Articles | Volume 16, issue 19
https://doi.org/10.5194/acp-16-12531-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-12531-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Air–snow exchange of nitrate: a modelling approach to investigate physicochemical processes in surface snow at Dome C, Antarctica
Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich Research Park, Norfolk, NR4 7TJ, Norwich, UK
now at: Météo France, CNRM, Centre National de Recherches Météorologiques, UMR3589, 42 avenue G. Coriolis, 31057 Toulouse CEDEX 1, France
Joël Savarino
Université Grenoble Alpes, Laboratoire de Glaciologie et Géophysique de l'Environnement (LGGE), 38041 Grenoble, France
CNRS, LGGE UMR5183, 38041 Grenoble, France
Ghislain Picard
Université Grenoble Alpes, Laboratoire de Glaciologie et Géophysique de l'Environnement (LGGE), 38041 Grenoble, France
CNRS, LGGE UMR5183, 38041 Grenoble, France
Related authors
Matan Ben-Asher, Florence Magnin, Sebastian Westermann, Josué Bock, Emmanuel Malet, Johan Berthet, Ludovic Ravanel, and Philip Deline
Earth Surf. Dynam., 11, 899–915, https://doi.org/10.5194/esurf-11-899-2023, https://doi.org/10.5194/esurf-11-899-2023, 2023
Short summary
Short summary
Quantitative knowledge of water availability on high mountain rock slopes is very limited. We use a numerical model and field measurements to estimate the water balance at a steep rock wall site. We show that snowmelt is the main source of water at elevations >3600 m and that snowpack hydrology and sublimation are key factors. The new information presented here can be used to improve the understanding of thermal, hydrogeological, and mechanical processes on steep mountain rock slopes.
Josué Bock, Jan Kaiser, Max Thomas, Andreas Bott, and Roland von Glasow
Geosci. Model Dev., 15, 5807–5828, https://doi.org/10.5194/gmd-15-5807-2022, https://doi.org/10.5194/gmd-15-5807-2022, 2022
Short summary
Short summary
MISTRA-v9.0 is an atmospheric boundary layer chemistry model. The model includes a detailed particle description with regards to the microphysics, gas–particle interactions, and liquid phase chemistry within particles. Version 9.0 is the first release of MISTRA as an open-source community model. This paper presents a thorough description of the model characteristics and components. We show some examples of simulations reproducing previous studies with MISTRA with good consistency.
Josué Bock, Martine Michou, Pierre Nabat, Manabu Abe, Jane P. Mulcahy, Dirk J. L. Olivié, Jörg Schwinger, Parvadha Suntharalingam, Jerry Tjiputra, Marco van Hulten, Michio Watanabe, Andrew Yool, and Roland Séférian
Biogeosciences, 18, 3823–3860, https://doi.org/10.5194/bg-18-3823-2021, https://doi.org/10.5194/bg-18-3823-2021, 2021
Short summary
Short summary
In this study we analyse surface ocean dimethylsulfide (DMS) concentration and flux to the atmosphere from four CMIP6 Earth system models over the historical and ssp585 simulations.
Our analysis of contemporary (1980–2009) climatologies shows that models better reproduce observations in mid to high latitudes. The models disagree on the sign of the trend of the global DMS flux from 1980 onwards. The models agree on a positive trend of DMS over polar latitudes following sea-ice retreat dynamics.
Naomi E. Ochwat, Ted A. Scambos, Alison F. Banwell, Robert S. Anderson, Michelle L. Maclennan, Ghislain Picard, Julia A. Shates, Sebastian Marinsek, Liliana Margonari, Martin Truffer, and Erin C. Pettit
The Cryosphere, 18, 1709–1731, https://doi.org/10.5194/tc-18-1709-2024, https://doi.org/10.5194/tc-18-1709-2024, 2024
Short summary
Short summary
On the Antarctic Peninsula, there is a small bay that had sea ice fastened to the shoreline (
fast ice) for over a decade. The fast ice stabilized the glaciers that fed into the ocean. In January 2022, the fast ice broke away. Using satellite data we found that this was because of low sea ice concentrations and a high long-period ocean wave swell. We find that the glaciers have responded to this event by thinning, speeding up, and retreating by breaking off lots of icebergs at remarkable rates.
Inès Ollivier, Hans Christian Steen-Larsen, Barbara Stenni, Laurent Arnaud, Mathieu Casado, Alexandre Cauquoin, Giuliano Dreossi, Christophe Genthon, Bénédicte Minster, Ghislain Picard, Martin Werner, and Amaëlle Landais
EGUsphere, https://doi.org/10.5194/egusphere-2024-685, https://doi.org/10.5194/egusphere-2024-685, 2024
Short summary
Short summary
The role of post-depositional processes taking place at the ice sheet's surface on the water stable isotope signal measured in polar ice cores is not fully understood. Using field observations and modelling results, we show that the original precipitation isotopic signal at Dome C, East Antarctica, is modified by post-depositional processes and provide the first quantitative estimation of their mean impact on the isotopic signal observed in the snow.
Justin Murfitt, Claude Duguay, Ghislain Picard, and Juha Lemmetyinen
The Cryosphere, 18, 869–888, https://doi.org/10.5194/tc-18-869-2024, https://doi.org/10.5194/tc-18-869-2024, 2024
Short summary
Short summary
This research focuses on the interaction between microwave signals and lake ice under wet conditions. Field data collected for Lake Oulujärvi in Finland were used to model backscatter under different conditions. The results of the modelling likely indicate that a combination of increased water content and roughness of different interfaces caused backscatter to increase. These results could help to identify areas where lake ice is unsafe for winter transportation.
Sara Arioli, Ghislain Picard, Laurent Arnaud, Simon Gascoin, Esteban Alonso-González, Marine Poizat, and Mark Irvine
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-55, https://doi.org/10.5194/essd-2024-55, 2024
Preprint under review for ESSD
Short summary
Short summary
High accuracy and precision maps of the surface temperature of snow were acquired with an uncooled thermal infrared camera during winter 2021–2022 and spring 2023. The accuracy -mean absolute error- improved from 1.28 K to 0.67 K between the seasons thanks to an improved camera setup and temperature stabilization. The dataset represents a major advance in order to validate satellite measurements and physical snow models over complex topography.
Claudio Stefanini, Giovanni Macelloni, Marion Leduc-Leballeur, Vincent Favier, Benjamin Pohl, and Ghislain Picard
The Cryosphere, 18, 593–608, https://doi.org/10.5194/tc-18-593-2024, https://doi.org/10.5194/tc-18-593-2024, 2024
Short summary
Short summary
Local and large-scale meteorological conditions have been considered in order to explain some peculiar changes of snow grains on the East Antarctic Plateau from 2000 to 2022, by using remote sensing observations and reanalysis. We identified some extreme grain size events on the highest ice divide, resulting from a combination of conditions of low wind speed and low temperature. Moreover, the beginning of seasonal grain growth has been linked to the occurrence of atmospheric rivers.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, Roberto Grilli, Quentin Fournier, Irène Ventrillard, Nicolas Caillon, and Kathy Law
Atmos. Chem. Phys., 24, 1361–1388, https://doi.org/10.5194/acp-24-1361-2024, https://doi.org/10.5194/acp-24-1361-2024, 2024
Short summary
Short summary
This study reports the first simultaneous records of oxygen (Δ17O) and nitrogen (δ15N) isotopes in nitrogen dioxide (NO2) and nitrate (NO3−). These data are combined with atmospheric observations to explore sub-daily N reactive chemistry and quantify N fractionation effects in an Alpine winter city. The results highlight the necessity of using Δ17O and δ15N in both NO2 and NO3− to avoid biased estimations of NOx sources and fates from NO3− isotopic records in urban winter environments.
Romilly Harris Stuart, Amaëlle Landais, Laurent Arnaud, Christo Buizert, Emilie Capron, Marie Dumont, Quentin Libois, Robert Mulvaney, Anaïs Orsi, Ghislain Picard, Frédéric Prié, Jeffery Severinghaus, Barbara Stenni, and Patricia Martinerie
EGUsphere, https://doi.org/10.5194/egusphere-2023-2585, https://doi.org/10.5194/egusphere-2023-2585, 2023
Short summary
Short summary
The influence of local accumulation rate and temperature on δO2/N2 ice core records, a key dating tool, are not fully understood, but required for a full mechanistic understanding. We show evidence that mean δO2/N2 is strongly dependent on local accumulation rate and temperature, in addition to the well documented insolation dependence. Snowpack modelling is used to investigate which physical properties drive the mechanistic dependence on these local parameters.
V. Holly L. Winton, Robert Mulvaney, Joel Savarino, Kyle R. Clem, and Markus M. Frey
Clim. Past Discuss., https://doi.org/10.5194/cp-2023-96, https://doi.org/10.5194/cp-2023-96, 2023
Revised manuscript accepted for CP
Short summary
Short summary
In 2018, a new 120 m ice core was drilled in a region located under the Antarctic ozone hole. We present the first results including a 1300-year record of snow accumulation and aerosol chemistry. We investigate the aerosol and moisture source regions and atmospheric processes related to the ice core record and discuss what this means for developing a record of past ultraviolet-radiation and ozone depletion using the stable isotopic composition of nitrate measured in the same ice core.
Jean Emmanuel Sicart, Victor Ramseyer, Ghislain Picard, Laurent Arnaud, Catherine Coulaud, Guilhem Freche, Damien Soubeyrand, Yves Lejeune, Marie Dumont, Isabelle Gouttevin, Erwan Le Gac, Frédéric Berger, Jean-Matthieu Monnet, Laurent Borgniet, Éric Mermin, Nick Rutter, Clare Webster, and Richard Essery
Earth Syst. Sci. Data, 15, 5121–5133, https://doi.org/10.5194/essd-15-5121-2023, https://doi.org/10.5194/essd-15-5121-2023, 2023
Short summary
Short summary
Forests strongly modify the accumulation, metamorphism and melting of snow in midlatitude and high-latitude regions. Two field campaigns during the winters 2016–17 and 2017–18 were conducted in a coniferous forest in the French Alps to study interactions between snow and vegetation. This paper presents the field site, instrumentation and collection methods. The observations include forest characteristics, meteorology, snow cover and snow interception by the canopy during precipitation events.
Thomas Dethinne, Quentin Glaude, Ghislain Picard, Christoph Kittel, Patrick Alexander, Anne Orban, and Xavier Fettweis
The Cryosphere, 17, 4267–4288, https://doi.org/10.5194/tc-17-4267-2023, https://doi.org/10.5194/tc-17-4267-2023, 2023
Short summary
Short summary
We investigate the sensitivity of the regional climate model
Modèle Atmosphérique Régional(MAR) to the assimilation of wet-snow occurrence estimated by remote sensing datasets. The assimilation is performed by nudging the MAR snowpack temperature. The data assimilation is performed over the Antarctic Peninsula for the 2019–2021 period. The results show an increase in the melt production (+66.7 %) and a decrease in surface mass balance (−4.5 %) of the model for the 2019–2020 melt season.
Matan Ben-Asher, Florence Magnin, Sebastian Westermann, Josué Bock, Emmanuel Malet, Johan Berthet, Ludovic Ravanel, and Philip Deline
Earth Surf. Dynam., 11, 899–915, https://doi.org/10.5194/esurf-11-899-2023, https://doi.org/10.5194/esurf-11-899-2023, 2023
Short summary
Short summary
Quantitative knowledge of water availability on high mountain rock slopes is very limited. We use a numerical model and field measurements to estimate the water balance at a steep rock wall site. We show that snowmelt is the main source of water at elevations >3600 m and that snowpack hydrology and sublimation are key factors. The new information presented here can be used to improve the understanding of thermal, hydrogeological, and mechanical processes on steep mountain rock slopes.
Alexis Lamothe, Joel Savarino, Patrick Ginot, Lison Soussaintjean, Elsa Gautier, Pete D. Akers, Nicolas Caillon, and Joseph Erbland
Atmos. Meas. Tech., 16, 4015–4030, https://doi.org/10.5194/amt-16-4015-2023, https://doi.org/10.5194/amt-16-4015-2023, 2023
Short summary
Short summary
Ammonia is a reactive gas in our atmosphere that is key in air quality issues. Assessing its emissions and how it reacts is a hot topic that can be addressed from the past. Stable isotopes (the mass of the molecule) measured in ice cores (glacial archives) can teach us a lot. However, the concentrations in ice cores are very small. We propose a protocol to limit the contamination and apply it to one ice core drilled in Mont Blanc, describing the opportunities our method brings.
Yaowen Zheng, Nicholas R. Golledge, Alexandra Gossart, Ghislain Picard, and Marion Leduc-Leballeur
The Cryosphere, 17, 3667–3694, https://doi.org/10.5194/tc-17-3667-2023, https://doi.org/10.5194/tc-17-3667-2023, 2023
Short summary
Short summary
Positive degree-day (PDD) schemes are widely used in many Antarctic numerical ice sheet models. However, the PDD approach has not been systematically explored for its application in Antarctica. We have constructed a novel grid-cell-level spatially distributed PDD (dist-PDD) model and assessed its accuracy. We suggest that an appropriately parameterized dist-PDD model can be a valuable tool for exploring Antarctic surface melt beyond the satellite era.
Esteban Alonso-González, Simon Gascoin, Sara Arioli, and Ghislain Picard
The Cryosphere, 17, 3329–3342, https://doi.org/10.5194/tc-17-3329-2023, https://doi.org/10.5194/tc-17-3329-2023, 2023
Short summary
Short summary
Data assimilation techniques are a promising approach to improve snowpack simulations in remote areas that are difficult to monitor. This paper studies the ability of satellite-observed land surface temperature to improve snowpack simulations through data assimilation. We show that it is possible to improve snowpack simulations, but the temporal resolution of the observations and the algorithm used are critical to obtain satisfactory results.
Zhuang Jiang, Becky Alexander, Joel Savarino, and Lei Geng
EGUsphere, https://doi.org/10.5194/egusphere-2023-1054, https://doi.org/10.5194/egusphere-2023-1054, 2023
Short summary
Short summary
Ice-core nitrate could track the past atmospheric NOx and oxidant level, but its interpretation is hampered by the post-depositional processing. In this work, an inverse model was developed and tested against two polar sites, and was shown to well reproduce the observed nitrate signals in snow and atmosphere, suggesting that the model can properly correct for the effect of post-depositional processing. This model offers a very useful tool for future studies on ice-core nitrate records.
Sara Arioli, Ghislain Picard, Laurent Arnaud, and Vincent Favier
The Cryosphere, 17, 2323–2342, https://doi.org/10.5194/tc-17-2323-2023, https://doi.org/10.5194/tc-17-2323-2023, 2023
Short summary
Short summary
To assess the drivers of the snow grain size evolution during snow drift, we exploit a 5-year time series of the snow grain size retrieved from spectral-albedo observations made with a new, autonomous, multi-band radiometer and compare it to observations of snow drift, snowfall and snowmelt at a windy location of coastal Antarctica. Our results highlight the complexity of the grain size evolution in the presence of snow drift and show an overall tendency of snow drift to limit its variations.
Simone Ventisette, Samuele Baldini, Claudio Artoni, Silvia Becagli, Laura Caiazzo, Barbara Delmonte, Massimo Frezzotti, Raffaello Nardin, Joel Savarino, Mirko Severi, Andrea Spolaor, Barbara Stenni, and Rita Traversi
EGUsphere, https://doi.org/10.5194/egusphere-2023-393, https://doi.org/10.5194/egusphere-2023-393, 2023
Preprint archived
Short summary
Short summary
The paper reports the spatial variability of concentration and fluxes of chemical impurities in superficial snow over unexplored area of the East Antarctic ice sheet. Pinatubo and Puyehue-Cordón Caulle volcanic eruptions in non-sea salt sulfate and dust snow pits record were used to achieve the accumulation rates. Deposition (wet, dry and uptake from snow surface) and post deposition processes are constrained. These knowledges are fundamental in Antarctic ice cores stratigraphies interpretation.
Melody Sandells, Nick Rutter, Kirsty Wivell, Richard Essery, Stuart Fox, Chawn Harlow, Ghislain Picard, Alexandre Roy, Alain Royer, and Peter Toose
EGUsphere, https://doi.org/10.5194/egusphere-2023-696, https://doi.org/10.5194/egusphere-2023-696, 2023
Short summary
Short summary
Satellite microwave observations are used for weather forecasting. In Arctic regions this is complicated by natural emission from the snow. By simulating airborne observations from in situ measurements of snow, this study shows how snow properties affect the signal within the atmosphere. Fresh snowfall between flights changed the airborne measurements. Good knowledge of snow layering and structure can be used to account for the effects of snow, and could unlock these data to improve forecasts.
Ghislain Picard, Marion Leduc-Leballeur, Alison F. Banwell, Ludovic Brucker, and Giovanni Macelloni
The Cryosphere, 16, 5061–5083, https://doi.org/10.5194/tc-16-5061-2022, https://doi.org/10.5194/tc-16-5061-2022, 2022
Short summary
Short summary
Using a snowpack radiative transfer model, we investigate in which conditions meltwater can be detected from passive microwave satellite observations from 1.4 to 37 GHz. In particular, we determine the minimum detectable liquid water content, the maximum depth of detection of a buried wet snow layer and the risk of false alarm due to supraglacial lakes. These results provide information for the developers of new, more advanced satellite melt products and for the users of the existing products.
Pete D. Akers, Joël Savarino, Nicolas Caillon, Olivier Magand, and Emmanuel Le Meur
Atmos. Chem. Phys., 22, 15637–15657, https://doi.org/10.5194/acp-22-15637-2022, https://doi.org/10.5194/acp-22-15637-2022, 2022
Short summary
Short summary
Nitrate isotopes in Antarctic ice do not preserve the seasonal isotopic cycles of the atmosphere, which limits their use to study the past. We studied nitrate along an 850 km Antarctic transect to learn how these cycles are changed by sunlight-driven chemistry in the snow. Our findings suggest that the snow accumulation rate and other environmental signals can be extracted from nitrate with the right sampling and analytical approaches.
Dominic Saunderson, Andrew Mackintosh, Felicity McCormack, Richard Selwyn Jones, and Ghislain Picard
The Cryosphere, 16, 4553–4569, https://doi.org/10.5194/tc-16-4553-2022, https://doi.org/10.5194/tc-16-4553-2022, 2022
Short summary
Short summary
We investigate the variability in surface melt on the Shackleton Ice Shelf in East Antarctica over the last 2 decades (2003–2021). Using daily satellite observations and the machine learning approach of a self-organising map, we identify nine distinct spatial patterns of melt. These patterns allow comparisons of melt within and across melt seasons and highlight the importance of both air temperatures and local controls such as topography, katabatic winds, and albedo in driving surface melt.
Yanzhi Cao, Zhuang Jiang, Becky Alexander, Jihong Cole-Dai, Joel Savarino, Joseph Erbland, and Lei Geng
Atmos. Chem. Phys., 22, 13407–13422, https://doi.org/10.5194/acp-22-13407-2022, https://doi.org/10.5194/acp-22-13407-2022, 2022
Short summary
Short summary
We investigate the potential of ice-core preserved nitrate isotopes as proxies of stratospheric ozone variability by measuring nitrate isotopes in a shallow ice core from the South Pole. The large variability in the snow accumulation rate and its slight increase after the 1970s masked any signals caused by the ozone hole. Moreover, the nitrate oxygen isotope decrease may reflect changes in the atmospheric oxidation environment in the Southern Ocean.
Ghislain Picard, Henning Löwe, and Christian Mätzler
The Cryosphere, 16, 3861–3866, https://doi.org/10.5194/tc-16-3861-2022, https://doi.org/10.5194/tc-16-3861-2022, 2022
Short summary
Short summary
Microwave satellite observations used to monitor the cryosphere require radiative transfer models for their interpretation. These models represent how microwaves are scattered by snow and ice. However no existing theory is suitable for all types of snow and ice found on Earth. We adapted a recently published generic scattering theory to snow and show how it may improve the representation of snows with intermediate densities (~500 kg/m3) and/or with coarse grains at high microwave frequencies.
Albane Barbero, Roberto Grilli, Markus M. Frey, Camille Blouzon, Detlev Helmig, Nicolas Caillon, and Joël Savarino
Atmos. Chem. Phys., 22, 12025–12054, https://doi.org/10.5194/acp-22-12025-2022, https://doi.org/10.5194/acp-22-12025-2022, 2022
Short summary
Short summary
The high reactivity of the summer Antarctic boundary layer results in part from the emissions of nitrogen oxides produced during photo-denitrification of the snowpack, but its underlying mechanisms are not yet fully understood. The results of this study suggest that more NO2 is produced from the snowpack early in the photolytic season, possibly due to stronger UV irradiance caused by a smaller solar zenith angle near the solstice.
Gauthier Vérin, Florent Domine, Marcel Babin, Ghislain Picard, and Laurent Arnaud
The Cryosphere, 16, 3431–3449, https://doi.org/10.5194/tc-16-3431-2022, https://doi.org/10.5194/tc-16-3431-2022, 2022
Short summary
Short summary
Snow physical properties on Arctic sea ice are monitored during the melt season. As snow grains grow, and the snowpack thickness is reduced, the surface albedo decreases. The extra absorbed energy accelerates melting. Radiative transfer modeling shows that more radiation is then transmitted to the snow–sea-ice interface. A sharp increase in transmitted radiation takes place when the snowpack thins significantly, and this coincides with the initiation of the phytoplankton bloom in the seawater.
Josué Bock, Jan Kaiser, Max Thomas, Andreas Bott, and Roland von Glasow
Geosci. Model Dev., 15, 5807–5828, https://doi.org/10.5194/gmd-15-5807-2022, https://doi.org/10.5194/gmd-15-5807-2022, 2022
Short summary
Short summary
MISTRA-v9.0 is an atmospheric boundary layer chemistry model. The model includes a detailed particle description with regards to the microphysics, gas–particle interactions, and liquid phase chemistry within particles. Version 9.0 is the first release of MISTRA as an open-source community model. This paper presents a thorough description of the model characteristics and components. We show some examples of simulations reproducing previous studies with MISTRA with good consistency.
Zhuang Jiang, Joel Savarino, Becky Alexander, Joseph Erbland, Jean-Luc Jaffrezo, and Lei Geng
The Cryosphere, 16, 2709–2724, https://doi.org/10.5194/tc-16-2709-2022, https://doi.org/10.5194/tc-16-2709-2022, 2022
Short summary
Short summary
A record of year-round atmospheric nitrate isotopic composition along with snow nitrate isotopic data from Summit, Greenland, revealed apparent enrichments in nitrogen isotopes in snow nitrate compared to atmospheric nitrate, in addition to a relatively smaller degree of changes in oxygen isotopes. The results suggest that at this site post-depositional processing takes effect, which should be taken into account when interpreting ice-core nitrate isotope records.
Saehee Lim, Meehye Lee, Joel Savarino, and Paolo Laj
Atmos. Chem. Phys., 22, 5099–5115, https://doi.org/10.5194/acp-22-5099-2022, https://doi.org/10.5194/acp-22-5099-2022, 2022
Short summary
Short summary
We determined δ15N(NO3−) and Δ17O(NO3−) of PM2.5 in Seoul during 2018–2019 and estimated quantitatively the contribution of oxidation pathways to NO3− formation and NOx emission sources. The nighttime pathway played a significant role in NO3− formation during the winter, and its contribution further increased up to 70 % on haze days when PM2.5 was greater than 75 µg m−3. Vehicle emissions were confirmed as a main NO3− source with an increasing contribution from coal combustion in winter.
Alvaro Robledano, Ghislain Picard, Laurent Arnaud, Fanny Larue, and Inès Ollivier
The Cryosphere, 16, 559–579, https://doi.org/10.5194/tc-16-559-2022, https://doi.org/10.5194/tc-16-559-2022, 2022
Short summary
Short summary
Topography controls the surface temperature of snow-covered, mountainous areas. We developed a modelling chain that uses ray-tracing methods to quantify the impact of a few topographic effects on snow surface temperature at high spatial resolution. Its large spatial and temporal variations are correctly simulated over a 50 km2 area in the French Alps, and our results show that excluding a single topographic effect results in cooling (or warming) effects on the order of 1 °C.
Maria Belke-Brea, Florent Domine, Ghislain Picard, Mathieu Barrere, and Laurent Arnaud
Biogeosciences, 18, 5851–5869, https://doi.org/10.5194/bg-18-5851-2021, https://doi.org/10.5194/bg-18-5851-2021, 2021
Short summary
Short summary
Expanding shrubs in the Arctic change snowpacks into a mix of snow, impurities and buried branches. Snow is a translucent medium into which light penetrates and gets partly absorbed by branches or impurities. Measurements of light attenuation in snow in Northern Quebec, Canada, showed (1) black-carbon-dominated light attenuation in snowpacks without shrubs and (2) buried branches influence radiation attenuation in snow locally, leading to melting and pockets of large crystals close to branches.
Laura Crick, Andrea Burke, William Hutchison, Mika Kohno, Kathryn A. Moore, Joel Savarino, Emily A. Doyle, Sue Mahony, Sepp Kipfstuhl, James W. B. Rae, Robert C. J. Steele, R. Stephen J. Sparks, and Eric W. Wolff
Clim. Past, 17, 2119–2137, https://doi.org/10.5194/cp-17-2119-2021, https://doi.org/10.5194/cp-17-2119-2021, 2021
Short summary
Short summary
The ~ 74 ka eruption of Toba was one of the largest eruptions of the last 100 ka. We have measured the sulfur isotopic composition for 11 Toba eruption candidates in two Antarctic ice cores. Sulfur isotopes allow us to distinguish between large eruptions that have erupted material into the stratosphere and smaller ones that reach lower altitudes. Using this we have identified the events most likely to be Toba and place the eruption on the transition into a cold period in the Northern Hemisphere.
Zhuang Jiang, Becky Alexander, Joel Savarino, Joseph Erbland, and Lei Geng
The Cryosphere, 15, 4207–4220, https://doi.org/10.5194/tc-15-4207-2021, https://doi.org/10.5194/tc-15-4207-2021, 2021
Short summary
Short summary
We used a snow photochemistry model (TRANSITS) to simulate the seasonal nitrate snow profile at Summit, Greenland. Comparisons between model outputs and observations suggest that at Summit post-depositional processing is active and probably dominates the snowpack δ15N seasonality. We also used the model to assess the degree of snow nitrate loss and the consequences in its isotopes at present and in the past, which helps for quantitative interpretations of ice-core nitrate records.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, and Nicolas Caillon
Atmos. Chem. Phys., 21, 10477–10497, https://doi.org/10.5194/acp-21-10477-2021, https://doi.org/10.5194/acp-21-10477-2021, 2021
Short summary
Short summary
We report an efficient method to collect atmospheric NO2 adapted for multi-isotopic analysis and present the first NO2 triple oxygen and double nitrogen isotope measurements. Atmospheric samplings carried out in Grenoble, France, highlight the NO2 isotopic signature sensitivity to the local NOx emissions and chemical regimes. These preliminary results are very promising for using the combination of Δ17O and δ15N of NO2 as a probe of the atmospheric NOx emissions and chemistry.
Josué Bock, Martine Michou, Pierre Nabat, Manabu Abe, Jane P. Mulcahy, Dirk J. L. Olivié, Jörg Schwinger, Parvadha Suntharalingam, Jerry Tjiputra, Marco van Hulten, Michio Watanabe, Andrew Yool, and Roland Séférian
Biogeosciences, 18, 3823–3860, https://doi.org/10.5194/bg-18-3823-2021, https://doi.org/10.5194/bg-18-3823-2021, 2021
Short summary
Short summary
In this study we analyse surface ocean dimethylsulfide (DMS) concentration and flux to the atmosphere from four CMIP6 Earth system models over the historical and ssp585 simulations.
Our analysis of contemporary (1980–2009) climatologies shows that models better reproduce observations in mid to high latitudes. The models disagree on the sign of the trend of the global DMS flux from 1980 onwards. The models agree on a positive trend of DMS over polar latitudes following sea-ice retreat dynamics.
Alison F. Banwell, Rajashree Tri Datta, Rebecca L. Dell, Mahsa Moussavi, Ludovic Brucker, Ghislain Picard, Christopher A. Shuman, and Laura A. Stevens
The Cryosphere, 15, 909–925, https://doi.org/10.5194/tc-15-909-2021, https://doi.org/10.5194/tc-15-909-2021, 2021
Short summary
Short summary
Ice shelves are thick floating layers of glacier ice extending from the glaciers on land that buttress much of the Antarctic Ice Sheet and help to protect it from losing ice to the ocean. However, the stability of ice shelves is vulnerable to meltwater lakes that form on their surfaces during the summer. This study focuses on the northern George VI Ice Shelf on the western side of the AP, which had an exceptionally long and extensive melt season in 2019/2020 compared to the previous 31 seasons.
François Tuzet, Marie Dumont, Ghislain Picard, Maxim Lamare, Didier Voisin, Pierre Nabat, Mathieu Lafaysse, Fanny Larue, Jesus Revuelto, and Laurent Arnaud
The Cryosphere, 14, 4553–4579, https://doi.org/10.5194/tc-14-4553-2020, https://doi.org/10.5194/tc-14-4553-2020, 2020
Short summary
Short summary
This study presents a field dataset collected over 30 d from two snow seasons at a Col du Lautaret site (French Alps). The dataset compares different measurements or estimates of light-absorbing particle (LAP) concentrations in snow, highlighting a gap in the current understanding of the measurement of these quantities. An ensemble snowpack model is then evaluated for this dataset estimating that LAPs shorten each snow season by around 10 d despite contrasting meteorological conditions.
Maxim Lamare, Marie Dumont, Ghislain Picard, Fanny Larue, François Tuzet, Clément Delcourt, and Laurent Arnaud
The Cryosphere, 14, 3995–4020, https://doi.org/10.5194/tc-14-3995-2020, https://doi.org/10.5194/tc-14-3995-2020, 2020
Short summary
Short summary
Terrain features found in mountainous regions introduce large errors into the calculation of the physical properties of snow using optical satellite images. We present a new model performing rapid calculations of solar radiation over snow-covered rugged terrain that we tested over a site in the French Alps. The results of the study show that all the interactions between sunlight and the terrain should be accounted for over snow-covered surfaces to correctly estimate snow properties from space.
Albane Barbero, Camille Blouzon, Joël Savarino, Nicolas Caillon, Aurélien Dommergue, and Roberto Grilli
Atmos. Meas. Tech., 13, 4317–4331, https://doi.org/10.5194/amt-13-4317-2020, https://doi.org/10.5194/amt-13-4317-2020, 2020
Short summary
Short summary
In this paper, we present a compact, affordable and robust instrument for in situ measurements of different trace gases: NOx, IO, CHOCHO and O3 with very low detection limits. The device weighs 15 kg and has a total electrical power consumption of < 300 W. Its very low detection limits and its design make it suitable for field applications to address different questions such as how to better constrain the oxidative capacity of the atmosphere and study the chemistry of highly reactive species.
Fanny Larue, Ghislain Picard, Laurent Arnaud, Inès Ollivier, Clément Delcourt, Maxim Lamare, François Tuzet, Jesus Revuelto, and Marie Dumont
The Cryosphere, 14, 1651–1672, https://doi.org/10.5194/tc-14-1651-2020, https://doi.org/10.5194/tc-14-1651-2020, 2020
Short summary
Short summary
The effect of surface roughness on snow albedo is often overlooked,
although a small change in albedo may strongly affect the surface energy
budget. By carving artificial roughness in an initially smooth snowpack,
we highlight albedo reductions of 0.03–0.04 at 700 nm and 0.06–0.10 at 1000 nm. A model using photon transport is developed to compute albedo considering roughness and applied to understand the impact of roughness as a function of snow properties and illumination conditions.
V. Holly L. Winton, Alison Ming, Nicolas Caillon, Lisa Hauge, Anna E. Jones, Joel Savarino, Xin Yang, and Markus M. Frey
Atmos. Chem. Phys., 20, 5861–5885, https://doi.org/10.5194/acp-20-5861-2020, https://doi.org/10.5194/acp-20-5861-2020, 2020
Short summary
Short summary
The transfer of the nitrogen stable isotopic composition in nitrate between the air and snow at low accumulation sites in Antarctica leaves an UV imprint in the snow. Quantifying how nitrate isotope values change allows us to interpret longer ice core records. Based on nitrate observations and modelling at Kohnen, East Antarctica, the dominant factors controlling the nitrate isotope signature in deep snow layers are the depth of light penetration into the snowpack and the snow accumulation rate.
Ghislain Picard, Marie Dumont, Maxim Lamare, François Tuzet, Fanny Larue, Roberta Pirazzini, and Laurent Arnaud
The Cryosphere, 14, 1497–1517, https://doi.org/10.5194/tc-14-1497-2020, https://doi.org/10.5194/tc-14-1497-2020, 2020
Short summary
Short summary
Surface albedo is an essential variable of snow-covered areas. The measurement of this variable over a tilted terrain with levelled sensors is affected by artefacts that need to be corrected. Here we develop a theory of spectral albedo measurement over slopes from which we derive four correction algorithms. The comparison to in situ measurements taken in the Alps shows the adequacy of the theory, and the application of the algorithms shows systematic improvements.
Marion Leduc-Leballeur, Ghislain Picard, Giovanni Macelloni, Arnaud Mialon, and Yann H. Kerr
The Cryosphere, 14, 539–548, https://doi.org/10.5194/tc-14-539-2020, https://doi.org/10.5194/tc-14-539-2020, 2020
Short summary
Short summary
To study the coast and ice shelves affected by melt in Antarctica during the austral summer, we exploited the 1.4 GHz radiometric satellite observations. We showed that this frequency provides additional information on melt occurrence and on the location of the water in the snowpack compared to the 19 GHz observations. This opens an avenue for improving the melting season monitoring with a combination of both frequencies and exploring the possibility of deep-water detection in the snowpack.
Philippe Massicotte, Rémi Amiraux, Marie-Pier Amyot, Philippe Archambault, Mathieu Ardyna, Laurent Arnaud, Lise Artigue, Cyril Aubry, Pierre Ayotte, Guislain Bécu, Simon Bélanger, Ronald Benner, Henry C. Bittig, Annick Bricaud, Éric Brossier, Flavienne Bruyant, Laurent Chauvaud, Debra Christiansen-Stowe, Hervé Claustre, Véronique Cornet-Barthaux, Pierre Coupel, Christine Cox, Aurelie Delaforge, Thibaud Dezutter, Céline Dimier, Florent Domine, Francis Dufour, Christiane Dufresne, Dany Dumont, Jens Ehn, Brent Else, Joannie Ferland, Marie-Hélène Forget, Louis Fortier, Martí Galí, Virginie Galindo, Morgane Gallinari, Nicole Garcia, Catherine Gérikas Ribeiro, Margaux Gourdal, Priscilla Gourvil, Clemence Goyens, Pierre-Luc Grondin, Pascal Guillot, Caroline Guilmette, Marie-Noëlle Houssais, Fabien Joux, Léo Lacour, Thomas Lacour, Augustin Lafond, José Lagunas, Catherine Lalande, Julien Laliberté, Simon Lambert-Girard, Jade Larivière, Johann Lavaud, Anita LeBaron, Karine Leblanc, Florence Le Gall, Justine Legras, Mélanie Lemire, Maurice Levasseur, Edouard Leymarie, Aude Leynaert, Adriana Lopes dos Santos, Antonio Lourenço, David Mah, Claudie Marec, Dominique Marie, Nicolas Martin, Constance Marty, Sabine Marty, Guillaume Massé, Atsushi Matsuoka, Lisa Matthes, Brivaela Moriceau, Pierre-Emmanuel Muller, Christopher-John Mundy, Griet Neukermans, Laurent Oziel, Christos Panagiotopoulos, Jean-Jacques Pangrazi, Ghislain Picard, Marc Picheral, France Pinczon du Sel, Nicole Pogorzelec, Ian Probert, Bernard Quéguiner, Patrick Raimbault, Joséphine Ras, Eric Rehm, Erin Reimer, Jean-François Rontani, Søren Rysgaard, Blanche Saint-Béat, Makoto Sampei, Julie Sansoulet, Catherine Schmechtig, Sabine Schmidt, Richard Sempéré, Caroline Sévigny, Yuan Shen, Margot Tragin, Jean-Éric Tremblay, Daniel Vaulot, Gauthier Verin, Frédéric Vivier, Anda Vladoiu, Jeremy Whitehead, and Marcel Babin
Earth Syst. Sci. Data, 12, 151–176, https://doi.org/10.5194/essd-12-151-2020, https://doi.org/10.5194/essd-12-151-2020, 2020
Short summary
Short summary
The Green Edge initiative was developed to understand the processes controlling the primary productivity and the fate of organic matter produced during the Arctic spring bloom (PSB). In this article, we present an overview of an extensive and comprehensive dataset acquired during two expeditions conducted in 2015 and 2016 on landfast ice southeast of Qikiqtarjuaq Island in Baffin Bay.
Detlev Helmig, Daniel Liptzin, Jacques Hueber, and Joel Savarino
The Cryosphere, 14, 199–209, https://doi.org/10.5194/tc-14-199-2020, https://doi.org/10.5194/tc-14-199-2020, 2020
Short summary
Short summary
We present 15 months of trace gas observations from air withdrawn within the snowpack and from above the snow at Concordia Station in Antarctica. The data show occasional positive spikes, indicative of pollution from the station generator. The pollution signal can be seen in snowpack air shortly after it is observed above the snow surface, and lasting for up to several days, much longer than above the surface.
Christiaan T. van Dalum, Willem Jan van de Berg, Quentin Libois, Ghislain Picard, and Michiel R. van den Broeke
Geosci. Model Dev., 12, 5157–5175, https://doi.org/10.5194/gmd-12-5157-2019, https://doi.org/10.5194/gmd-12-5157-2019, 2019
Short summary
Short summary
Climate models are often limited to relatively simple snow albedo schemes. Therefore, we have developed the SNOWBAL module to couple a climate model with a physically based wavelength dependent snow albedo model. Using SNOWBAL v1.2 to couple the snow albedo model TARTES with the regional climate model RACMO2 indicates a potential performance gain for the Greenland ice sheet.
Francois Tuzet, Marie Dumont, Laurent Arnaud, Didier Voisin, Maxim Lamare, Fanny Larue, Jesus Revuelto, and Ghislain Picard
The Cryosphere, 13, 2169–2187, https://doi.org/10.5194/tc-13-2169-2019, https://doi.org/10.5194/tc-13-2169-2019, 2019
Short summary
Short summary
Here we present a novel method to estimate the impurity content (e.g. black carbon or mineral dust) in Alpine snow based on measurements of light extinction profiles. This method is proposed as an alternative to chemical measurements, allowing rapid retrievals of vertical concentrations of impurities in the snowpack. In addition, the results provide a better understanding of the impact of impurities on visible light extinction in snow.
Gauthier Verin, Florent Dominé, Marcel Babin, Ghislain Picard, and Laurent Arnaud
The Cryosphere Discuss., https://doi.org/10.5194/tc-2019-113, https://doi.org/10.5194/tc-2019-113, 2019
Publication in TC not foreseen
Short summary
Short summary
The results of two sampling campaigns conducted on landfast sea ice in Baffin Bay show that the melt season can be divided into four main phases during which surface albedo and snow properties show distinct signatures. A radiative transfer model was used to successfully reconstruct the albedo from snow properties. This modeling work highlights that only little changes on the very surface of the snowpack are able to dramatically change the albedo, a key element for the energy budget of sea ice.
Ghislain Picard, Laurent Arnaud, Romain Caneill, Eric Lefebvre, and Maxim Lamare
The Cryosphere, 13, 1983–1999, https://doi.org/10.5194/tc-13-1983-2019, https://doi.org/10.5194/tc-13-1983-2019, 2019
Short summary
Short summary
To study how snow accumulates in Antarctica, we analyze daily surface elevation recorded by an automatic laser scanner. We show that new snow often accumulates in thick patches covering a small fraction of the surface. Most patches are removed by erosion within weeks, implying that only a few contribute to the snowpack. This explains the heterogeneity on the surface and in the snowpack. These findings are important for surface mass and energy balance, photochemistry, and ice core interpretation.
Nicolas Champollion, Ghislain Picard, Laurent Arnaud, Éric Lefebvre, Giovanni Macelloni, Frédérique Rémy, and Michel Fily
The Cryosphere, 13, 1215–1232, https://doi.org/10.5194/tc-13-1215-2019, https://doi.org/10.5194/tc-13-1215-2019, 2019
Short summary
Short summary
The snow density close to the surface has been retrieved from satellite observations at Dome C on the Antarctic Ice Sheet. It shows a marked decrease between 2002 and 2011 of about 10 kg m-3 yr-1. This trend has been confirmed by in situ measurements and other satellite observations though no long-term meteorological evolution has been found. These results have implications for surface mass balance and energy budget.
Tommaso Galeazzo, Slimane Bekki, Erwan Martin, Joël Savarino, and Stephen R. Arnold
Atmos. Chem. Phys., 18, 17909–17931, https://doi.org/10.5194/acp-18-17909-2018, https://doi.org/10.5194/acp-18-17909-2018, 2018
Short summary
Short summary
Volcanic sulfur can have climatic impacts for the planet via sulfate aerosol formation, leading also to pollution events. We provide model constraints on tropospheric volcanic sulfate formation, with implications for its lifetime and impacts on regional air quality. Oxygen isotope investigations from our model suggest that in the poor tropospheric plumes of halogens, the O2/TMI sulfur oxidation pathway might significantly control sulfate production. The produced sulfate has no isotopic anomaly.
Shaojie Song, Hélène Angot, Noelle E. Selin, Hubert Gallée, Francesca Sprovieri, Nicola Pirrone, Detlev Helmig, Joël Savarino, Olivier Magand, and Aurélien Dommergue
Atmos. Chem. Phys., 18, 15825–15840, https://doi.org/10.5194/acp-18-15825-2018, https://doi.org/10.5194/acp-18-15825-2018, 2018
Short summary
Short summary
Mercury is a trace metal with adverse health effects on human and wildlife. Its unique property makes it undergo long-range transport, and even remote Antarctica receives significant inputs. This paper presents the first model that aims to understand mercury behavior over the Antarctic Plateau. We find that mercury is quickly cycled between snow and air in the sunlit period, likely driven by bromine chemistry, and that several uncertain processes contribute to its behavior in the dark period.
Alexander Kokhanovsky, Maxim Lamare, Biagio Di Mauro, Ghislain Picard, Laurent Arnaud, Marie Dumont, François Tuzet, Carsten Brockmann, and Jason E. Box
The Cryosphere, 12, 2371–2382, https://doi.org/10.5194/tc-12-2371-2018, https://doi.org/10.5194/tc-12-2371-2018, 2018
Short summary
Short summary
This work presents a new technique with which to derive the snow microphysical and optical properties from snow spectral reflectance measurements. The technique is robust and easy to use, and it does not require the extraction of snow samples from a given snowpack. It can be used in processing satellite imagery over extended fresh dry, wet and polluted snowfields.
Ghislain Picard, Melody Sandells, and Henning Löwe
Geosci. Model Dev., 11, 2763–2788, https://doi.org/10.5194/gmd-11-2763-2018, https://doi.org/10.5194/gmd-11-2763-2018, 2018
Short summary
Short summary
The Snow Microwave Radiative Transfer (SMRT) is a novel model developed to calculate how microwaves are scattered and emitted by snow. The model is built from separate, interconnecting modules to make it easy to compare different aspects of the theory. SMRT is the first model to allow a choice of how to represent the microstructure of the snow, which is extremely important, and has been used to unite multiple previous studies. This model will ultimately be used to observe snow from space.
Alexandra Touzeau, Amaëlle Landais, Samuel Morin, Laurent Arnaud, and Ghislain Picard
Geosci. Model Dev., 11, 2393–2418, https://doi.org/10.5194/gmd-11-2393-2018, https://doi.org/10.5194/gmd-11-2393-2018, 2018
Short summary
Short summary
We introduced a new module of water vapor diffusion into the snowpack model Crocus. Vapor transport locally modifies the density of snow layers, possibly influencing compaction. It also affects the original isotopic signature of snow layers. We also introduced water isotopes (𝛿18O) in the model. Over 10 years, the modeled attenuation of isotopic variations due to vapor diffusion is 7–18 % lower than the observations. Thus, other processes are required to explain the total attenuation.
Fifi Ibrahime Adodo, Frédérique Remy, and Ghislain Picard
The Cryosphere, 12, 1767–1778, https://doi.org/10.5194/tc-12-1767-2018, https://doi.org/10.5194/tc-12-1767-2018, 2018
Short summary
Short summary
In Antarctica, the seasonal cycle of the backscatter behaves differently at high and low frequencies, peaking in winter and in summer, respectively. At the intermediate frequency, some areas behave analogously to low frequency in terms of the seasonal cycle, but other areas behave analogously to high frequency. This calls into question the empirical relationships often used to correct elevation changes from radar penetration into the snowpack using backscatter.
Mathieu Casado, Amaelle Landais, Ghislain Picard, Thomas Münch, Thomas Laepple, Barbara Stenni, Giuliano Dreossi, Alexey Ekaykin, Laurent Arnaud, Christophe Genthon, Alexandra Touzeau, Valerie Masson-Delmotte, and Jean Jouzel
The Cryosphere, 12, 1745–1766, https://doi.org/10.5194/tc-12-1745-2018, https://doi.org/10.5194/tc-12-1745-2018, 2018
Short summary
Short summary
Ice core isotopic records rely on the knowledge of the processes involved in the archival processes of the snow. In the East Antarctic Plateau, post-deposition processes strongly affect the signal found in the surface and buried snow compared to the initial climatic signal. We evaluate the different contributions to the surface snow isotopic composition between the precipitation and the exchanges with the atmosphere and the variability of the isotopic signal found in profiles from snow pits.
Francois Tuzet, Marie Dumont, Matthieu Lafaysse, Ghislain Picard, Laurent Arnaud, Didier Voisin, Yves Lejeune, Luc Charrois, Pierre Nabat, and Samuel Morin
The Cryosphere, 11, 2633–2653, https://doi.org/10.5194/tc-11-2633-2017, https://doi.org/10.5194/tc-11-2633-2017, 2017
Short summary
Short summary
Light-absorbing impurities deposited on snow, such as soot or dust, strongly modify its evolution. We implemented impurity deposition and evolution in a detailed snowpack model, thereby expanding the reach of such models into addressing the subtle interplays between snow physics and impurities' optical properties. Model results were evaluated based on innovative field observations at an Alpine site. This allows future investigations in the fields of climate, hydrology and avalanche prediction.
Marie Dumont, Laurent Arnaud, Ghislain Picard, Quentin Libois, Yves Lejeune, Pierre Nabat, Didier Voisin, and Samuel Morin
The Cryosphere, 11, 1091–1110, https://doi.org/10.5194/tc-11-1091-2017, https://doi.org/10.5194/tc-11-1091-2017, 2017
Short summary
Short summary
Snow spectral albedo in the visible/near-infrared range has been continuously measured during a winter season at Col de Porte alpine site (French Alps; 45.30° N, 5.77°E; 1325 m a.s.l.). This study highlights that the variations of spectral albedo can be successfully explained by variations of the following snow surface variables: snow-specific surface area, effective light-absorbing impurities content, presence of liquid water and slope.
Sakiko Ishino, Shohei Hattori, Joel Savarino, Bruno Jourdain, Susanne Preunkert, Michel Legrand, Nicolas Caillon, Albane Barbero, Kota Kuribayashi, and Naohiro Yoshida
Atmos. Chem. Phys., 17, 3713–3727, https://doi.org/10.5194/acp-17-3713-2017, https://doi.org/10.5194/acp-17-3713-2017, 2017
Short summary
Short summary
We show the first simultaneous observations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica. The contrasting seasonal trends between oxygen isotopes of ozone and those of sulfate and nitrate indicate that these signatures in sulfate and nitrate are mainly controlled by changes in oxidation chemistry. We also discuss the specific oxidation chemistry induced by the unique phenomena at the site.
Mathieu Casado, Amaelle Landais, Ghislain Picard, Thomas Münch, Thomas Laepple, Barbara Stenni, Giuliano Dreossi, Alexey Ekaykin, Laurent Arnaud, Christophe Genthon, Alexandra Touzeau, Valérie Masson-Delmotte, and Jean Jouzel
The Cryosphere Discuss., https://doi.org/10.5194/tc-2016-263, https://doi.org/10.5194/tc-2016-263, 2016
Revised manuscript not accepted
Short summary
Short summary
Ice core isotopic records rely on the knowledge of the processes involved in the archival of the snow. In the East Antarctic Plateau, post-deposition processes strongly affect the signal found in the surface and buried snow compared to the initial climatic signal. We evaluate the different contributions to the surface snow isotopic composition between the precipitation and the exchanges with the atmosphere and the variability of the isotopic signal found in profiles from snow pits.
Ghislain Picard, Quentin Libois, and Laurent Arnaud
The Cryosphere, 10, 2655–2672, https://doi.org/10.5194/tc-10-2655-2016, https://doi.org/10.5194/tc-10-2655-2016, 2016
Short summary
Short summary
The absorption of visible light in ice is very weak but its precise value is unknown. By measuring the profile of light intensity in snow, Warren and Brand (2006) deduced that light is attenuated by a factor 2 per kilometer in pure ice at a wavelength of 400 nm. We replicated their experiment on a large number of samples and found that ice absorption is at least 10 times stronger. The paper explores various potential physical and statistical biases that could impact the experiment.
Ghislain Picard, Laurent Arnaud, Jean-Michel Panel, and Samuel Morin
The Cryosphere, 10, 1495–1511, https://doi.org/10.5194/tc-10-1495-2016, https://doi.org/10.5194/tc-10-1495-2016, 2016
Short summary
Short summary
A cost-effective automatic laser scan has been built to measure snow depth spatio-temporal variations. Deployed in the Alps and in Dome C (Antarctica), two devices acquired daily scans covering a surface area of 100–150 m2. The precision and long-term stability of the measurements are about 1 cm and the accuracy is better than 5 cm. These high performances are particularly suited at Dome C, where it was possible to reveal that most of the accumulation in the year 2015 stems from a single event.
Mathieu Casado, Amaelle Landais, Valérie Masson-Delmotte, Christophe Genthon, Erik Kerstel, Samir Kassi, Laurent Arnaud, Ghislain Picard, Frederic Prie, Olivier Cattani, Hans-Christian Steen-Larsen, Etienne Vignon, and Peter Cermak
Atmos. Chem. Phys., 16, 8521–8538, https://doi.org/10.5194/acp-16-8521-2016, https://doi.org/10.5194/acp-16-8521-2016, 2016
Short summary
Short summary
Climatic conditions in Concordia are very cold (−55 °C in average) and very dry, imposing difficult conditions to measure the water vapour isotopic composition. New developments in infrared spectroscopy enable now the measurement of isotopic composition in water vapour traces (down to 20 ppmv). Here we present the results results of a first campaign of measurement of isotopic composition of water vapour in Concordia, the site where the 800 000 years long ice core was drilled.
Michel Legrand, Susanne Preunkert, Joël Savarino, Markus M. Frey, Alexandre Kukui, Detlev Helmig, Bruno Jourdain, Anna E. Jones, Rolf Weller, Neil Brough, and Hubert Gallée
Atmos. Chem. Phys., 16, 8053–8069, https://doi.org/10.5194/acp-16-8053-2016, https://doi.org/10.5194/acp-16-8053-2016, 2016
Short summary
Short summary
Surface ozone, the most abundant atmospheric oxidant, has been measured since 2004 at the coastal East Antarctic site of Dumont d’Urville, and since 2007 at the Concordia station located on the high East Antarctic plateau. Long-term changes, seasonal and diurnal cycles, as well as inter-annual summer variability observed at these two East Antarctic sites are discussed. Influences like sea ice extent and outflow from inland Antarctica are discussed.
Ghislain Picard, Quentin Libois, Laurent Arnaud, Gauthier Verin, and Marie Dumont
The Cryosphere, 10, 1297–1316, https://doi.org/10.5194/tc-10-1297-2016, https://doi.org/10.5194/tc-10-1297-2016, 2016
Short summary
Short summary
Albedo of snow surfaces depends on snow grain size. By measuring albedo during 3 years at Dome C in Antarctica with an automatic spectroradiometer, we were able to monitor the snow specific surface area and show an overall growth of the grains in spring and summer followed by an accumulation of small-grained snow from mid-summer. This study focuses on the uncertainties due to the spectroradiometer and concludes that the observed variations are significant with respect to the precision.
Luc Charrois, Emmanuel Cosme, Marie Dumont, Matthieu Lafaysse, Samuel Morin, Quentin Libois, and Ghislain Picard
The Cryosphere, 10, 1021–1038, https://doi.org/10.5194/tc-10-1021-2016, https://doi.org/10.5194/tc-10-1021-2016, 2016
Short summary
Short summary
This study investigates the assimilation of optical reflectances, snowdepth data and both combined into a multilayer snowpack model. Data assimilation is performed with an ensemble-based method, the Sequential Importance Resampling Particle filter. Experiments assimilating only synthetic data are conducted at one point in the French Alps, the Col du Lautaret, over five hydrological years. Results of the assimilation experiments show improvements of the snowpack bulk variables estimates.
Alexandra Touzeau, Amaëlle Landais, Barbara Stenni, Ryu Uemura, Kotaro Fukui, Shuji Fujita, Sarah Guilbaud, Alexey Ekaykin, Mathieu Casado, Eugeni Barkan, Boaz Luz, Olivier Magand, Grégory Teste, Emmanuel Le Meur, Mélanie Baroni, Joël Savarino, Ilann Bourgeois, and Camille Risi
The Cryosphere, 10, 837–852, https://doi.org/10.5194/tc-10-837-2016, https://doi.org/10.5194/tc-10-837-2016, 2016
Short summary
Short summary
The relationship between water isotope ratios and temperature is investigated in precipitation snow at Vostok and Dome C, as well as in surface snow along traverses. The temporal slope of the linear regression for the precipitation is smaller than the geographical slope. Thus, using the latter could lead to an underestimation of past temperature changes. The processes active at remote sites (best glacial analogs) are explored through a combination of water isotopes in short snow pits.
Lucie Bazin, Amaelle Landais, Emilie Capron, Valérie Masson-Delmotte, Catherine Ritz, Ghislain Picard, Jean Jouzel, Marie Dumont, Markus Leuenberger, and Frédéric Prié
Clim. Past, 12, 729–748, https://doi.org/10.5194/cp-12-729-2016, https://doi.org/10.5194/cp-12-729-2016, 2016
Short summary
Short summary
We present new measurements of δO2⁄N2 and δ18Oatm performed on well-conserved ice from EDC covering MIS5 and between 380 and 800 ka. The combination of the observation of a 100 ka periodicity in the new δO2⁄N2 record with a MIS5 multi-site multi-proxy study has revealed a potential influence of local climatic parameters on δO2⁄N2. Moreover, we propose that the varying delay between d18Oatm and precession for the last 800 ka is affected by the occurrence of ice sheet discharge events.
Alexandre Roy, Alain Royer, Olivier St-Jean-Rondeau, Benoit Montpetit, Ghislain Picard, Alex Mavrovic, Nicolas Marchand, and Alexandre Langlois
The Cryosphere, 10, 623–638, https://doi.org/10.5194/tc-10-623-2016, https://doi.org/10.5194/tc-10-623-2016, 2016
Joël Savarino, William C. Vicars, Michel Legrand, Suzanne Preunkert, Bruno Jourdain, Markus M. Frey, Alexandre Kukui, Nicolas Caillon, and Jaime Gil Roca
Atmos. Chem. Phys., 16, 2659–2673, https://doi.org/10.5194/acp-16-2659-2016, https://doi.org/10.5194/acp-16-2659-2016, 2016
Short summary
Short summary
Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable isotopes and concentrations of nitrate are measured. Using a box model, we show that there is s systematic discrepancy between observations and model results. We suggest that this discrepancy probably results from unknown NOx chemistry above the Antarctic ice sheet. However, possible misconception in the stable isotope mass balance is not completely excluded.
E. Gautier, J. Savarino, J. Erbland, A. Lanciki, and P. Possenti
Clim. Past, 12, 103–113, https://doi.org/10.5194/cp-12-103-2016, https://doi.org/10.5194/cp-12-103-2016, 2016
Short summary
Short summary
We evaluate the local-scale variability of a sulfate profile at a low-accumulation site (Dome C, Antarctica) to assess the representativeness of one ice core for volcanic reconstructions. Peak statistical occurrence, depth and flux variability are evaluated from five cores. Due to local-scale variability, 64 volcanic peaks can be identified by a five-cores analysis, while only half of them can be assessed from two cores. Using five cores, the uncertainty of the mean flux is reduced to 29 %.
Q. Libois, G. Picard, L. Arnaud, M. Dumont, M. Lafaysse, S. Morin, and E. Lefebvre
The Cryosphere, 9, 2383–2398, https://doi.org/10.5194/tc-9-2383-2015, https://doi.org/10.5194/tc-9-2383-2015, 2015
Short summary
Short summary
The albedo and surface energy budget of the Antarctic Plateau are largely determined by snow specific surface area. The latter experiences substantial daily-to-seasonal variations in response to meteorological conditions. In particular, it decreases by a factor three in summer, causing a drop in albedo. These variations are monitored from in situ and remote sensing observations at Dome C. For the first time, they are also simulated with a snowpack evolution model adapted to Antarctic conditions.
H. Löwe and G. Picard
The Cryosphere, 9, 2101–2117, https://doi.org/10.5194/tc-9-2101-2015, https://doi.org/10.5194/tc-9-2101-2015, 2015
Short summary
Short summary
The paper establishes a theoretical link between two widely used microwave models for snow. The scattering formulations from both models are unified by reformulating their microstructure models in a common framework. The results show that the scattering formulations can be considered equivalent, if exactly the same microstructure model is used. The paper also provides a method to measure a hitherto unknown input parameter for the microwave models from tomography images of snow.
J. Erbland, J. Savarino, S. Morin, J. L. France, M. M. Frey, and M. D. King
Atmos. Chem. Phys., 15, 12079–12113, https://doi.org/10.5194/acp-15-12079-2015, https://doi.org/10.5194/acp-15-12079-2015, 2015
Short summary
Short summary
In this paper, we describe the development of a numerical model which aims at representing nitrate recycling at the air-snow interface on the East Antarctic Plateau. Stable isotopes are used as diagnostic and evaluation tools by comparing the model's results to recent field measurements of nitrate and key atmospheric species at Dome C, Antarctica. From sensitivity tests conducted with the model, we propose a framework for the interpretation of the nitrate isotope record in deep ice cores.
T. A. Berhanu, J. Savarino, J. Erbland, W. C. Vicars, S. Preunkert, J. F. Martins, and M. S. Johnson
Atmos. Chem. Phys., 15, 11243–11256, https://doi.org/10.5194/acp-15-11243-2015, https://doi.org/10.5194/acp-15-11243-2015, 2015
Short summary
Short summary
In this field study at Dome C, Antarctica, we investigated the effect of solar UV photolysis on the stable isotopes of nitrate in snow via comparison of two identical snow pits while exposing only one to solar UV. From the difference between the average isotopic fractionations calculated for each pit, we determined a purely photolytic nitrogen isotopic fractionation of -55.8‰, in good agreement with what has been recently determined in a laboratory study.
S. Preunkert, M. Legrand, M. M. Frey, A. Kukui, J. Savarino, H. Gallée, M. King, B. Jourdain, W. Vicars, and D. Helmig
Atmos. Chem. Phys., 15, 6689–6705, https://doi.org/10.5194/acp-15-6689-2015, https://doi.org/10.5194/acp-15-6689-2015, 2015
Short summary
Short summary
During two austral summers HCHO was investigated in air, snow, and interstitial air at the Concordia site located on the East Antarctic Plateau. Snow emission fluxes were estimated to be around 1 to 2 and 3 to 5 x 10^12 molecules m-2 s-1 at night and at noon, respectively. Shading experiments suggest that the photochemical HCHO production in the snowpack at Concordia remains negligible. The mean HCHO level of 130pptv observed at 1m above the surface is quite well reproduced by 1-D simulations.
L. Geng, J. Cole-Dai, B. Alexander, J. Erbland, J. Savarino, A. J. Schauer, E. J. Steig, P. Lin, Q. Fu, and M. C. Zatko
Atmos. Chem. Phys., 14, 13361–13376, https://doi.org/10.5194/acp-14-13361-2014, https://doi.org/10.5194/acp-14-13361-2014, 2014
Short summary
Short summary
Examinations on snowpit and firn core results from Summit, Greenland suggest that there are two mechanisms leading to the observed double nitrate peaks in some years in the industrial era: 1) long-rang transport of nitrate and 2) enhanced local photochemical production of nitrate. Both of these mechanisms are related to pollution transport, as the additional nitrate from either direct transport or enhanced local photochemistry requires enhanced nitrogen sources from anthropogenic emissions.
J.-C. Gallet, F. Domine, J. Savarino, M. Dumont, and E. Brun
The Cryosphere, 8, 1205–1215, https://doi.org/10.5194/tc-8-1205-2014, https://doi.org/10.5194/tc-8-1205-2014, 2014
G. Picard, A. Royer, L. Arnaud, and M. Fily
The Cryosphere, 8, 1105–1119, https://doi.org/10.5194/tc-8-1105-2014, https://doi.org/10.5194/tc-8-1105-2014, 2014
Q. Libois, G. Picard, J. L. France, L. Arnaud, M. Dumont, C. M. Carmagnola, and M. D. King
The Cryosphere, 7, 1803–1818, https://doi.org/10.5194/tc-7-1803-2013, https://doi.org/10.5194/tc-7-1803-2013, 2013
Related subject area
Subject: Gases | Research Activity: Atmospheric Modelling and Data Analysis | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
CO anthropogenic emissions in Europe from 2011 to 2021: insights from Measurement of Pollution in the Troposphere (MOPITT) satellite data
Constraining long-term NOx emissions over the United States and Europe using nitrate wet deposition monitoring networks
Analysis of an intense O3 pollution episode on the Atlantic coast of the Iberian Peninsula using photochemical modeling: characterization of transport pathways and accumulation processes
Atmospheric oxygen as a tracer for fossil fuel carbon dioxide: a sensitivity study in the UK
MIXv2: a long-term mosaic emission inventory for Asia (2010–2017)
Organosulfate produced from consumption of SO3 speeds up sulfuric acid–dimethylamine atmospheric nucleation
Contribution of expanded marine sulfur chemistry to the seasonal variability of dimethyl sulfide oxidation products and size-resolved sulfate aerosol
Spatial disparities of ozone pollution in the Sichuan Basin spurred by extreme, hot weather
Global impacts of aviation on air quality evaluated at high resolution
Bias correction of OMI HCHO columns based on FTIR and aircraft measurements and impact on top-down emission estimates
Investigation of the renewed methane growth post-2007 with high-resolution 3-D variational inverse modeling and isotopic constraints
Revisiting day-of-week ozone patterns in an era of evolving US air quality
Air quality and radiative impacts of downward-propagating sudden stratospheric warmings (SSWs)
Estimation of the atmospheric hydroxyl radical oxidative capacity using multiple hydrofluorocarbons (HFCs)
Investigating the differences in calculating global mean surface CO2 abundance: the impact of analysis methodologies and site selection
Meteorological characteristics of extreme ozone pollution events in China and their future predictions
Evaluating modelled tropospheric columns of CH4, CO, and O3 in the Arctic using ground-based Fourier transform infrared (FTIR) measurements
The high-resolution Global Aviation emissions Inventory based on ADS-B (GAIA) for 2019–2021
Zonal variability of methane trends derived from satellite data
Weekly derived top-down volatile-organic-compound fluxes over Europe from TROPOMI HCHO data from 2018 to 2021
Technical note: Challenges of detecting free tropospheric ozone trends in a sparsely sampled environment
Current status of model predictions of volatile organic compounds and impacts on surface ozone predictions during summer in China
Utility of Geostationary Lightning Mapper-derived lightning NO emission estimates in air quality modeling studies
The suitability of atmospheric oxygen measurements to constrain western European fossil-fuel CO2 emissions and their trends
Future tropospheric ozone budget and distribution over east Asia under a net-zero scenario
Comprehensive multiphase chlorine chemistry in the box model CAABA/MECCA: implications for atmospheric oxidative capacity
Insights into soil NO emissions and the contribution to surface ozone formation in China
The impact of gaseous degradation on the equilibrium state of gas/particle partitioning of semi-volatile organic compounds
An intercomparison of satellite, airborne, and ground-level observations with WRF-CAMx simulations of NO2 columns over Houston, TX during the September 2021 TRACER-AQ campaign
Development, intercomparison, and evaluation of an improved mechanism for the oxidation of dimethyl sulfide in the UKCA model
A better representation of VOC chemistry in WRF-Chem and its impact on ozone over Los Angeles
Technical note: An assessment of the performance of statistical bias correction techniques for global chemistry-climate model surface ozone fields
The atmospheric oxidizing capacity in China – Part 1: Roles of different photochemical processes
Benefits of net-zero policies for future ozone pollution in China
Simulating impacts on UK air quality from net-zero forest planting scenarios
Understanding offshore high-ozone events during TRACER-AQ 2021 in Houston: insights from WRF–CAMx photochemical modeling
Opinion: Establishing a science-into-policy process for tropospheric ozone assessment
Atmospheric composition and climate impacts of a future hydrogen economy
Assessment of isoprene and near-surface ozone sensitivities to water stress over the Euro-Mediterranean region
The impact multi-decadal of changes in VOCs speciation on urban ozone chemistry: A case study in Birmingham, United Kingdom
Nighttime ozone in the lower boundary layer: insights from 3-year tower-based measurements in South China and regional air quality modeling
What controls ozone sensitivity in the upper tropical troposphere?
Summertime tropospheric ozone source apportionment study in Madrid (Spain)
Modelling the impacts of emission changes on O3 sensitivity, atmospheric oxidation capacity, and pollution transport over the Catalonia region
A regional modelling study of halogen chemistry within a volcanic plume of Mt Etna's Christmas 2018 eruption
Constraining the budget of atmospheric carbonyl sulfide using a 3-D chemical transport model
Atmospheric CO2 inversion reveals the Amazon as a minor carbon source caused by fire emissions, with forest uptake offsetting about half of these emissions
Rapid O3 assimilations – Part 2: Tropospheric O3 changes accompanied by declining NOx emissions in the USA and Europe in 2005–2020
High-resolution air quality simulations of ozone exceedance events during the Lake Michigan Ozone Study
Simulations of winter ozone in the Upper Green River basin, Wyoming, using WRF-Chem
Audrey Fortems-Cheiney, Gregoire Broquet, Elise Potier, Robin Plauchu, Antoine Berchet, Isabelle Pison, Hugo Denier van der Gon, and Stijn Dellaert
Atmos. Chem. Phys., 24, 4635–4649, https://doi.org/10.5194/acp-24-4635-2024, https://doi.org/10.5194/acp-24-4635-2024, 2024
Short summary
Short summary
We have estimated the carbon monixide (CO) European emissions from satellite observations of the MOPITT instrument at the relatively high resolution of 0.5° for a period of over 10 years from 2011 to 2021. The analysis of the inversion results reveals the challenges associated with the inversion of CO emissions at the regional scale over Europe.
Amy Christiansen, Loretta J. Mickley, and Lu Hu
Atmos. Chem. Phys., 24, 4569–4589, https://doi.org/10.5194/acp-24-4569-2024, https://doi.org/10.5194/acp-24-4569-2024, 2024
Short summary
Short summary
In this work, we provide an additional constraint on emissions and trends of nitrogen oxides using nitrate wet deposition (NWD) fluxes over the United States and Europe from 1980–2020. We find that NWD measurements constrain total NOx emissions well. We also find evidence of NOx emission overestimates in both domains, but especially over Europe, where NOx emissions are overestimated by a factor of 2. Reducing NOx emissions over Europe improves model representation of ozone at the surface.
Eduardo Torre-Pascual, Gotzon Gangoiti, Ana Rodríguez-García, Estibaliz Sáez de Cámara, Joana Ferreira, Carla Gama, María Carmen Gómez, Iñaki Zuazo, Jose Antonio García, and Maite de Blas
Atmos. Chem. Phys., 24, 4305–4329, https://doi.org/10.5194/acp-24-4305-2024, https://doi.org/10.5194/acp-24-4305-2024, 2024
Short summary
Short summary
We present an analysis of an intense air pollution episode of tropospheric ozone (O3) along the Atlantic coast of the Iberian Peninsula, incorporating both measured and simulated parameters. Our study extends beyond surface-level factors to include altitude-related parameters. These episodes stem from upper-atmosphere O3 accumulation in preceding days, transported to surface layers, causing rapid O3 concentration increase.
Hannah Chawner, Eric Saboya, Karina E. Adcock, Tim Arnold, Yuri Artioli, Caroline Dylag, Grant L. Forster, Anita Ganesan, Heather Graven, Gennadi Lessin, Peter Levy, Ingrid T. Luijkx, Alistair Manning, Penelope A. Pickers, Chris Rennick, Christian Rödenbeck, and Matthew Rigby
Atmos. Chem. Phys., 24, 4231–4252, https://doi.org/10.5194/acp-24-4231-2024, https://doi.org/10.5194/acp-24-4231-2024, 2024
Short summary
Short summary
The quantity of atmospheric potential oxygen (APO), derived from coincident measurements of carbon dioxide (CO2) and oxygen (O2), has been proposed as a tracer for fossil fuel CO2 emissions. In this model sensitivity study, we examine the use of APO for this purpose in the UK and compare our model to observations. We find that our model simulations are most sensitive to uncertainties relating to ocean fluxes and boundary conditions.
Meng Li, Junichi Kurokawa, Qiang Zhang, Jung-Hun Woo, Tazuko Morikawa, Satoru Chatani, Zifeng Lu, Yu Song, Guannan Geng, Hanwen Hu, Jinseok Kim, Owen R. Cooper, and Brian C. McDonald
Atmos. Chem. Phys., 24, 3925–3952, https://doi.org/10.5194/acp-24-3925-2024, https://doi.org/10.5194/acp-24-3925-2024, 2024
Short summary
Short summary
In this work, we developed MIXv2, a mosaic Asian emission inventory for 2010–2017. With high spatial (0.1°) and monthly temporal resolution, MIXv2 integrates anthropogenic and open biomass burning emissions across seven sectors following a mosaic methodology. It provides CO2 emissions data alongside nine key pollutants and three chemical mechanisms. Our publicly accessible gridded monthly emissions data can facilitate long-term atmospheric and climate model analyses.
Xiaomeng Zhang, Yongjian Lian, Shendong Tan, and Shi Yin
Atmos. Chem. Phys., 24, 3593–3612, https://doi.org/10.5194/acp-24-3593-2024, https://doi.org/10.5194/acp-24-3593-2024, 2024
Short summary
Short summary
Atmospheric new particle formation (NPF) has a significant influence on the global climate, local air quality and human health. Using a combination of quantum chemical calculations and kinetics modeling, we find that thhe gas-phase organosulfate produced from consumption of SO3 can significantly enhance SA–DMA nucleation in the polluted boundary layer, resulting in non-negligible contributions to NPF. Our findings provide important insights into organic sulfur in atmospheric aerosol formation.
Linia Tashmim, William C. Porter, Qianjie Chen, Becky Alexander, Charles H. Fite, Christopher D. Holmes, Jeffrey R. Pierce, Betty Croft, and Sakiko Ishino
Atmos. Chem. Phys., 24, 3379–3403, https://doi.org/10.5194/acp-24-3379-2024, https://doi.org/10.5194/acp-24-3379-2024, 2024
Short summary
Short summary
Dimethyl sulfide (DMS) is mostly emitted from ocean surfaces and represents the largest natural source of sulfur for the atmosphere. Once in the atmosphere, DMS forms stable oxidation products such as SO2 and H2SO4, which can subsequently contribute to airborne particle formation and growth. In this study, we update the DMS oxidation mechanism in the chemical transport model GEOS-Chem and describe resulting changes in particle growth as well as the overall global sulfur budget.
Nan Wang, Yunsong Du, Dongyang Chen, Haiyan Meng, Xi Chen, Li Zhou, Guangming Shi, Yu Zhan, Miao Feng, Wei Li, Mulan Chen, Zhenliang Li, and Fumo Yang
Atmos. Chem. Phys., 24, 3029–3042, https://doi.org/10.5194/acp-24-3029-2024, https://doi.org/10.5194/acp-24-3029-2024, 2024
Short summary
Short summary
In the scorching August 2022 heatwave, China's Sichuan Basin saw a stark contrast in ozone (O3) levels between Chengdu and Chongqing. The regional disparities were studied considering meteorology, precursors, photochemistry, and transportation. The study highlighted the importance of tailored pollution control measures and underlined the necessity for region-specific strategies to combat O3 pollution on a regional scale.
Sebastian D. Eastham, Guillaume P. Chossière, Raymond L. Speth, Daniel J. Jacob, and Steven R. H. Barrett
Atmos. Chem. Phys., 24, 2687–2703, https://doi.org/10.5194/acp-24-2687-2024, https://doi.org/10.5194/acp-24-2687-2024, 2024
Short summary
Short summary
Emissions from aircraft are known to cause air quality impacts worldwide, but the scale and mechanisms of this impact are not well understood. This work uses high-resolution computational modeling of the atmosphere to show that air pollution changes from aviation are mostly the result of emissions during cruise (high-altitude) operations, that these impacts are related to how much non-aviation pollution is present, and that prior regional assessments have underestimated these impacts.
Jean-François Müller, Trissevgeni Stavrakou, Glenn-Michael Oomen, Beata Opacka, Isabelle De Smedt, Alex Guenther, Corinne Vigouroux, Bavo Langerock, Carlos Augusto Bauer Aquino, Michel Grutter, James Hannigan, Frank Hase, Rigel Kivi, Erik Lutsch, Emmanuel Mahieu, Maria Makarova, Jean-Marc Metzger, Isamu Morino, Isao Murata, Tomoo Nagahama, Justus Notholt, Ivan Ortega, Mathias Palm, Amelie Röhling, Wolfgang Stremme, Kimberly Strong, Ralf Sussmann, Yao Té, and Alan Fried
Atmos. Chem. Phys., 24, 2207–2237, https://doi.org/10.5194/acp-24-2207-2024, https://doi.org/10.5194/acp-24-2207-2024, 2024
Short summary
Short summary
Formaldehyde observations from satellites can be used to constrain the emissions of volatile organic compounds, but those observations have biases. Using an atmospheric model, aircraft and ground-based remote sensing data, we quantify these biases, propose a correction to the data, and assess the consequence of this correction for the evaluation of emissions.
Joël Thanwerdas, Marielle Saunois, Antoine Berchet, Isabelle Pison, and Philippe Bousquet
Atmos. Chem. Phys., 24, 2129–2167, https://doi.org/10.5194/acp-24-2129-2024, https://doi.org/10.5194/acp-24-2129-2024, 2024
Short summary
Short summary
We investigate the causes of the renewed growth of atmospheric methane (CH4) after 2007 using inverse modeling. We use the additional information provided by observations of CH4 isotopic compositions to better differentiate between the emission categories. Accounting for the large uncertainties in source signatures, our results suggest that the post-2007 increase in atmospheric CH4 was caused by similar increases in emissions from (1) fossil fuels and (2) agriculture and waste.
Heather Simon, Christian Hogrefe, Andrew Whitehill, Kristen M. Foley, Jennifer Liljegren, Norm Possiel, Benjamin Wells, Barron H. Henderson, Lukas C. Valin, Gail Tonnesen, K. Wyat Appel, and Shannon Koplitz
Atmos. Chem. Phys., 24, 1855–1871, https://doi.org/10.5194/acp-24-1855-2024, https://doi.org/10.5194/acp-24-1855-2024, 2024
Short summary
Short summary
We assess observed and modeled ozone weekend–weekday differences in the USA from 2002–2019. A subset of urban areas that were NOx-saturated at the beginning of the period transitioned to NOx-limited conditions. Multiple rural areas of California were NOx-limited for the entire period but become less influenced by local day-of-week emission patterns in more recent years. The model produces more NOx-saturated conditions than the observations but captures trends in weekend–weekday ozone patterns.
Ryan S. Williams, Michaela I. Hegglin, Patrick Jöckel, Hella Garny, and Keith P. Shine
Atmos. Chem. Phys., 24, 1389–1413, https://doi.org/10.5194/acp-24-1389-2024, https://doi.org/10.5194/acp-24-1389-2024, 2024
Short summary
Short summary
During winter, a brief but abrupt reversal of the mean stratospheric westerly flow (~30 km high) around the Arctic occurs ~6 times a decade. Using a chemistry–climate model, about half of these events are shown to induce large anomalies in Arctic ozone (>25 %) and water vapour (>±25 %) around ~8–12 km altitude for up to 2–3 months, important for weather forecasting. We also calculate a doubling to trebling of the risk in breaches of mid-latitude surface air quality (ozone) standards (~60 ppbv).
Rona L. Thompson, Stephen A. Montzka, Martin K. Vollmer, Jgor Arduini, Molly Crotwell, Paul B. Krummel, Chris Lunder, Jens Mühle, Simon O'Doherty, Ronald G. Prinn, Stefan Reimann, Isaac Vimont, Hsiang Wang, Ray F. Weiss, and Dickon Young
Atmos. Chem. Phys., 24, 1415–1427, https://doi.org/10.5194/acp-24-1415-2024, https://doi.org/10.5194/acp-24-1415-2024, 2024
Short summary
Short summary
The hydroxyl radical determines the atmospheric lifetimes of numerous species including methane. Since OH is very short-lived, it is not possible to directly measure its concentration on scales relevant for understanding its effect on other species. Here, OH is inferred by looking at changes in hydrofluorocarbons (HFCs). We find that OH levels have been fairly stable over our study period (2004 to 2021), suggesting that OH is not the main driver of the recent increase in atmospheric methane.
Zhendong Wu, Alex Vermeulen, Yousuke Sawa, Ute Karstens, Wouter Peters, Remco de Kok, Xin Lan, Yasuyuki Nagai, Akinori Ogi, and Oksana Tarasova
Atmos. Chem. Phys., 24, 1249–1264, https://doi.org/10.5194/acp-24-1249-2024, https://doi.org/10.5194/acp-24-1249-2024, 2024
Short summary
Short summary
This study focuses on exploring the differences in calculating global surface CO2 and its growth rate, considering the impact of analysis methodologies and site selection. Our study reveals that the current global CO2 network has a good capacity to represent global surface CO2 and its growth rate, as well as trends in atmospheric CO2 mass changes. However, small differences exist in different analyses due to the impact of methodology and site selection.
Yang Yang, Yang Zhou, Hailong Wang, Mengyun Li, Huimin Li, Pinya Wang, Xu Yue, Ke Li, Jia Zhu, and Hong Liao
Atmos. Chem. Phys., 24, 1177–1191, https://doi.org/10.5194/acp-24-1177-2024, https://doi.org/10.5194/acp-24-1177-2024, 2024
Short summary
Short summary
This study reveals that extreme ozone pollution over the North China Plain and Yangtze River Delta is due to the chemical production related to hot and dry conditions, and the regional transport explains the ozone pollution over the Sichuan Basin and Pearl River Delta. The frequency of meteorological conditions of the extreme ozone pollution increases from the past to the future. The sustainable scenario is the optimal path to retaining clean air in China in the future.
Victoria A. Flood, Kimberly Strong, Cynthia H. Whaley, Kaley A. Walker, Thomas Blumenstock, James W. Hannigan, Johan Mellqvist, Justus Notholt, Mathias Palm, Amelie N. Röhling, Stephen Arnold, Stephen Beagley, Rong-You Chien, Jesper Christensen, Makoto Deushi, Srdjan Dobricic, Xinyi Dong, Joshua S. Fu, Michael Gauss, Wanmin Gong, Joakim Langner, Kathy S. Law, Louis Marelle, Tatsuo Onishi, Naga Oshima, David A. Plummer, Luca Pozzoli, Jean-Christophe Raut, Manu A. Thomas, Svetlana Tsyro, and Steven Turnock
Atmos. Chem. Phys., 24, 1079–1118, https://doi.org/10.5194/acp-24-1079-2024, https://doi.org/10.5194/acp-24-1079-2024, 2024
Short summary
Short summary
It is important to understand the composition of the Arctic atmosphere and how it is changing. Atmospheric models provide simulations that can inform policy. This study examines simulations of CH4, CO, and O3 by 11 models. Model performance is assessed by comparing results matched in space and time to measurements from five high-latitude ground-based infrared spectrometers. This work finds that models generally underpredict the concentrations of these gases in the Arctic troposphere.
Roger Teoh, Zebediah Engberg, Marc Shapiro, Lynnette Dray, and Marc E. J. Stettler
Atmos. Chem. Phys., 24, 725–744, https://doi.org/10.5194/acp-24-725-2024, https://doi.org/10.5194/acp-24-725-2024, 2024
Short summary
Short summary
Emissions from aircraft contribute to climate change and degrade air quality. We describe an up-to-date 4D emissions inventory of global aviation from 2019 to 2021 based on actual flown trajectories. In 2019, 40.2 million flights collectively travelled 61 billion kilometres using 283 Tg of fuel. Long-haul flights were responsible for 43 % of CO2. The emissions inventory is made available for use in future studies to evaluate the negative externalities arising from global aviation.
Jonas Hachmeister, Oliver Schneising, Michael Buchwitz, John P. Burrows, Justus Notholt, and Matthias Buschmann
Atmos. Chem. Phys., 24, 577–595, https://doi.org/10.5194/acp-24-577-2024, https://doi.org/10.5194/acp-24-577-2024, 2024
Short summary
Short summary
We quantified changes in atmospheric methane concentrations using satellite data and a dynamic linear model approach. We calculated global annual methane increases for the years 2019–2022, which are in good agreement with other sources. For zonal methane growth rates, we identified strong inter-hemispheric differences in 2019 and 2022. For 2022, we could attribute decreases in the global growth rate to the Northern Hemisphere, possibly related to a reduction in anthropogenic emissions.
Glenn-Michael Oomen, Jean-François Müller, Trissevgeni Stavrakou, Isabelle De Smedt, Thomas Blumenstock, Rigel Kivi, Maria Makarova, Mathias Palm, Amelie Röhling, Yao Té, Corinne Vigouroux, Martina M. Friedrich, Udo Frieß, François Hendrick, Alexis Merlaud, Ankie Piters, Andreas Richter, Michel Van Roozendael, and Thomas Wagner
Atmos. Chem. Phys., 24, 449–474, https://doi.org/10.5194/acp-24-449-2024, https://doi.org/10.5194/acp-24-449-2024, 2024
Short summary
Short summary
Natural emissions from vegetation have a profound impact on air quality for their role in the formation of harmful tropospheric ozone and organic aerosols, yet these emissions are highly uncertain. In this study, we quantify emissions of organic gases over Europe using high-quality satellite measurements of formaldehyde. These satellite observations suggest that emissions from vegetation are much higher than predicted by models, especially in southern Europe.
Kai-Lan Chang, Owen R. Cooper, Audrey Gaudel, Irina Petropavlovskikh, Peter Effertz, Gary Morris, and Brian C. McDonald
EGUsphere, https://doi.org/10.5194/egusphere-2023-2739, https://doi.org/10.5194/egusphere-2023-2739, 2024
Short summary
Short summary
The great majority of observational trend studies of free tropospheric ozone use sparsely sampled ozonesonde and aircraft measurements as reference datasets. A ubiquitous assumption is that trends are accurate and reliable so long as long-term records are available. We show that sampling bias due to sparse samples can persistently reduce the trend accuracy, and highlight the importance of maintaining adequate frequency and continuity of observations.
Yongliang She, Jingyi Li, Xiaopu Lyu, Hai Guo, Momei Qin, Xiaodong Xie, Kangjia Gong, Fei Ye, Jianjiong Mao, Lin Huang, and Jianlin Hu
Atmos. Chem. Phys., 24, 219–233, https://doi.org/10.5194/acp-24-219-2024, https://doi.org/10.5194/acp-24-219-2024, 2024
Short summary
Short summary
In this study, we use multi-site volatile organic compound (VOC) measurements to evaluate the CMAQ-model-predicted VOCs and assess the impacts of VOC bias on O3 simulation. Our results demonstrate that current modeling setups and emission inventories are likely to underpredict VOC concentrations, and this underprediction of VOCs contributes to lower O3 predictions in China.
Peiyang Cheng, Arastoo Pour-Biazar, Yuling Wu, Shi Kuang, Richard T. McNider, and William J. Koshak
Atmos. Chem. Phys., 24, 41–63, https://doi.org/10.5194/acp-24-41-2024, https://doi.org/10.5194/acp-24-41-2024, 2024
Short summary
Short summary
Lightning-induced nitrogen monoxide (LNO) emission can be estimated from geostationary satellite observations. The present study uses the LNO emission estimates derived from geostationary satellite observations in an air quality modeling system to investigate the impact of LNO on air quality. Results indicate that significant ozone increase could be due to long-distance chemical transport, lightning activity in the upwind direction, and the mixing of high LNO (or ozone) plumes.
Christian Rödenbeck, Karina E. Adcock, Markus Eritt, Maksym Gachkivskyi, Christoph Gerbig, Samuel Hammer, Armin Jordan, Ralph F. Keeling, Ingeborg Levin, Fabian Maier, Andrew C. Manning, Heiko Moossen, Saqr Munassar, Penelope A. Pickers, Michael Rothe, Yasunori Tohjima, and Sönke Zaehle
Atmos. Chem. Phys., 23, 15767–15782, https://doi.org/10.5194/acp-23-15767-2023, https://doi.org/10.5194/acp-23-15767-2023, 2023
Short summary
Short summary
The carbon dioxide content of the Earth atmosphere is increasing due to human emissions from burning of fossil fuels, causing global climate change. The strength of the fossil-fuel emissions is estimated by inventories based on energy data, but independent validation of these inventories has been recommended by the Intergovernmental Panel on Climate Change. Here we investigate the potential to validate inventories based on measurements of small changes in the atmospheric oxygen content.
Xuewei Hou, Oliver Wild, Bin Zhu, and James Lee
Atmos. Chem. Phys., 23, 15395–15411, https://doi.org/10.5194/acp-23-15395-2023, https://doi.org/10.5194/acp-23-15395-2023, 2023
Short summary
Short summary
In response to the climate crisis, many countries have committed to net zero in a certain future year. The impacts of net-zero scenarios on tropospheric O3 are less well studied and remain unclear. In this study, we quantified the changes of tropospheric O3 budgets, spatiotemporal distributions of future surface O3 in east Asia and regional O3 source contributions for 2060 under a net-zero scenario using the NCAR Community Earth System Model (CESM) and online O3-tagging methods.
Meghna Soni, Rolf Sander, Lokesh K. Sahu, Domenico Taraborrelli, Pengfei Liu, Ankit Patel, Imran A. Girach, Andrea Pozzer, Sachin S. Gunthe, and Narendra Ojha
Atmos. Chem. Phys., 23, 15165–15180, https://doi.org/10.5194/acp-23-15165-2023, https://doi.org/10.5194/acp-23-15165-2023, 2023
Short summary
Short summary
The study presents the implementation of comprehensive multiphase chlorine chemistry in the box model CAABA/MECCA. Simulations for contrasting urban environments of Asia and Europe highlight the significant impacts of chlorine on atmospheric oxidation capacity and composition. Chemical processes governing the production and loss of chlorine-containing species has been discussed. The updated chemical mechanism will be useful to interpret field measurements and for future air quality studies.
Ling Huang, Jiong Fang, Jiaqiang Liao, Greg Yarwood, Hui Chen, Yangjun Wang, and Li Li
Atmos. Chem. Phys., 23, 14919–14932, https://doi.org/10.5194/acp-23-14919-2023, https://doi.org/10.5194/acp-23-14919-2023, 2023
Short summary
Short summary
Surface ozone concentrations have emerged as a major environmental issue in China. Although control strategies aimed at reducing NOx emissions from conventional combustion sources are widely recognized, soil NOx emissions have received little attention. The impact of soil NO emissions on ground-level ozone concentration is yet to be evaluated. In this study, we estimated the soil NO emissions and evaluated its impact on ozone formation in China.
Fu-Jie Zhu, Zi-Feng Zhang, Li-Yan Liu, Pu-Fei Yang, Peng-Tuan Hu, Geng-Bo Ren, Meng Qin, and Wan-Li Ma
EGUsphere, https://doi.org/10.5194/egusphere-2023-2376, https://doi.org/10.5194/egusphere-2023-2376, 2023
Short summary
Short summary
Gas/particle partitioning is an important atmospheric behavior for SVOCs. The observation of that the gaseous degradation could disrupt the equilibrium state of gas/particle partitioning of low molecular weight SVOCs, was demonstrated and evaluated by a steady-state model, with increasing gas/particle partitioning quotients about 1 to 8.4 times. The present study suggested the interplay between degradation and G/P partitioning of SVOCs.
M. Omar Nawaz, Jeremiah Johnson, Greg Yarwood, Benjamin de Foy, Laura M. Judd, and Daniel L. Goldberg
EGUsphere, https://doi.org/10.5194/egusphere-2023-2844, https://doi.org/10.5194/egusphere-2023-2844, 2023
Short summary
Short summary
NO2 is a gas with implications for air pollution. An air campaign conducted in Houston provided an opportunity to compare NO2 from different instruments and a model. Observations from aircrafts and the TROPOMI satellite instrument agreed well with measurements on the ground, however the latter estimated lower values. We find that NO2 simulated in our model performed worse and find the worst performance in downtown Houston, suggesting that vehicle emissions of NO2 may be underestimated.
Ben A. Cala, Scott Archer-Nicholls, James Weber, N. Luke Abraham, Paul T. Griffiths, Lorrie Jacob, Y. Matthew Shin, Laura E. Revell, Matthew Woodhouse, and Alexander T. Archibald
Atmos. Chem. Phys., 23, 14735–14760, https://doi.org/10.5194/acp-23-14735-2023, https://doi.org/10.5194/acp-23-14735-2023, 2023
Short summary
Short summary
Dimethyl sulfide (DMS) is an important trace gas emitted from the ocean recognised as setting the sulfate aerosol background, but its oxidation is complex. As a result representation in chemistry-climate models is greatly simplified. We develop and compare a new mechanism to existing mechanisms via a series of global and box model experiments. Our studies show our updated DMS scheme is a significant improvement but significant variance exists between mechanisms.
Qindan Zhu, Rebecca H. Schwantes, Matthew Coggon, Colin Harkins, Jordan Schnell, Jian He, Havala O. T. Pye, Meng Li, Barry Baker, Zachary Moon, Ravan Ahmadov, Eva Y. Pfannerstill, Bryan Place, Paul Wooldridge, Benjamin C. Schulze, Caleb Arata, Anthony Bucholtz, John H. Seinfeld, Carsten Warneke, Chelsea E. Stockwell, Lu Xu, Kristen Zuraski, Michael A. Robinson, Andy Neuman, Patrick R. Veres, Jeff Peischl, Steven S. Brown, Allen H. Goldstein, Ronald C. Cohen, and Brian C. McDonald
EGUsphere, https://doi.org/10.5194/egusphere-2023-2742, https://doi.org/10.5194/egusphere-2023-2742, 2023
Short summary
Short summary
Volatile organic compounds (VOCs) fuel the production of air pollutants like ozone and particulate matter. The representation of VOC chemistry remains challenging due to its complexity in speciation and reactions. Here, we develop a chemical mechanism, RACM2B-VCP, that better represent VOCs chemistry in urban areas such as Los Angeles. We also discuss the contribution of VOCs emitted from Volatile Chemical Products and other anthropogenic sources to total VOC reactivity and O3.
Christoph Staehle, Harald E. Rieder, and Arlene M. Fiore
EGUsphere, https://doi.org/10.5194/egusphere-2023-2743, https://doi.org/10.5194/egusphere-2023-2743, 2023
Short summary
Short summary
Chemistry-climate models show biases compared to surface ozone observations, and thus require bias-correction for impact studies and the assessment of air quality changes. We compare the performance of commonly used correction techniques for model outputs available via CMIP6. While all methods can reduce model biases, better results are obtained for more complex approaches. Thus, our study suggests broader use of these techniques in studies seeking to inform air quality management and policy.
Jianing Dai, Guy P. Brasseur, Mihalis Vrekoussis, Maria Kanakidou, Kun Qu, Yijuan Zhang, Hongliang Zhang, and Tao Wang
Atmos. Chem. Phys., 23, 14127–14158, https://doi.org/10.5194/acp-23-14127-2023, https://doi.org/10.5194/acp-23-14127-2023, 2023
Short summary
Short summary
In this study, we used a regional chemical transport model to characterize the different parameters of atmospheric oxidative capacity in recent chemical environments in China. These parameters include the production and destruction rates of ozone and other oxidants, the ozone production efficiency, the OH reactivity, and the length of the reaction chain responsible for the formation of ozone and ROx. They are also affected by the aerosol burden in the atmosphere.
Zhenze Liu, Oliver Wild, Ruth M. Doherty, Fiona M. O'Connor, and Steven T. Turnock
Atmos. Chem. Phys., 23, 13755–13768, https://doi.org/10.5194/acp-23-13755-2023, https://doi.org/10.5194/acp-23-13755-2023, 2023
Short summary
Short summary
We investigate the impact of net-zero policies on surface ozone pollution in China. A chemistry–climate model is used to simulate ozone changes driven by local and external emissions, methane, and warmer climates. A deep learning model is applied to generate more robust ozone projection, and we find that the benefits of net-zero policies may be overestimated with the chemistry–climate model. Nevertheless, it is clear that the policies can still substantially reduce ozone pollution in future.
Gemma Purser, Mathew R. Heal, Edward J. Carnell, Stephen Bathgate, Julia Drewer, James I. L. Morison, and Massimo Vieno
Atmos. Chem. Phys., 23, 13713–13733, https://doi.org/10.5194/acp-23-13713-2023, https://doi.org/10.5194/acp-23-13713-2023, 2023
Short summary
Short summary
Forest expansion is a ″net-zero“ pathway, but change in land cover alters air quality in many ways. This study combines tree planting suitability data with UK measured emissions of biogenic volatile organic compounds to simulate spatial and temporal changes in atmospheric composition for planting scenarios of four species. Decreases in fine particulate matter are relatively larger than increases in ozone, which may indicate a net benefit of tree planting on human health aspects of air quality.
Wei Li, Yuxuan Wang, Xueying Liu, Ehsan Soleimanian, Travis Griggs, James Flynn, and Paul Walter
Atmos. Chem. Phys., 23, 13685–13699, https://doi.org/10.5194/acp-23-13685-2023, https://doi.org/10.5194/acp-23-13685-2023, 2023
Short summary
Short summary
This study examined high offshore ozone events in Galveston Bay and the Gulf of Mexico, using boat data and WRF–CAMx modeling during the TRACER-AQ 2021 field campaign. On average, high ozone is caused by chemistry due to the regional transport of volatile organic compounds and downwind advection of NOx from the ship channel. Two case studies show advection of ozone can be another process leading to high ozone, and accurate wind prediction is crucial for air quality forecasting in coastal areas.
Richard G. Derwent, David D. Parrish, and Ian C. Faloona
Atmos. Chem. Phys., 23, 13613–13623, https://doi.org/10.5194/acp-23-13613-2023, https://doi.org/10.5194/acp-23-13613-2023, 2023
Short summary
Short summary
Elevated tropospheric ozone concentrations driven by anthropogenic precursor emissions are a world-wide health and environmental concern; however, this issue lacks a generally accepted understanding of the scientific issues. Here, we briefly outline the elements required to conduct an international assessment process to establish a conceptual model of the underpinning science and motivate international policy forums for regulating ozone production over hemispheric and global scales.
Nicola J. Warwick, Alex T. Archibald, Paul T. Griffiths, James Keeble, Fiona M. O'Connor, John A. Pyle, and Keith P. Shine
Atmos. Chem. Phys., 23, 13451–13467, https://doi.org/10.5194/acp-23-13451-2023, https://doi.org/10.5194/acp-23-13451-2023, 2023
Short summary
Short summary
A chemistry–climate model has been used to explore the atmospheric response to changes in emissions of hydrogen and other species associated with a shift from fossil fuel to hydrogen use. Leakage of hydrogen results in indirect global warming, offsetting greenhouse gas emission reductions from reduced fossil fuel use. To maximise the benefit of hydrogen as an energy source, hydrogen leakage and emissions of methane, carbon monoxide and nitrogen oxides should be minimised.
Susanna Strada, Andrea Pozzer, Graziano Giuliani, Erika Coppola, Fabien Solmon, Xiaoyan Jiang, Alex Guenther, Efstratios Bourtsoukidis, Dominique Serça, Jonathan Williams, and Filippo Giorgi
Atmos. Chem. Phys., 23, 13301–13327, https://doi.org/10.5194/acp-23-13301-2023, https://doi.org/10.5194/acp-23-13301-2023, 2023
Short summary
Short summary
Water deficit modifies emissions of isoprene, an aromatic compound released by plants that influences the production of an air pollutant such as ozone. Numerical modelling shows that, during the warmest and driest summers, isoprene decreases between −20 and −60 % over the Euro-Mediterranean region, while near-surface ozone only diminishes by a few percent. Decreases in isoprene emissions not only happen under dry conditions, but also could occur after prolonged or repeated water deficits.
Jianghao Li, Alastair C. Lewis, Jim R. Hopkins, Stephen J. Andrews, Tim Murrells, Neil Passant, Ben Richmond, Siqi Hou, William Bloss, Roy Harrison, and Zongbo Shi
EGUsphere, https://doi.org/10.5194/egusphere-2023-2294, https://doi.org/10.5194/egusphere-2023-2294, 2023
Short summary
Short summary
A summertime ozone event at an urban site in Birmingham is sensitive to volatile organic compound (VOCs), particularly those of oxygenated VOCs. The roles of anthropogenic VOC sources in urban ozone chemistry are examined by integrating the 1990–2019 national atmospheric emission inventory into model scenarios. Road transport remains the most powerful means to further reduce ozone in this case study, but the benefits maybe offset if solvent emission of VOCs were to continue to increase.
Guowen He, Cheng He, Haofan Wang, Xiao Lu, Chenglei Pei, Xiaonuan Qiu, Chenxi Liu, Yiming Wang, Nanxi Liu, Jinpu Zhang, Lei Lei, Yiming Liu, Haichao Wang, Tao Deng, Qi Fan, and Shaojia Fan
Atmos. Chem. Phys., 23, 13107–13124, https://doi.org/10.5194/acp-23-13107-2023, https://doi.org/10.5194/acp-23-13107-2023, 2023
Short summary
Short summary
We analyze nighttime ozone in the lower boundary layer (up to 500 m) from the 2017–2019 measurements at the Canton Tower and the WRF-CMAQ model. We identify a strong ability of the residual layer to store daytime ozone in the convective mixing layer, investigate the chemical and meteorological factors controlling nighttime ozone in the residual layer, and quantify the contribution of nighttime ozone in the residual layer to both the nighttime and the following day’s surface ozone air quality.
Clara M. Nussbaumer, Horst Fischer, Jos Lelieveld, and Andrea Pozzer
Atmos. Chem. Phys., 23, 12651–12669, https://doi.org/10.5194/acp-23-12651-2023, https://doi.org/10.5194/acp-23-12651-2023, 2023
Short summary
Short summary
Ozone is a greenhouse gas and contributes to the earth’s radiative energy budget and therefore to global warming. This effect is the largest in the upper troposphere. In this study, we investigate the processes controlling ozone formation and the sensitivity to its precursors in the upper tropical troposphere based on model simulations by the ECHAM5/MESSy2 Atmospheric Chemistry (EMAC) model. We find that NO𝑥 emissions from lightning most importantly affect ozone chemistry at these altitudes.
David de la Paz, Rafael Borge, Juan Manuel de Andrés, Luis Miguel Tovar, Golam Sarwar, and Sergey L. Napelenok
EGUsphere, https://doi.org/10.5194/egusphere-2023-2056, https://doi.org/10.5194/egusphere-2023-2056, 2023
Short summary
Short summary
This modelling study shows that around 70 % of ground-level ozone (O3) in Madrid (Spain) is transported from other regions. Nonetheless, local sources, mainly road traffic, play a significant role, specially under stagnation conditions associated to regional air recirculation. Our results suggest that local measures may be effective to reduce O3 peaks (potentially, up to 30 %) and thus, reduce impacts from high-O3 episodes in the Madrid metropolitan area.
Alba Badia, Veronica Vidal, Sergi Ventura, Roger Curcoll, Ricard Segura, and Gara Villalba
Atmos. Chem. Phys., 23, 10751–10774, https://doi.org/10.5194/acp-23-10751-2023, https://doi.org/10.5194/acp-23-10751-2023, 2023
Short summary
Short summary
Improving air quality is a top priority in urban areas. In this study, we used an air quality model to analyse the air quality changes occurring over the metropolitan area of Barcelona and other rural areas affected by transport of the atmospheric plume from the city during mobility restrictions. Our results show that mitigation strategies intended to reduce O3 should be designed according to the local meteorology, air transport, and particular ozone chemistry of the urban area.
Herizo Narivelo, Paul David Hamer, Virginie Marécal, Luke Surl, Tjarda Roberts, Sophie Pelletier, Béatrice Josse, Jonathan Guth, Mickaël Bacles, Simon Warnach, Thomas Wagner, Stefano Corradini, Giuseppe Salerno, and Lorenzo Guerrieri
Atmos. Chem. Phys., 23, 10533–10561, https://doi.org/10.5194/acp-23-10533-2023, https://doi.org/10.5194/acp-23-10533-2023, 2023
Short summary
Short summary
Volcanic emissions emit large quantities of gases and primary aerosols that can play an important role in atmospheric chemistry. We present a study of the fate of volcanic bromine emissions from the eruption of Mount Etna around Christmas 2018. Using a numerical model and satellite observations, we analyse the impact of the volcanic plume and how it modifies the composition of the air over the whole Mediterranean basin, in particular on tropospheric ozone through the bromine-explosion cycle.
Michael P. Cartwright, Richard J. Pope, Jeremy J. Harrison, Martyn P. Chipperfield, Chris Wilson, Wuhu Feng, David P. Moore, and Parvadha Suntharalingam
Atmos. Chem. Phys., 23, 10035–10056, https://doi.org/10.5194/acp-23-10035-2023, https://doi.org/10.5194/acp-23-10035-2023, 2023
Short summary
Short summary
A 3-D chemical transport model, TOMCAT, is used to simulate global atmospheric carbonyl sulfide (OCS) distribution. Modelled OCS compares well with satellite observations of OCS from limb-sounding satellite observations. Model simulations also compare adequately with surface and atmospheric observations and suitably capture the seasonality of OCS and background concentrations.
Luana S. Basso, Chris Wilson, Martyn P. Chipperfield, Graciela Tejada, Henrique L. G. Cassol, Egídio Arai, Mathew Williams, T. Luke Smallman, Wouter Peters, Stijn Naus, John B. Miller, and Manuel Gloor
Atmos. Chem. Phys., 23, 9685–9723, https://doi.org/10.5194/acp-23-9685-2023, https://doi.org/10.5194/acp-23-9685-2023, 2023
Short summary
Short summary
The Amazon’s carbon balance may have changed due to forest degradation, deforestation and warmer climate. We used an atmospheric model and atmospheric CO2 observations to quantify Amazonian carbon emissions (2010–2018). The region was a small carbon source to the atmosphere, mostly due to fire emissions. Forest uptake compensated for ~ 50 % of the fire emissions, meaning that the remaining forest is still a small carbon sink. We found no clear evidence of weakening carbon uptake over the period.
Rui Zhu, Zhaojun Tang, Xiaokang Chen, Xiong Liu, and Zhe Jiang
Atmos. Chem. Phys., 23, 9745–9763, https://doi.org/10.5194/acp-23-9745-2023, https://doi.org/10.5194/acp-23-9745-2023, 2023
Short summary
Short summary
Ozone Monitoring Instrument (OMI) and surface O3 observations are used to investigate the changes in tropospheric O3 in the USA and Europe in 2005–2020. The surface-based assimilations show limited changes in surface and tropospheric column O3. The OMI-based assimilations show larger decreases in tropospheric O3 columns in 2010–2014, related to a decline in free-tropospheric NO2. Analysis suggests limited impacts of local emissions decline on tropospheric O3 over the USA and Europe in 2005–2020.
R. Bradley Pierce, Monica Harkey, Allen Lenzen, Lee M. Cronce, Jason A. Otkin, Jonathan L. Case, David S. Henderson, Zac Adelman, Tsengel Nergui, and Christopher R. Hain
Atmos. Chem. Phys., 23, 9613–9635, https://doi.org/10.5194/acp-23-9613-2023, https://doi.org/10.5194/acp-23-9613-2023, 2023
Short summary
Short summary
We evaluate two high-resolution model simulations with different meteorological inputs but identical chemistry and anthropogenic emissions, with the goal of identifying a model configuration best suited for characterizing air quality in locations where lake breezes commonly affect local air quality along the Lake Michigan shoreline. This analysis complements other studies in evaluating the impact of meteorological inputs and parameterizations on air quality in a complex environment.
Shreta Ghimire, Zachary J. Lebo, Shane Murphy, Stefan Rahimi, and Trang Tran
Atmos. Chem. Phys., 23, 9413–9438, https://doi.org/10.5194/acp-23-9413-2023, https://doi.org/10.5194/acp-23-9413-2023, 2023
Short summary
Short summary
High wintertime ozone levels have occurred often in recent years in mountain basins with oil and gas production facilities. Photochemical modeling of ozone production serves as a basis for understanding the mechanism by which it occurs and for predictive capability. We present photochemical model simulations of ozone formation and accumulation in the Upper Green River basin, Wyoming, demonstrating the model's ability to simulate wintertime ozone and the sensitivity of ozone to its precursors.
Cited articles
Abbatt, J. P. D.: Interaction of HNO3 with water–ice surfaces at temperatures of the free troposphere, Geophys. Res. Lett., 24, 1479–1482, https://doi.org/10.1029/97GL01403, 1997.
Abbatt, J. P. D.: Interactions of atmospheric trace gases with ice surfaces: adsorption and reaction, Chem. Rev., 103, 4783–4800, https://doi.org/10.1021/cr0206418, 2003.
Abbatt, J. P. D., Bartels-Rausch, T., Ullerstam, M., and Ye, T. J.: Uptake of acetone, ethanol and benzene to snow and ice: effects of surface area and temperature, Environ. Res. Lett., 3, 045008, https://doi.org/10.1088/1748-9326/3/4/045008, 2008.
Arimoto, R., Zeng, T., Davis, D., Wang, Y., Khaing, H., Nesbit, C., and Huey, G.: Concentrations and sources of aerosol ions and trace elements during ANTCI-2003, Atmos. Environ., 42, 2864–2876, https://doi.org/10.1016/j.atmosenv.2007.05.054, 2008.
Arora, O. P., Cziczo, D. J., Morgan, A. M., Abbatt, J. P. D., and Niedziela, R. F.: Uptake of nitric acid by sub-micron-sized ice particles, Geophys. Res. Lett., 26, 3621–3624, https://doi.org/10.1029/1999GL010881, 1999.
Bales, R. C., Losleben, M. V., McConnell, J. R., Fuhrer, K., and Neftel, A.: H2O2 in snow, air and open pore space in firn at Summit, Greenland, Geophys. Res. Lett., 22, 1261–1264, https://doi.org/10.1029/95GL01110, 1995.
Barret, M., Dominé, F., Houdier, S., Gallet, J.-C., Weibring, P., Walega, J., Fried, A., and Richter, D.: Formaldehyde in the Alaskan Arctic snowpack: partitioning and physical processes involved in air-snow exchanges, J. Geophys. Res., 116, D00R03, https://doi.org/10.1029/2011JD016038, 2011a.
Barret, M., Houdier, S., and Dominé, F.: Thermodynamics of the formaldehyde–water and formaldehyde–ice systems for atmospheric applications, J. Phys. Chem. A, 115, 307–317, https://doi.org/10.1021/jp108907u, 2011b.
Beine, H., Dominé, F., Simpson, W., Honrath, R., Sparapani, R., Zhou, X., and King, M.: Snow-pile and chamber experiments during the Polar Sunrise Experiment “Alert 2000”: exploration of nitrogen chemistry, Atmos. Environ., 36, 2707–2719, https://doi.org/10.1016/S1352-2310(02)00120-6, 2002.
Beine, H. J., Dominé, F., Ianniello, A., Nardino, M., Allegrini, I., Teinilä, K., and Hillamo, R.: Fluxes of nitrates between snow surfaces and the atmosphere in the European high Arctic, Atmos. Chem. Phys., 3, 335–346, https://doi.org/10.5194/acp-3-335-2003, 2003.
Berhanu, T. A., Meusinger, C., Erbland, J., Jost, R., Bhattacharya, S. K., Johnson, M. S., and Savarino, J.: Laboratory study of nitrate photolysis in Antarctic snow. II. Isotopic effects and wavelength dependence, J. Chem. Phys., 140, 244306, https://doi.org/10.1063/1.4882899, 2014.
Bianco, R., Wang, S., and Hynes, J. T.: Theoretical study of the dissociation of nitric acid at a model aqueous surface, J. Phys. Chem. A, 111, 11033–11042, https://doi.org/10.1021/jp075054a, 2007.
Bianco, R., Wang, S., and Hynes, J. T.: Infrared signatures of HNO3 and NO3− at a model aqueous surface. A theoretical study, J. Phys. Chem. A, 112, 9467–9476, https://doi.org/10.1021/jp802563g, 2008.
Bock, J. and Jacobi, H.-W.: Development of a mechanism for nitrate photochemistry in snow, J. Phys. Chem. A, 114, 1790–1796, https://doi.org/10.1021/jp909205e, 2010.
Bolton, K. and Pettersson, J. B. C.: A molecular dynamics study of the long-time ice Ih surface dynamics, J. Phys. Chem. B, 104, 1590–1595, https://doi.org/10.1021/jp9934883, 2000.
Boxe, C. S. and Saiz-Lopez, A.: Multiphase modeling of nitrate photochemistry in the quasi-liquid layer (QLL): implications for NOx release from the Arctic and coastal Antarctic snowpack, Atmos. Chem. Phys., 8, 4855–4864, https://doi.org/10.5194/acp-8-4855-2008, 2008.
Brandt, R. E. and Warren, S. G.: Solar-heating rates and temperature profiles in Antarctic snow and ice, J. Glaciol., 39, 99–110, https://doi.org/10.3198/1993JoG39-131-99-110, 1993.
Brun, E., Six, D., Picard, G., Vionnet, V., Arnaud, L., Bazile, E., Boone, A., Bouchard, A., Genthon, C., Guidard, V., Le Moigne, P., Rabier, F., and Seity, Y.: Snow/atmosphere coupled simulation at Dome C, Antarctica, J. Glaciol., 57, 721–736, https://doi.org/10.3189/002214311797409794, 2011.
Buch, V., Sadlej, J., Aytemiz-Uras, N., and Devlin, J. P.: Solvation and ionization stages of HCl on ice nanocrystals, J. Phys. Chem. A, 106, 9374–9389, https://doi.org/10.1021/jp021539h, 2002.
Calonne, N., Geindreau, C., and Flin, F.: Macroscopic modeling for heat and water vapor transfer in dry snow by homogenization, J. Phys. Chem. B, 118, 13393–13403, https://doi.org/10.1021/jp5052535, 2014.
Champollion, N., Picard, G., Arnaud, L., Lefebvre, E., and Fily, M.: Hoar crystal development and disappearance at Dome C, Antarctica: observation by near-infrared photography and passive microwave satellite, The Cryosphere, 7, 1247–1262, https://doi.org/10.5194/tc-7-1247-2013, 2013.
Chu, L. and Anastasio, C.: Quantum yields of hydroxyl radical and nitrogen dioxide from the photolysis of nitrate on ice, J. Phys. Chem. A, 107, 9594–9602, https://doi.org/10.1021/jp0349132, 2003.
Chu, L. and Anastasio, C.: Temperature and wavelength dependence of nitrite photolysis in frozen and aqueous solutions, Environ. Sci. Technol., 41, 3626–3632, https://doi.org/10.1021/es062731q, 2007.
Colbeck, S.: Snow-crystal growth with varying surface temperatures and radiation penetration, J. Glaciol., 35, 23–29, https://doi.org/10.3189/002214389793701536, 1989.
Conklin, M. H., Sigg, A., Neftel, A., and Bales, R. C.: Atmosphere-snow transfer function for H2O2: microphysical considerations, J. Geophys. Res., 98, 18367–18376, https://doi.org/10.1029/93JD01194, 1993.
Cotter, E. S. N., Jones, A. E., Wolff, E. W., and Bauguitte, S. J.-B.: What controls photochemical NO and NO2 production from Antarctic snow? Laboratory investigation assessing the wavelength and temperature dependence, J. Geophys. Res., 108, 4147, https://doi.org/10.1029/2002JD002602, 2003.
Cox, R. A., Fernandez, M. A., Symington, A., Ullerstam, M., and Abbatt, J. P. D.: A kinetic model for uptake of HNO3 and HCl on ice in a coated wall flow system, Phys. Chem. Chem. Phys., 7, 3434–3442, https://doi.org/10.1039/b506683b, 2005.
Crowley, J. N., Ammann, M., Cox, R. A., Hynes, R. G., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., and Wallington, T. J.: Evaluated kinetic and photochemical data for atmospheric chemistry: Volume V – heterogeneous reactions on solid substrates, Atmos. Chem. Phys., 10, 9059–9223, https://doi.org/10.5194/acp-10-9059-2010, 2010.
Davis, D., Eisele, F., Chen, G., Crawford, J., Huey, G., Tanner, D., Slusher, D., Mauldin, L., Oncley, S., Lenschow, D., Semmer, S., Shetter, R., Lefer, B., Arimoto, R., Hogan, A., Grube, P., Lazzara, M., Bandy, A., Thornton, D., Berresheim, H., Bingemer, H., Hutterli, M., McConnell, J., Bales, R., Dibb, J., Buhr, M., Park, J., McMurry, P., Swanson, A., Meinardi, S., and Blake, D.: An overview of ISCAT 2000, Atmos. Environ., 38, 5363–5373, https://doi.org/10.1016/j.atmosenv.2004.05.037, 2004.
Davis, D., Seelig, J., Huey, G., Crawford, J., Chen, G., Wang, Y., Buhr, M., Helmig, D., Neff, W., and Blake, D.: A reassessment of Antarctic plateau reactive nitrogen based on ANTCI 2003 airborne and ground based measurements, Atmos. Environ., 42, 2831–2848, https://doi.org/10.1016/j.atmosenv.2007.07.039, 2008.
Dibb, J. E., Talbot, R. W., Munger, J. W., Jacob, D. J., and Fan, S.-M.: Air-snow exchange of HNO3 and NOy at Summit, Greenland, J. Geophys. Res., 103, 3475–3486, https://doi.org/10.1029/97JD03132, 1998.
Dibb, J. E., Arsenault, M., Peterson, M. C., and Honrath, R. E.: Fast nitrogen oxide photochemistry in Summit, Greenland snow, Atmos. Environ., 36, 2501–2511, https://doi.org/10.1016/S1352-2310(02)00130-9, 2002.
Dibb, J. E., Gregory Huey, L., Slusher, D. L., and Tanner, D. J.: Soluble reactive nitrogen oxides at South Pole during ISCAT 2000, Atmos. Environ., 38, 5399–5409, https://doi.org/10.1016/j.atmosenv.2003.01.001, 2004.
Dominé, F. and Rauzy, C.: Influence of the ice growth rate on the incorporation of gaseous HCl, Atmos. Chem. Phys., 4, 2513–2519, https://doi.org/10.5194/acp-4-2513-2004, 2004.
Dominé, F. and Thibert, E.: Relationship between atmospheric composition and snow composition for HCl and HNO3, in: Proceedings of a Boulder Symposium, IAHS Publ. no. 228, pp. 3–10, edited by: Tonnessen, K. A., Williams, M. W., and Tranter, M., 12–13 July 1995, Boulder, Colorado, USA, 1995.
Dominé, F. and Thibert, E.: Mechanism of incorporation of trace gases in ice grown from the gas phase, Geophys. Res. Lett., 23, 3627–3630, https://doi.org/10.1029/96GL03290, 1996.
Dominé, F., Thibert, E., Van Landeghem, F., Silvente, E., and Wagnon, P.: Diffusion and solubility of HCl in ice: preliminary results, Geophys. Res. Lett., 21, 601–604, https://doi.org/10.1029/94GL00512, 1994.
Dominé, F., Thibert, E., Silvente, E., Legrand, M., and Jaffrezo, J.-L.: Determining past atmospheric HCl mixing ratios from ice core analyses, J. Atmos. Chem., 21, 165–186, https://doi.org/10.1007/BF00696579, 1995.
Dominé, F., Albert, M., Huthwelker, T., Jacobi, H.-W., Kokhanovsky, A. A., Lehning, M., Picard, G., and Simpson, W. R.: Snow physics as relevant to snow photochemistry, Atmos. Chem. Phys., 8, 171–208, https://doi.org/10.5194/acp-8-171-2008, 2008.
Dominé, F., Bock, J., Voisin, D., and Donaldson, D. J.: Can we model snow photochemistry? Problems with the current approaches, J. Phys. Chem. A, 117, 4733–4749, https://doi.org/10.1021/jp3123314, 2013.
Dubowski, Y., Colussi, A. J., and Hoffmann, M. R.: Nitrogen dioxide release in the 302 nm band photolysis of spray-frozen aqueous nitrate solutions. Atmospheric implications, J. Phys. Chem. A, 105, 4928–4932, https://doi.org/10.1021/jp0042009, 2001.
Dubowski, Y., Colussi, A. J., Boxe, C., and Hoffmann, M. R.: Monotonic increase of nitrite yields in the photolysis of nitrate in ice and water between 238 and 294 K, J. Phys. Chem. A, 106, 6967–6971, https://doi.org/10.1021/jp0142942, 2002.
Ebner, P. P., Andreoli, C., Schneebeli, M., and Steinfeld, A.: Tomography-based characterization of ice-air interface dynamics of temperature gradient snow metamorphism under advective conditions, J. Geophys. Res.-Earth, 120, 2437–2451, https://doi.org/10.1002/2015JF003648, 2015.
Eisele, F., Davis, D., Helmig, D., Oltmans, S., Neff, W., Huey, G., Tanner, D., Chen, G., Crawford, J., and Arimoto, R.: Antarctic Tropospheric Chemistry Investigation (ANTCI) 2003 overview, Atmos. Environ., 42, 2749–2761, https://doi.org/10.1016/j.atmosenv.2007.04.013, 2008.
Erbland, J., Vicars, W. C., Savarino, J., Morin, S., Frey, M. M., Frosini, D., Vince, E., and Martins, J. M. F.: Air–snow transfer of nitrate on the East Antarctic Plateau – Part 1: Isotopic evidence for a photolytically driven dynamic equilibrium in summer, Atmos. Chem. Phys., 13, 6403–6419, https://doi.org/10.5194/acp-13-6403-2013, 2013.
Erbland, J., Savarino, J., Morin, S., France, J. L., Frey, M. M., and King, M. D.: Air–snow transfer of nitrate on the East Antarctic Plateau – Part 2: An isotopic model for the interpretation of deep ice-core records, Atmos. Chem. Phys., 15, 12079–12113, https://doi.org/10.5194/acp-15-12079-2015, 2015.
Finlayson-Pitts, B. J. and Pitts, J. N.: Chemistry of the upper and lower atmosphere: theory, experiments, and applications, Academic Press, San Diego, USA, 2000.
Flanner, M. G. and Zender, C. S.: Linking snowpack microphysics and albedo evolution, J. Geophys. Res., 111, D12208, https://doi.org/10.1029/2005JD006834, 2006.
Flin, F. and Brzoska, J.-B.: The temperature-gradient metamorphism of snow: vapour diffusion model and application to tomographic images, Ann. Glaciol., 49, 17–21, https://doi.org/10.3189/172756408787814834, 2008.
Flin, F., Brzoska, J.-B., Lesaffre, B., Coléou, C., and Pieritz, R. A.: Full three-dimensional modelling of curvature-dependent snow metamorphism: first results and comparison with experimental tomographic data, J. Phys. D Appl. Phys., 36, A49–A54, https://doi.org/10.1088/0022-3727/36/10A/310, 2003.
France, J. L., King, M. D., Frey, M. M., Erbland, J., Picard, G., Preunkert, S., MacArthur, A., and Savarino, J.: Snow optical properties at Dome C (Concordia), Antarctica; implications for snow emissions and snow chemistry of reactive nitrogen, Atmos. Chem. Phys., 11, 9787–9801, https://doi.org/10.5194/acp-11-9787-2011, 2011.
Fréville, H., Brun, E., Picard, G., Tatarinova, N., Arnaud, L., Lanconelli, C., Reijmer, C., and van den Broeke, M.: Using MODIS land surface temperatures and the Crocus snow model to understand the warm bias of ERA-Interim reanalyses at the surface in Antarctica, The Cryosphere, 8, 1361–1373, https://doi.org/10.5194/tc-8-1361-2014, 2014.
Frey, M. M., Savarino, J., Morin, S., Erbland, J., and Martins, J. M. F.: Photolysis imprint in the nitrate stable isotope signal in snow and atmosphere of East Antarctica and implications for reactive nitrogen cycling, Atmos. Chem. Phys., 9, 8681–8696, https://doi.org/10.5194/acp-9-8681-2009, 2009.
Gallet, J.-C., Dominé, F., Arnaud, L., Picard, G., and Savarino, J.: Vertical profile of the specific surface area and density of the snow at Dome C and on a transect to Dumont D'Urville, Antarctica – albedo calculations and comparison to remote sensing products, The Cryosphere, 5, 631–649, https://doi.org/10.5194/tc-5-631-2011, 2011.
Gallet, J.-C., Dominé, F., Savarino, J., Dumont, M., and Brun, E.: The growth of sublimation crystals and surface hoar on the Antarctic plateau, The Cryosphere, 8, 1205–1215, https://doi.org/10.5194/tc-8-1205-2014, 2014.
Hansen, A. C. and Foslien, W. E.: A macroscale mixture theory analysis of deposition and sublimation rates during heat and mass transfer in dry snow, The Cryosphere, 9, 1857–1878, https://doi.org/10.5194/tc-9-1857-2015, 2015.
Hanson, D. R.: The uptake of HNO3 onto ice, NAT, and frozen sulfuric acid, Geophys. Res. Lett., 19, 2063–2066, https://doi.org/10.1029/92GL02182, 1992.
Hobbs, P. V.: Ice physics, Clarendon Press, Oxford, UK, 1974.
Honrath, R., Lu, Y., Peterson, M., Dibb, J., Arsenault, M., Cullen, N., and Steffen, K.: Vertical fluxes of NOx, HONO, and HNO3 above the snowpack at Summit, Greenland, Atmos. Environ., 36, 2629–2640, https://doi.org/10.1016/S1352-2310(02)00132-2, 2002.
Honrath, R. E., Peterson, M. C., Guo, S., Dibb, J. E., Shepson, P. B., and Campbell, B.: Evidence of NOx production within or upon ice particles in the Greenland snowpack, Geophys. Res. Lett., 26, 695–698, https://doi.org/10.1029/1999GL900077, 1999.
Honrath, R. E., Guo, S., Peterson, M. C., Dziobak, M. P., Dibb, J. E., and Arsenault, M. A.: Photochemical production of gas phase NOx from ice crystal NO3−, J. Geophys. Res., 105, 24183–24190, https://doi.org/10.1029/2000JD900361, 2000a.
Honrath, R. E., Peterson, M. C., Dziobak, M. P., Dibb, J. E., Arsenault, M. A., and Green, S. A.: Release of NOx from sunlight-irradiated midlatitude snow, Geophys. Res. Lett., 27, 2237–2240, https://doi.org/10.1029/1999GL011286, 2000b.
Hudson, P. K., Shilling, J. E., Tolbert, M. A., and Toon, O. B.: Uptake of nitric acid on ice at tropospheric temperatures: implications for cirrus clouds, J. Phys. Chem. A, 106, 9874–9882, https://doi.org/10.1021/jp020508j, 2002.
Huthwelker, T., Ammann, M., and Peter, T.: The uptake of acidic gases on ice, Chem. Rev., 106, 1375–1444, https://doi.org/10.1021/cr020506v, 2006.
Hutterli, M. A., Röthlisberger, R., and Bales, R. C.: Atmosphere-to-snow-to-firn transfer studies of HCHO at Summit, Greenland, Geophys. Res. Lett., 26, 1691–1694, https://doi.org/10.1029/1999GL900327, 1999.
Hutterli, M. A., Bales, R. C., McConnell, J. R., and Stewart, R. W.: HCHO in Antarctic snow: preservation in ice cores and air-snow exchange, Geophys. Res. Lett., 29, 1235, https://doi.org/10.1029/2001GL014256, 2002.
Hutterli, M. A., McConnell, J. R., Bales, R. C., and Stewart, R. W.: Sensitivity of hydrogen peroxide (H2O2) and formaldehyde (HCHO) preservation in snow to changing environmental conditions: implications for ice core records, J. Geophys. Res., 108, 4023, https://doi.org/10.1029/2002JD002528, 2003.
Hynes, R. G., Fernandez, M. A., and Cox, R. A.: Uptake of HNO3 on water-ice and coadsorption of HNO3 and HCl in the temperature range 210–235 K, J. Geophys. Res., 107, 4797, https://doi.org/10.1029/2001JD001557, 2002.
Jacob, P. and Klockow, D.: Measurements of hydrogen peroxide in Antarctic ambient air, snow and firn cores, Fresen. J. Anal. Chem., 346, 429–434, https://doi.org/10.1007/BF00325856, 1993.
Jacobi, H.-W. and Hilker, B.: A mechanism for the photochemical transformation of nitrate in snow, J. Photoch. Photobio. A, 185, 371–382, https://doi.org/10.1016/j.jphotochem.2006.06.039, 2007.
Jones, A. E., Weller, R., Wolff, E. W., and Jacobi, H. W.: Speciation and rate of photochemical NO and NO2 production in Antarctic snow, Geophys. Res. Lett., 27, 345–348, https://doi.org/10.1029/1999GL010885, 2000.
Jones, A. E., Wolff, E. W., Salmon, R. A., Bauguitte, S. J.-B., Roscoe, H. K., Anderson, P. S., Ames, D., Clemitshaw, K. C., Fleming, Z. L., Bloss, W. J., Heard, D. E., Lee, J. D., Read, K. A., Hamer, P., Shallcross, D. E., Jackson, A. V., Walker, S. L., Lewis, A. C., Mills, G. P., Plane, J. M. C., Saiz-Lopez, A., Sturges, W. T., and Worton, D. R.: Chemistry of the Antarctic Boundary Layer and the Interface with Snow: an overview of the CHABLIS campaign, Atmos. Chem. Phys., 8, 3789–3803, https://doi.org/10.5194/acp-8-3789-2008, 2008.
Jones, A. E., Wolff, E. W., Ames, D., Bauguitte, S. J.-B., Clemitshaw, K. C., Fleming, Z., Mills, G. P., Saiz-Lopez, A., Salmon, R. A., Sturges, W. T., and Worton, D. R.: The multi-seasonal NOy budget in coastal Antarctica and its link with surface snow and ice core nitrate: results from the CHABLIS campaign, Atmos. Chem. Phys., 11, 9271–9285, https://doi.org/10.5194/acp-11-9271-2011, 2011.
Jones, A. E., Brough, N., Anderson, P. S., and Wolff, E. W.: HO2NO2 and HNO3 in the coastal Antarctic winter night: a “lab-in-the-field” experiment, Atmos. Chem. Phys., 14, 11843–11851, https://doi.org/10.5194/acp-14-11843-2014, 2014.
Kaempfer, T. and Plapp, M.: Phase-field modeling of dry snow metamorphism, Phys. Rev. E, 79, 031502, https://doi.org/10.1103/PhysRevE.79.031502, 2009.
Kärcher, B. and Basko, M. M.: Trapping of trace gases in growing ice crystals, J. Geophys. Res.-Atmos., 109, D22204, https://doi.org/10.1029/2004JD005254, 2004.
Kärcher, B., Abbatt, J. P. D., Cox, R. A., Popp, P. J., and Voigt, C.: Trapping of trace gases by growing ice surfaces including surface-saturated adsorption, J. Geophys. Res., 114, D13306, https://doi.org/10.1029/2009JD011857, 2009.
Křepelová, A., Newberg, J., Huthwelker, T., Bluhm, H., and Ammann, M.: The nature of nitrate at the ice surface studied by XPS and NEXAFS, Phys. Chem. Chem. Phys., 12, 8870–8880, https://doi.org/10.1039/c0cp00359j, 2010.
Kuipers Munneke, P., van den Broeke, M. R., Reijmer, C. H., Helsen, M. M., Boot, W., Schneebeli, M., and Steffen, K.: The role of radiation penetration in the energy budget of the snowpack at Summit, Greenland, The Cryosphere, 3, 155–165, https://doi.org/10.5194/tc-3-155-2009, 2009.
Laird, S. K. and Sommerfeld, R. A.: Nitric acid adsorption on ice: a preliminary study, Geophys. Res. Lett., 22, 921–923, https://doi.org/10.1029/95GL00817, 1995.
Legrand, M. and Mayewski, P.: Glaciochemistry of polar ice cores: a review, Rev. Geophys., 35, 219–243, https://doi.org/10.1029/96RG03527, 1997.
Leu, M.-T.: Laboratory studies of sticking coefficients and heterogeneous reactions important in the Antarctic stratosphere, Geophys. Res. Let., 15, 17–20, https://doi.org/10.1029/GL015i001p00017, 1988.
Leu, M.-T., Keyser, L. F., and Timonen, R. S.: Morphology and surface areas of thin ice films, J. Phys. Chem. B, 101, 6259–6262, https://doi.org/10.1021/jp963251w, 1997.
Liao, W. and Tan, D.: 1-D Air-snowpack modeling of atmospheric nitrous acid at South Pole during ANTCI 2003, Atmos. Chem. Phys., 8, 7087–7099, https://doi.org/10.5194/acp-8-7087-2008, 2008.
Libois, Q., Picard, G., Dumont, M., Arnaud, L., Sergent, C., Pougatch, E., Sudul, M., and Vial, D.: Experimental determination of the absorption enhancement parameter of snow, J. Glaciol., 60, 714–724, https://doi.org/10.3189/2014JoG14J015, 2014.
Libois, Q., Picard, G., Arnaud, L., Dumont, M., Lafaysse, M., Morin, S., and Lefebvre, E.: Summertime evolution of snow specific surface area close to the surface on the Antarctic Plateau, The Cryosphere, 9, 2383–2398, https://doi.org/10.5194/tc-9-2383-2015, 2015.
Marbouty, D.: An experimental study of temperature-gradient metamorphism, J. Glaciol., 26, 303–312, 1980.
Marchand, P., Marcotte, G., and Ayotte, P.: Spectroscopic study of HNO3 dissociation on ice, J. Phys. Chem. A, 116, 12112–12122, https://doi.org/10.1021/jp309533f, 2012.
Marcotte, G., Ayotte, P., Bendounan, A., Sirotti, F., Laffon, C., and Parent, P.: Dissociative adsorption of nitric acid at the surface of amorphous solid water revealed by X-ray absorption spectroscopy, J. Phys. Chem. Lett., 4, 2643–2648, https://doi.org/10.1021/jz401310j, 2013.
Marcotte, G., Marchand, P., Pronovost, S., Ayotte, P., Laffon, C., and Parent, P.: Surface-enhanced nitrate photolysis on ice, J. Phys. Chem. A, 119, 1996–2005, https://doi.org/10.1021/jp511173w, 2015.
McConnell, J. R., Bales, R. C., Winterle, J. R., Kuhns, H., and Stearns, C. R.: A lumped parameter model for the atmosphere-to-snow transfer function for hydrogen peroxide, J. Geophys. Res., 102, 26809–26818, https://doi.org/10.1029/96JC02194, 1997a.
McConnell, J. R., Winterle, J. R., Bales, R. C., Thompson, A. M., and Stewart, R. W.: Physically based inversion of surface snow concentrations of H2O2 to atmospheric concentrations at South Pole, Geophys. Res. Lett., 24, 441–444, https://doi.org/10.1029/97GL00183, 1997b.
McConnell, J. R., Bales, R. C., Stewart, R. W., Thompson, A. M., Albert, M. R., and Ramos, R.: Physically based modeling of atmosphere-to-snow-to-firn transfer of H2O2 at South Pole, J. Geophys. Res., 103, 10561–10570, https://doi.org/10.1029/98JD00460, 1998.
Meusinger, C., Berhanu, T. A., Erbland, J., Savarino, J., and Johnson, M. S.: Laboratory study of nitrate photolysis in Antarctic snow. I. Observed quantum yield, domain of photolysis, and secondary chemistry, J. Chem. Phys., 140, 244305, https://doi.org/10.1063/1.4882898, 2014.
Miller, D. and Adams, E.: A microstructural dry-snow metamorphism model for kinetic crystal growth, J. Glaciol., 55, 1003–1011, https://doi.org/10.3189/002214309790794832, 2009.
Murray, K. A., Kramer, L. J., Doskey, P. V., Ganzeveld, L., Seok, B., Van Dam, B., and Helmig, D.: Dynamics of ozone and nitrogen oxides at Summit, Greenland. II. Simulating snowpack chemistry during a spring high ozone event with a 1-D process-scale model, Atmos. Environ., 117, 110–123, https://doi.org/10.1016/j.atmosenv.2015.07.004, 2015.
Perrier, S., Sassin, P., and Dominé, F.: Diffusion and solubility of HCHO in ice: preliminary results, Can. J. Phys., 81, 319–324, https://doi.org/10.1139/p03-033, 2003.
Picard, G., Brucker, L., Fily, M., Gallée, H., and Krinner, G.: Modeling time series of microwave brightness temperature in Antarctica, J. Glaciol., 55, 537–551, https://doi.org/10.3189/002214309788816678, 2009.
Picard, G., Dominé, F., Krinner, G., Arnaud, L., and Lefebvre, E.: Inhibition of the positive snow-albedo feedback by precipitation in interior Antarctica, Nature Climate Change, 2, 795–798, https://doi.org/10.1038/nclimate1590, 2012.
Picard, G., Libois, Q., Arnaud, L., Verin, G., and Dumont, M.: Development and calibration of an automatic spectral albedometer to estimate near-surface snow SSA time series, The Cryosphere, 10, 1297–1316, https://doi.org/10.5194/tc-10-1297-2016, 2016.
Pinzer, B. R. and Schneebeli, M.: Snow metamorphism under alternating temperature gradients: morphology and recrystallization in surface snow, Geophys. Res. Lett., 36, L23503, https://doi.org/10.1029/2009GL039618, 2009.
Pinzer, B. R., Schneebeli, M., and Kaempfer, T. U.: Vapor flux and recrystallization during dry snow metamorphism under a steady temperature gradient as observed by time-lapse micro-tomography, The Cryosphere, 6, 1141–1155, https://doi.org/10.5194/tc-6-1141-2012, 2012.
Preunkert, S., Ancellet, G., Legrand, M., Kukui, A., Kerbrat, M., Sarda-Estève, R., Gros, V., and Jourdain, B.: Oxidant Production over Antarctic Land and its Export (OPALE) project: an overview of the 2010–2011 summer campaign, J. Geophys. Res., 117, D15307, https://doi.org/10.1029/2011JD017145, 2012.
Pruppacher, H. R. and Klett, J. D.: Microphysics of clouds and precipitation, 2nd revised and enlarged edn., Kluwer Academic Publishers, Dordrecht/Boston/London, 1997.
Riikonen, S., Parkkinen, P., Halonen, L., and Gerber, R. B.: Ionization of nitric acid on crystalline ice: the role of defects and collective proton movement, J. Phys. Chem. Lett., 4, 1850–1855, https://doi.org/10.1021/jz400531q, 2013.
Riikonen, S., Parkkinen, P., Halonen, L., and Gerber, R. B.: Ionization of acids on the quasi-liquid layer of ice, J. Phys. Chem. A, 118, 5029–5037, https://doi.org/10.1021/jp505627n, 2014.
Röthlisberger, R., Hutterli, M. A., Wolff, E. W., Mulvaney, R., Fischer, H., Bigler, M., Goto-Azuma, K., Hansson, M. E., Ruth, U., Siggaard-Andersen, M.-L., and Steffensen, J. P.: Nitrate in Greenland and Antarctic ice cores: a detailed description of post-depositional processes, Ann. Glaciol., 35, 209–216, https://doi.org/10.3189/172756402781817220, 2002.
Seinfeld, J. H. and Pandis, S. N.: Atmospheric chemistry and physics : from air pollution to climate change, Wiley, New York, USA, 1998.
Sigg, A. and Neftel, A.: Seasonal variations in hydrogen peroxide in polar ice cores, Ann. Glaciol., 10, 157–162, 1988.
Sigg, A., Staffelbach, T., and Neftel, A.: Gas phase measurements of hydrogen peroxide in Greenland and their meaning for the interpretation of H2O2 records in ice cores, J. Atmos. Chem., 14, 223–232, https://doi.org/10.1007/BF00115235, 1992.
Sokolov, O. and Abbatt, J. P. D.: Competitive adsorption of atmospheric trace gases onto ice at 228 K: HNO3/HCl, 1-Butanol/Acetic acid and 1-Butanol/HCl, Geophys. Res. Lett., 29, 1851, https://doi.org/10.1029/2002GL014843, 2002.
Sommerfeld, R. A.: A branch grain theory of temperature gradient metamorphism in snow, J. Geophys. Res., 88, 1484–1494, https://doi.org/10.1029/JC088iC02p01484, 1983.
Thibert, E. and Dominé, F.: Thermodynamics and kinetics of the solid solution of HCl in ice, J. Phys. Chem. B, 101, 3554–3565, https://doi.org/10.1021/jp962115o, 1997.
Thibert, E. and Dominé, F.: Thermodynamics and kinetics of the solid solution of HNO3 in ice, J. Phys. Chem. B, 102, 4432–4439, https://doi.org/10.1021/jp980569a, 1998.
Thomas, J. L., Stutz, J., Lefer, B., Huey, L. G., Toyota, K., Dibb, J. E., and von Glasow, R.: Modeling chemistry in and above snow at Summit, Greenland – Part 1: Model description and results, Atmos. Chem. Phys., 11, 4899–4914, https://doi.org/10.5194/acp-11-4899-2011, 2011.
Town, M. S., Waddington, E. D., Walden, V. P., and Warren, S. G.: Temperatures, heating rates and vapour pressures in near-surface snow at the South Pole, J. Glaciol., 54, 487–498, https://doi.org/10.3189/002214308785837075, 2008.
Toyota, K., McConnell, J. C., Staebler, R. M., and Dastoor, A. P.: Air–snowpack exchange of bromine, ozone and mercury in the springtime Arctic simulated by the 1-D model PHANTAS – Part 1: In-snow bromine activation and its impact on ozone, Atmos. Chem. Phys., 14, 4101–4133, https://doi.org/10.5194/acp-14-4101-2014, 2014.
Traversi, R., Usoskin, I. G., Solanki, S. K., Becagli, S., Frezzotti, M., Severi, M., Stenni, B., and Udisti, R.: Nitrate in polar ice: a new tracer of solar variability, Sol. Phys., 280, 237–254, https://doi.org/10.1007/s11207-012-0060-3, 2012.
Traversi, R., Udisti, R., Frosini, D., Becagli, S., Ciardini, V., Funke, B., Lanconelli, C., Petkov, B., Scarchilli, C., Severi, M., and Vitale, V.: Insights on nitrate sources at Dome C (East Antarctic Plateau) from multi-year aerosol and snow records, Tellus B, 66, 22550, https://doi.org/10.3402/tellusb.v66.22550, 2014.
Ullerstam, M. and Abbatt, J. P. D.: Burial of gas-phase HNO3 by growing ice surfaces under tropospheric conditions, Phys. Chem. Chem. Phys., 7, 3596–3600, https://doi.org/10.1039/b507797d, 2005.
Ullerstam, M., Thornberry, T., and Abbatt, J. P. D.: Uptake of gas-phase nitric acid to ice at low partial pressures: evidence for unsaturated surface coverage, Faraday Discuss., 130, 211–226, https://doi.org/10.1039/b417418f, 2005.
Valdez, M. P., Dawson, G. A., and Bales, R. C.: Sulfur dioxide incorporation into ice depositing from the vapor, J. Geophys. Res., 94, 1095–1103, https://doi.org/10.1029/JD094iD01p01095, 1989.
Wolff, E. W., Jones, A. E., Bauguitte, S. J.-B., and Salmon, R. A.: The interpretation of spikes and trends in concentration of nitrate in polar ice cores, based on evidence from snow and atmospheric measurements, Atmos. Chem. Phys., 8, 5627–5634, https://doi.org/10.5194/acp-8-5627-2008, 2008.
Xueref, I. and Dominé, F.: FTIR spectroscopic studies of the simultaneous condensation of HCl and H2O at 190 K – Atmospheric applications, Atmos. Chem. Phys., 3, 1779–1789, https://doi.org/10.5194/acp-3-1779-2003, 2003.
Zhu, C., Xiang, B., Chu, L. T., and Zhu, L.: 308 nm photolysis of nitric acid in the gas phase, on aluminum surfaces, and on ice films, J. Phys. Chem. A, 114, 2561–2568, https://doi.org/10.1021/jp909867a, 2010.
Zondlo, M. A., Barone, S. B., and Tolbert, M. A.: Uptake of HNO3 on ice under upper tropospheric conditions, Geophys. Res. Lett., 24, 1391–1394, https://doi.org/10.1029/97GL01287, 1997.
Short summary
We develop a physically based parameterisation of the co-condensation process. Our model includes solid-state diffusion within a snow grain. It reproduces with good agreement the nitrate measurement in surface snow. Winter and summer concentrations are driven respectively by thermodynamic equilibrium and co-condensation. Adsorbed nitrate likely accounts for a minor part. This work shows that co-condensation is required to explain the chemical composition of snow undergoing temperature gradient.
We develop a physically based parameterisation of the co-condensation process. Our model...
Altmetrics
Final-revised paper
Preprint