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Volume 15, issue 2 | Copyright

Special issue: ROle of Nighttime chemistry in controlling the Oxidising Capacity...

Atmos. Chem. Phys., 15, 973-990, 2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 28 Jan 2015

Research article | 28 Jan 2015

Influence of aerosol chemical composition on N2O5 uptake: airborne regional measurements in northwestern Europe

W. T. Morgan1, B. Ouyang2, J. D. Allan1,3, E. Aruffo4, P. Di Carlo4, O. J. Kennedy2, D. Lowe1, M. J. Flynn1, P. D. Rosenberg5, P. I. Williams1,3, R. Jones2, G. B. McFiggans1, and H. Coe1 W. T. Morgan et al.
  • 1School of Earth, Atmospheric & Environmental Sciences, University of Manchester, Manchester, UK
  • 2Department of Chemistry, University of Cambridge, Cambridge, UK
  • 3National Centre for Atmospheric Science, University of Manchester, Manchester, UK
  • 4CETEMPS – Dipartimento di Fisica, Universita di L'Aquila, L'Aquila, Italy
  • 5School of Earth & Environment, University of Leeds, Leeds, UK

Abstract. Aerosol chemical composition was found to influence nighttime atmospheric chemistry during a series of airborne measurements in northwestern Europe in summer conditions, which has implications for regional air quality and climate. The uptake of dinitrogen pentoxide, γ (N2O5), to particle surfaces was found to be modulated by the amount of water content and ammonium nitrate present in the aerosol. The conditions prevalent in this study suggest that the net uptake rate of N2O5 to atmospheric aerosols was relatively efficient compared to previous studies, with γ (N2O5) values in the range 0.01–0.03. This is likely a consequence of the elevated relative humidity in the region, which promotes greater aerosol water content. Increased nitrate concentrations relative to particulate water were found to suppress N2O5 uptake. The results presented here contrast with previous ambient studies of N2O5 uptake, which have generally taken place in low-nitrate environments in the USA. Comparison of the N2O5 uptake derived from the measurements with a parameterised scheme that is based on the ratio of particulate water to nitrate yielded reasonably good agreement in terms of the magnitude and variation in uptake, provided the effect of chloride was neglected. An additional suppression of the parameterised uptake is likely required to fully capture the variation in N2O5 uptake, which could be achieved via the known suppression by organic aerosol. However, existing parameterisations representing the suppression by organic aerosol were unable to fully represent the variation in N2O5 uptake. These results provide important ambient measurement constraint on our ability to predict N2O5 uptake in regional and global aerosol models. N2O5 uptake is a potentially important source of nitrate aerosol and a sink of the nitrate radical, which is the main nocturnal oxidant in the atmosphere. The results further highlight the importance of ammonium nitrate in northwestern Europe as a key component of atmospheric composition in the region.

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This paper used observations from a research aircraft flying around the UK to investigate how air pollution in north-western Europe can alter nighttime chemical reactions in the atmosphere. These chemical reactions can worsen air quality in the region, as well as influence regional climate change. Ammonium nitrate aerosol appears to play an important role. The paper indicates that representation of these chemical reactions is poorly represented in models used for air quality and climate.
This paper used observations from a research aircraft flying around the UK to investigate how...