Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Atmos. Chem. Phys., 15, 13041-13057, 2015
https://doi.org/10.5194/acp-15-13041-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
Research article
25 Nov 2015
Signature of tropical fires in the diurnal cycle of tropospheric CO as seen from Metop-A/IASI
T. Thonat, C. Crevoisier, N. A. Scott, A. Chédin, R. Armante, and L. Crépeau Laboratoire de Météorologie Dynamique, CNRS, IPSL, École Polytechnique, Palaiseau, France
Abstract. Five years (July 2007 to June 2012) of CO tropospheric columns derived from the hyperspectral Infrared Atmospheric Sounding Interferometer (IASI) on-board Metop-A are used to study the impact of fires on the concentrations of CO in the troposphere. Following Chédin et al. (2005, 2008), who found a quantitative relation between the daily tropospheric excess of CO2 and fire emissions, we show that tropospheric CO also displays a diurnal signal with a seasonality that agrees well with the seasonal evolution of fires given by Global Fire Emission Database version 3 (GFED3.1) and Global Fire Assimilation System version 1 (GFAS1.0) emissions and Moderate Resolution Imaging Spectroradiometer (MODIS) Collection 5 burned area product. Unlike day- or night-time CO fields, which mix local emissions with nearby emissions transported to the region of study, the day–night difference of CO allows to highlight the CO signal due to local fire emissions. A linear relationship between CO fire emissions from the GFED3.1 and GFAS1.0 inventories and the diurnal difference of IASI CO was found over various regions in the tropics, with a better agreement with GFAS1.0 (correlation coefficient of R2 ∼ 0.7) than GFED3.1 (R2 ∼ 0.6). Based on the specificity of the two main phases of the combustion (flaming vs. smoldering) and on the vertical sensitivity of the sounder to CO, the following mechanism is proposed to explain such a CO diurnal signal: at night, after the passing of IASI at 21:30 local time (LT), a large amount of CO emissions from the smoldering phase is trapped in the boundary layer before being uplifted the next morning by natural and pyroconvection up to the free troposphere, where it is seen by IASI at 09:30 LT. The results presented here highlight the need to take into account the specificity of both the flaming and smoldering phases of fire emissions in order to fully take advantage of CO observations.

Citation: Thonat, T., Crevoisier, C., Scott, N. A., Chédin, A., Armante, R., and Crépeau, L.: Signature of tropical fires in the diurnal cycle of tropospheric CO as seen from Metop-A/IASI, Atmos. Chem. Phys., 15, 13041-13057, https://doi.org/10.5194/acp-15-13041-2015, 2015.
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Short summary
Based on 5 years of CO columns derived from the IASI sounder, we show that tropospheric CO displays a diurnal signal with a seasonality and intensity that agrees well with the evolution of fires. We suggest that at night, after the passing of IASI at 21:30, a large amount of CO emissions from the smoldering phase is trapped in the boundary layer before being uplifted the next morning by natural and pyroconvection up to the free troposphere.
Based on 5 years of CO columns derived from the IASI sounder, we show that tropospheric CO...
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