Articles | Volume 16, issue 23
https://doi.org/10.5194/acp-16-15397-2016
https://doi.org/10.5194/acp-16-15397-2016
Research article
 | 
12 Dec 2016
Research article |  | 12 Dec 2016

Heterogeneous reaction of ClONO2 with TiO2 and SiO2 aerosol particles: implications for stratospheric particle injection for climate engineering

Mingjin Tang, James Keeble, Paul J. Telford, Francis D. Pope, Peter Braesicke, Paul T. Griffiths, N. Luke Abraham, James McGregor, I. Matt Watson, R. Anthony Cox, John A. Pyle, and Markus Kalberer

Related authors

Measurement report: Atmospheric ice nuclei in the Changbai Mountains (2623 m a.s.l.) in northeastern Asia
Yue Sun, Yujiao Zhu, Yanbin Qi, Lanxiadi Chen, Jiangshan Mu, Ye Shan, Yu Yang, Yanqiu Nie, Ping Liu, Can Cui, Ji Zhang, Mingxuan Liu, Lingli Zhang, Yufei Wang, Xinfeng Wang, Mingjin Tang, Wenxing Wang, and Likun Xue
Atmos. Chem. Phys., 24, 3241–3256, https://doi.org/10.5194/acp-24-3241-2024,https://doi.org/10.5194/acp-24-3241-2024, 2024
Short summary
Aerosol trace element solubility determined using ultrapure water batch leaching: an intercomparison study of four different leaching protocols
Rui Li, Prema Piyusha Panda, Yizhu Chen, Zhenming Zhu, Fu Wang, Yujiao Zhu, He Meng, Yan Ren, Ashwini Kumar, and Mingjin Tang
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-26,https://doi.org/10.5194/amt-2024-26, 2024
Preprint under review for AMT
Short summary
A study on the influence of inorganic ions, organic carbon and microstructure on the hygroscopic property of soot
Zhanyu Su, Lanxiadi Chen, Yuan Liu, Peng Zhang, Tianzeng Chen, Biwu Chu, Mingjin Tang, Qingxin Ma, and Hong He
Atmos. Chem. Phys., 24, 993–1003, https://doi.org/10.5194/acp-24-993-2024,https://doi.org/10.5194/acp-24-993-2024, 2024
Short summary
Preface to the inter-journal special issue “RUSTED: Reducing Uncertainty in Soluble aerosol Trace Element Deposition”
Morgane M. G. Perron, Susanne Fietz, Douglas S. Hamilton, Akinori Ito, Rachel U. Shelley, and Mingjin Tang
Atmos. Meas. Tech., 17, 165–166, https://doi.org/10.5194/amt-17-165-2024,https://doi.org/10.5194/amt-17-165-2024, 2024
Short summary
Seasonal variation of aerosol iron solubility in coarse and fine particles at an inland city in northwestern China
Huanhuan Zhang, Rui Li, Chengpeng Huang, Xiaofei Li, Shuwei Dong, Fu Wang, Tingting Li, Yizhu Chen, Guohua Zhang, Yan Ren, Qingcai Chen, Ru-jin Huang, Siyu Chen, Tao Xue, Xinming Wang, and Mingjin Tang
Atmos. Chem. Phys., 23, 3543–3559, https://doi.org/10.5194/acp-23-3543-2023,https://doi.org/10.5194/acp-23-3543-2023, 2023
Short summary

Related subject area

Subject: Gases | Research Activity: Laboratory Studies | Altitude Range: Stratosphere | Science Focus: Chemistry (chemical composition and reactions)
Technical note: A method for calculating offsets to ozone depletion and climate impacts of ozone-depleting substances
Gabrielle B. Dreyfus, Stephen A. Montzka, Stephen O. Andersen, and Richard Ferris
Atmos. Chem. Phys., 24, 2023–2032, https://doi.org/10.5194/acp-24-2023-2024,https://doi.org/10.5194/acp-24-2023-2024, 2024
Short summary
Measurement report: Radiative efficiencies of (CF3)2CFCN, CF3OCFCF2, and CF3OCF2CF3
Beni Adi Trisna, Seungnam Park, Injun Park, Jeongsoon Lee, and Jeong Sik Lim
Atmos. Chem. Phys., 23, 4489–4500, https://doi.org/10.5194/acp-23-4489-2023,https://doi.org/10.5194/acp-23-4489-2023, 2023
Short summary
UV spectroscopic determination of the chlorine monoxide (ClO) ∕ chlorine peroxide (ClOOCl) thermal equilibrium constant
J. Eric Klobas and David M. Wilmouth
Atmos. Chem. Phys., 19, 6205–6215, https://doi.org/10.5194/acp-19-6205-2019,https://doi.org/10.5194/acp-19-6205-2019, 2019
Short summary
Global warming potential estimates for the C1–C3 hydrochlorofluorocarbons (HCFCs) included in the Kigali Amendment to the Montreal Protocol
Dimitrios K. Papanastasiou, Allison Beltrone, Paul Marshall, and James B. Burkholder
Atmos. Chem. Phys., 18, 6317–6330, https://doi.org/10.5194/acp-18-6317-2018,https://doi.org/10.5194/acp-18-6317-2018, 2018
Short summary
UV and infrared absorption spectra, atmospheric lifetimes, and ozone depletion and global warming potentials for CCl2FCCl2F (CFC-112), CCl3CClF2 (CFC-112a), CCl3CF3 (CFC-113a), and CCl2FCF3 (CFC-114a)
Maxine E. Davis, François Bernard, Max R. McGillen, Eric L. Fleming, and James B. Burkholder
Atmos. Chem. Phys., 16, 8043–8052, https://doi.org/10.5194/acp-16-8043-2016,https://doi.org/10.5194/acp-16-8043-2016, 2016
Short summary

Cited articles

Ammann, M., Cox, R. A., Crowley, J. N., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI – heterogeneous reactions with liquid substrates, Atmos. Chem. Phys., 13, 8045–8228, https://doi.org/10.5194/acp-13-8045-2013, 2013.
Anderson, L. C. and Fahey, D. W.: Studies with ClONO2: Thermal-dissociation rate and catalytic conversion to NO using an NO/O3 chemi-luminescence detector, J. Phys. Chem., 94, 644–652, 1990.
Ball, S. M., Fried, A., Henry, B. E., and Mozurkewich, M.: The hydrolysis of ClONO2 on sub-micron liquid sulfuric acid aerosol, Geophys. Res. Lett., 25, 3339–3342, 1998.
Ballard, J., Johnston, W. B., Gunson, M. R., and Wassell, P. T.: Absolute absorption coefficients of ClONO2 infrared bands at stratospheric temperatures, J. Geophys. Res.-Atmos, 93, 1659–1665, 1988.
Download
Short summary
We have investigated for the first time the heterogeneous hydrolysis of ClONO2 on TiO2 and SiO2 aerosol particles at room temperature and at different relative humidities (RHs), using an aerosol flow tube. The kinetic data reported in our current and previous studies have been included in the UKCA chemistry–climate model to assess the impact of TiO2 injection on stratospheric chemistry and stratospheric ozone in particular.
Altmetrics
Final-revised paper
Preprint