Articles | Volume 15, issue 7
https://doi.org/10.5194/acp-15-3773-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-3773-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
08 Apr 2015
Research article |
| 08 Apr 2015
Atmospheric oxidation of isoprene and 1,3-butadiene: influence of aerosol acidity and relative humidity on secondary organic aerosol
M. Lewandowski
CORRESPONDING AUTHOR
US Environmental Protection Agency, National Exposure Research Laboratory, Research Triangle Park, NC 27711, USA
M. Jaoui
Alion Science and Technology, Inc., PO Box 12313, Research Triangle Park, NC 27709, USA
J. H. Offenberg
US Environmental Protection Agency, National Exposure Research Laboratory, Research Triangle Park, NC 27711, USA
J. D. Krug
US Environmental Protection Agency, National Exposure Research Laboratory, Research Triangle Park, NC 27711, USA
T. E. Kleindienst
US Environmental Protection Agency, National Exposure Research Laboratory, Research Triangle Park, NC 27711, USA
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Cited
27 citations as recorded by crossref.
- Organosulfates in atmospheric aerosols in Shanghai, China: seasonal and interannual variability, origin, and formation mechanisms Y. Wang et al. 10.5194/acp-21-2959-2021
- High molecular weight organic compounds (HMW-OCs) in severe winter haze: Direct observation and insights on the formation mechanism F. Duan et al. 10.1016/j.envpol.2016.07.004
- Seasonal variation of aerosol acidity in Nagoya, Japan and factors affecting it Q. Song & K. Osada 10.1016/j.aeaoa.2020.100062
- Effect of relative humidity on SOA formation from aromatic hydrocarbons: Implications from the evolution of gas- and particle-phase species T. Chen et al. 10.1016/j.scitotenv.2021.145015
- The effect of particle acidity on secondary organic aerosol formation from <i>α</i>-pinene photooxidation under atmospherically relevant conditions Y. Han et al. 10.5194/acp-16-13929-2016
- On-line study of the influence of seed particle acidity on ozonation reaction of pyrene S. Zhu et al. 10.1016/j.atmosenv.2021.118615
- Concurrent dominant pathways of multifunctional products formed from nocturnal isoprene oxidation H. Li et al. 10.1016/j.chemosphere.2023.138185
- Aqueous-phase mechanism for secondary organic aerosol formation from isoprene: application to the southeast United States and co-benefit of SO<sub>2</sub> emission controls E. Marais et al. 10.5194/acp-16-1603-2016
- Spectroscopic Determination of Aerosol pH from Acid–Base Equilibria in Inorganic, Organic, and Mixed Systems R. Craig et al. 10.1021/acs.jpca.7b05261
- Chemical composition of isoprene SOA under acidic and non-acidic conditions: effect of relative humidity K. Nestorowicz et al. 10.5194/acp-18-18101-2018
- Secondary organic aerosol formation via multiphase reaction of hydrocarbons in urban atmospheres using CAMx integrated with the UNIPAR model Z. Yu et al. 10.5194/acp-22-9083-2022
- Different roles of water in secondary organic aerosol formation from toluene and isoprene L. Jia & Y. Xu 10.5194/acp-18-8137-2018
- Mixing order of sulfate aerosols and isoprene epoxydiols affects secondary organic aerosol formation in chamber experiments T. Nah et al. 10.1016/j.atmosenv.2019.116953
- Photochemical reactions of 1,3-butadiene with nitrogen oxide in different matrices: Kinetic behavior, humidity effect, product and mechanisms Q. Wang et al. 10.1016/j.scitotenv.2020.137747
- Investigation of the Acid-Mediated Photosensitized Reactions of Amphiphilic α-Keto Acids at the Air–Water Interface Using Field-Induced Droplet Ionization Mass Spectrometry C. Gong et al. 10.1021/jasms.1c00022
- Elucidating the mechanism of 1,3-butadiene oxidation with O2: A DFT study W. Zhang et al. 10.1016/j.molstruc.2023.137109
- Secondary Organic Aerosol Formation from Isoprene: Selected Research, Historic Account and State of the Art M. Claeys & W. Maenhaut 10.3390/atmos12060728
- Effect of Relative Humidity on the Rate of New Particle Formation for Different VOCs A. Flueckiger & G. Petrucci 10.3390/atmos15040480
- Effects of NOx, SO2 and RH on the SOA formation from cyclohexene photooxidation S. Liu et al. 10.1016/j.chemosphere.2018.10.180
- Organic Hydroxy Acids as Highly Oxygenated Molecular (HOM) Tracers for Aged Isoprene Aerosol M. Jaoui et al. 10.1021/acs.est.9b05075
- Evaluation of Biogenic Organic Aerosols in the Amazon Rainforest Using WRF‐Chem With MOSAIC J. Mao et al. 10.1029/2021JD034913
- Influence of relative humidity on cyclohexene SOA formation from OH photooxidation S. Liu et al. 10.1016/j.chemosphere.2019.05.131
- Yields and molecular composition of gas-phase and secondary organic aerosol from the photooxidation of the volatile consumer product benzyl alcohol: formation of highly oxygenated and hydroxy nitro-aromatic compounds M. Jaoui et al. 10.5194/acp-23-4637-2023
- Influence of urban pollution on the production of organic particulate matter from isoprene epoxydiols in central Amazonia S. de Sá et al. 10.5194/acp-17-6611-2017
- Secondary organic aerosol from chlorine-initiated oxidation of isoprene D. Wang & L. Ruiz 10.5194/acp-17-13491-2017
- Sulfur radical formation from the tropospheric irradiation of aqueous sulfate aerosols J. Cope et al. 10.1073/pnas.2202857119
- Atmospheric oxidation of 1,3-butadiene: characterization of gas and aerosol reaction products and implications for PM<sub>2.5</sub> M. Jaoui et al. 10.5194/acp-14-13681-2014
26 citations as recorded by crossref.
- Organosulfates in atmospheric aerosols in Shanghai, China: seasonal and interannual variability, origin, and formation mechanisms Y. Wang et al. 10.5194/acp-21-2959-2021
- High molecular weight organic compounds (HMW-OCs) in severe winter haze: Direct observation and insights on the formation mechanism F. Duan et al. 10.1016/j.envpol.2016.07.004
- Seasonal variation of aerosol acidity in Nagoya, Japan and factors affecting it Q. Song & K. Osada 10.1016/j.aeaoa.2020.100062
- Effect of relative humidity on SOA formation from aromatic hydrocarbons: Implications from the evolution of gas- and particle-phase species T. Chen et al. 10.1016/j.scitotenv.2021.145015
- The effect of particle acidity on secondary organic aerosol formation from <i>α</i>-pinene photooxidation under atmospherically relevant conditions Y. Han et al. 10.5194/acp-16-13929-2016
- On-line study of the influence of seed particle acidity on ozonation reaction of pyrene S. Zhu et al. 10.1016/j.atmosenv.2021.118615
- Concurrent dominant pathways of multifunctional products formed from nocturnal isoprene oxidation H. Li et al. 10.1016/j.chemosphere.2023.138185
- Aqueous-phase mechanism for secondary organic aerosol formation from isoprene: application to the southeast United States and co-benefit of SO<sub>2</sub> emission controls E. Marais et al. 10.5194/acp-16-1603-2016
- Spectroscopic Determination of Aerosol pH from Acid–Base Equilibria in Inorganic, Organic, and Mixed Systems R. Craig et al. 10.1021/acs.jpca.7b05261
- Chemical composition of isoprene SOA under acidic and non-acidic conditions: effect of relative humidity K. Nestorowicz et al. 10.5194/acp-18-18101-2018
- Secondary organic aerosol formation via multiphase reaction of hydrocarbons in urban atmospheres using CAMx integrated with the UNIPAR model Z. Yu et al. 10.5194/acp-22-9083-2022
- Different roles of water in secondary organic aerosol formation from toluene and isoprene L. Jia & Y. Xu 10.5194/acp-18-8137-2018
- Mixing order of sulfate aerosols and isoprene epoxydiols affects secondary organic aerosol formation in chamber experiments T. Nah et al. 10.1016/j.atmosenv.2019.116953
- Photochemical reactions of 1,3-butadiene with nitrogen oxide in different matrices: Kinetic behavior, humidity effect, product and mechanisms Q. Wang et al. 10.1016/j.scitotenv.2020.137747
- Investigation of the Acid-Mediated Photosensitized Reactions of Amphiphilic α-Keto Acids at the Air–Water Interface Using Field-Induced Droplet Ionization Mass Spectrometry C. Gong et al. 10.1021/jasms.1c00022
- Elucidating the mechanism of 1,3-butadiene oxidation with O2: A DFT study W. Zhang et al. 10.1016/j.molstruc.2023.137109
- Secondary Organic Aerosol Formation from Isoprene: Selected Research, Historic Account and State of the Art M. Claeys & W. Maenhaut 10.3390/atmos12060728
- Effect of Relative Humidity on the Rate of New Particle Formation for Different VOCs A. Flueckiger & G. Petrucci 10.3390/atmos15040480
- Effects of NOx, SO2 and RH on the SOA formation from cyclohexene photooxidation S. Liu et al. 10.1016/j.chemosphere.2018.10.180
- Organic Hydroxy Acids as Highly Oxygenated Molecular (HOM) Tracers for Aged Isoprene Aerosol M. Jaoui et al. 10.1021/acs.est.9b05075
- Evaluation of Biogenic Organic Aerosols in the Amazon Rainforest Using WRF‐Chem With MOSAIC J. Mao et al. 10.1029/2021JD034913
- Influence of relative humidity on cyclohexene SOA formation from OH photooxidation S. Liu et al. 10.1016/j.chemosphere.2019.05.131
- Yields and molecular composition of gas-phase and secondary organic aerosol from the photooxidation of the volatile consumer product benzyl alcohol: formation of highly oxygenated and hydroxy nitro-aromatic compounds M. Jaoui et al. 10.5194/acp-23-4637-2023
- Influence of urban pollution on the production of organic particulate matter from isoprene epoxydiols in central Amazonia S. de Sá et al. 10.5194/acp-17-6611-2017
- Secondary organic aerosol from chlorine-initiated oxidation of isoprene D. Wang & L. Ruiz 10.5194/acp-17-13491-2017
- Sulfur radical formation from the tropospheric irradiation of aqueous sulfate aerosols J. Cope et al. 10.1073/pnas.2202857119
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Latest update: 25 Apr 2024
Short summary
This work explores the impact of acidic sulfate aerosol on the formation of SOA from isoprene and 1,3-butadiene. This study expands on previous work by extending the analysis over a broader range of humidities and aerosol liquid water contents. Extending the experiments to a wider range of hydrocarbons and across a more realistic range of humidities provides data of greater atmospheric relevance and contributes to development of acidity-influenced SOA chemistry mechanisms in air quality models.
This work explores the impact of acidic sulfate aerosol on the formation of SOA from isoprene...
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