Articles | Volume 16, issue 24
https://doi.org/10.5194/acp-16-15593-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-15593-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
19 Dec 2016
Research article |
| 19 Dec 2016
Nighttime atmospheric chemistry of iodine
Department of Atmospheric Chemistry and Climate, Institute of Physical
Chemistry Rocasolano, CSIC, Madrid, Spain
John M. C. Plane
School of Chemistry, University of Leeds, Leeds, UK
Carlos A. Cuevas
Department of Atmospheric Chemistry and Climate, Institute of Physical
Chemistry Rocasolano, CSIC, Madrid, Spain
Anoop S. Mahajan
Indian Institute of Tropical Meteorology, Pune, India
Jean-François Lamarque
Atmospheric Chemistry Observations & Modeling Laboratory, National Center for Atmospheric Research, Boulder, 10 Colorado, USA
Douglas E. Kinnison
Atmospheric Chemistry Observations & Modeling Laboratory, National Center for Atmospheric Research, Boulder, 10 Colorado, USA
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Cited
24 citations as recorded by crossref.
- Characterization of aerosol number size distributions and their effect on cloud properties at Syowa Station, Antarctica K. Hara et al. 10.5194/acp-21-12155-2021
- Rapid increase in atmospheric iodine levels in the North Atlantic since the mid-20th century C. Cuevas et al. 10.1038/s41467-018-03756-1
- Theoretical treatment of IO–X (X = N2, CO, CO2, H2O) complexes S. Marzouk et al. 10.1039/D1CP05536D
- Synthesis of Organic Iodine Compounds in Sweetcorn under the Influence of Exogenous Foliar Application of Iodine and Vanadium M. Grzanka et al. 10.3390/molecules27061822
- Ozone Formation Induced by the Impact of Reactive Bromine and Iodine Species on Photochemistry in a Polluted Marine Environment M. Shechner & E. Tas 10.1021/acs.est.7b02860
- Natural halogens buffer tropospheric ozone in a changing climate F. Iglesias-Suarez et al. 10.1038/s41558-019-0675-6
- Initial dynamic photoactive materials testing of an atmospheric chamber intended for radioactive and hazardous gases N. Smith et al. 10.1557/s43580-023-00708-w
- Organic bromine compounds produced in sea ice in Antarctic winter K. Abrahamsson et al. 10.1038/s41467-018-07062-8
- Global Bromine- and Iodine-Mediated Tropospheric Ozone Loss Estimated Using the CHASER Chemical Transport Model T. Sekiya et al. 10.2151/sola.2020-037
- Interaction process between gaseous CH3I and NaCl particles: implication for iodine dispersion in the atmosphere H. Houjeij et al. 10.1039/D1EM00266J
- A theoretical study of the microhydration processes of iodine nitrogen oxides A. Villard et al. 10.1002/qua.25792
- Box modelling of gas-phase atmospheric iodine chemical reactivity in case of a nuclear accident C. Fortin et al. 10.1016/j.atmosenv.2019.116838
- Diurnal cycle of iodine, bromine, and mercury concentrations in Svalbard surface snow A. Spolaor et al. 10.5194/acp-19-13325-2019
- Chemical Interactions Between Ship‐Originated Air Pollutants and Ocean‐Emitted Halogens Q. Li et al. 10.1029/2020JD034175
- Influence of emission inventory resolution on the modeled spatio-temporal distribution of air pollutants in Buenos Aires, Argentina, using WRF-Chem A. López-Noreña et al. 10.1016/j.atmosenv.2021.118839
- Full latitudinal marine atmospheric measurements of iodine monoxide H. Takashima et al. 10.5194/acp-22-4005-2022
- Influence of Interfering Ions and Adsorption Temperature on Radioactive Iodine Removal Efficiency and Stability of Ni-MOF-74 and Zr-UiO-66 T. Alghamdi et al. 10.1021/acsami.3c05821
- Investigation of the Reaction Mechanism and Kinetics of Iodic Acid with OH Radical Using Quantum Chemistry S. Khanniche et al. 10.1021/acsearthspacechem.7b00038
- Direct field evidence of autocatalytic iodine release from atmospheric aerosol Y. Tham et al. 10.1073/pnas.2009951118
- Detoxification of arsenite by iodide in frozen solution Q. Nguyen et al. 10.1016/j.chemosphere.2023.139903
- Evidence for renoxification in the tropical marine boundary layer C. Reed et al. 10.5194/acp-17-4081-2017
- Enhanced Chlorine and Bromine Atom Activation by Hydrolysis of Halogen Nitrates from Marine Aerosols at Polluted Coastal Areas E. Hoffmann et al. 10.1021/acs.est.8b05165
- Modelling the impacts of iodine chemistry on the northern Indian Ocean marine boundary layer A. Mahajan et al. 10.5194/acp-21-8437-2021
- Equation-of-motion coupled-cluster theory based on the 4-component Dirac–Coulomb(–Gaunt) Hamiltonian. Energies for single electron detachment, attachment, and electronically excited states A. Shee et al. 10.1063/1.5053846
24 citations as recorded by crossref.
- Characterization of aerosol number size distributions and their effect on cloud properties at Syowa Station, Antarctica K. Hara et al. 10.5194/acp-21-12155-2021
- Rapid increase in atmospheric iodine levels in the North Atlantic since the mid-20th century C. Cuevas et al. 10.1038/s41467-018-03756-1
- Theoretical treatment of IO–X (X = N2, CO, CO2, H2O) complexes S. Marzouk et al. 10.1039/D1CP05536D
- Synthesis of Organic Iodine Compounds in Sweetcorn under the Influence of Exogenous Foliar Application of Iodine and Vanadium M. Grzanka et al. 10.3390/molecules27061822
- Ozone Formation Induced by the Impact of Reactive Bromine and Iodine Species on Photochemistry in a Polluted Marine Environment M. Shechner & E. Tas 10.1021/acs.est.7b02860
- Natural halogens buffer tropospheric ozone in a changing climate F. Iglesias-Suarez et al. 10.1038/s41558-019-0675-6
- Initial dynamic photoactive materials testing of an atmospheric chamber intended for radioactive and hazardous gases N. Smith et al. 10.1557/s43580-023-00708-w
- Organic bromine compounds produced in sea ice in Antarctic winter K. Abrahamsson et al. 10.1038/s41467-018-07062-8
- Global Bromine- and Iodine-Mediated Tropospheric Ozone Loss Estimated Using the CHASER Chemical Transport Model T. Sekiya et al. 10.2151/sola.2020-037
- Interaction process between gaseous CH3I and NaCl particles: implication for iodine dispersion in the atmosphere H. Houjeij et al. 10.1039/D1EM00266J
- A theoretical study of the microhydration processes of iodine nitrogen oxides A. Villard et al. 10.1002/qua.25792
- Box modelling of gas-phase atmospheric iodine chemical reactivity in case of a nuclear accident C. Fortin et al. 10.1016/j.atmosenv.2019.116838
- Diurnal cycle of iodine, bromine, and mercury concentrations in Svalbard surface snow A. Spolaor et al. 10.5194/acp-19-13325-2019
- Chemical Interactions Between Ship‐Originated Air Pollutants and Ocean‐Emitted Halogens Q. Li et al. 10.1029/2020JD034175
- Influence of emission inventory resolution on the modeled spatio-temporal distribution of air pollutants in Buenos Aires, Argentina, using WRF-Chem A. López-Noreña et al. 10.1016/j.atmosenv.2021.118839
- Full latitudinal marine atmospheric measurements of iodine monoxide H. Takashima et al. 10.5194/acp-22-4005-2022
- Influence of Interfering Ions and Adsorption Temperature on Radioactive Iodine Removal Efficiency and Stability of Ni-MOF-74 and Zr-UiO-66 T. Alghamdi et al. 10.1021/acsami.3c05821
- Investigation of the Reaction Mechanism and Kinetics of Iodic Acid with OH Radical Using Quantum Chemistry S. Khanniche et al. 10.1021/acsearthspacechem.7b00038
- Direct field evidence of autocatalytic iodine release from atmospheric aerosol Y. Tham et al. 10.1073/pnas.2009951118
- Detoxification of arsenite by iodide in frozen solution Q. Nguyen et al. 10.1016/j.chemosphere.2023.139903
- Evidence for renoxification in the tropical marine boundary layer C. Reed et al. 10.5194/acp-17-4081-2017
- Enhanced Chlorine and Bromine Atom Activation by Hydrolysis of Halogen Nitrates from Marine Aerosols at Polluted Coastal Areas E. Hoffmann et al. 10.1021/acs.est.8b05165
- Modelling the impacts of iodine chemistry on the northern Indian Ocean marine boundary layer A. Mahajan et al. 10.5194/acp-21-8437-2021
- Equation-of-motion coupled-cluster theory based on the 4-component Dirac–Coulomb(–Gaunt) Hamiltonian. Energies for single electron detachment, attachment, and electronically excited states A. Shee et al. 10.1063/1.5053846
Latest update: 18 Apr 2024
Short summary
Electronic structure calculations are used to survey possible reactions that HOI and I2 could undergo at night in the lower troposphere, and hence reconcile measurements and models. The reactions NO3 + HOI and I2 + NO3 are included in two models to explore a new nocturnal iodine radical activation mechanism, leading to a reduction of nighttime HOI and I2. This chemistry can have a large impact on NO3 levels in the MBL, and hence upon the nocturnal oxidizing capacity of the marine atmosphere.
Electronic structure calculations are used to survey possible reactions that HOI and I2 could...
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