainties in our modelled CH4 growth rate include emissions of CH4 from wetlands, biomass burning emissions of CH4 and other compounds, biogenic NMVOC and the sensitivity of OH to NMVOC emission changes. Two inventories are used for CH4 emissions from wetlands, ORCHIDEE and LPJ, to investigate the role of uncertainties in these emissions. Although the higher climate sensitivity of ORCHIDEE improves the simulated CH4 growth rate change after Pinatubo, none of the two inventories properly captures the observed CH4 variability in this period.

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We quantify the processes responsible for methane growth rate variability in the period 1990 to 1995, a period with variations in climate and radiation due to the Pinatubo eruption. We find significant contributions from changes in the methane emission from wetlands, and in the methane removal by OH caused by stratospheric aerosols, by the decrease in temperature and water vapour, by stratospheric ozone depletion and by changes in emissions of CO and NMVOC.
We quantify the processes responsible for methane growth rate variability in the period 1990 to...