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Volume 14, issue 15
Atmos. Chem. Phys., 14, 7741–7756, 2014
https://doi.org/10.5194/acp-14-7741-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 14, 7741–7756, 2014
https://doi.org/10.5194/acp-14-7741-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 04 Aug 2014

Research article | 04 Aug 2014

Climatic controls on water vapor deuterium excess in the marine boundary layer of the North Atlantic based on 500 days of in situ, continuous measurements

H. C. Steen-Larsen1,2, A. E. Sveinbjörnsdottir3, A. J. Peters4, V. Masson-Delmotte1, M. P. Guishard4, G. Hsiao5, J. Jouzel1, D. Noone2, J. K. Warren4, and J. W. C. White6 H. C. Steen-Larsen et al.
  • 1Laboratoire des Sciences du Climat et de l'Environnement, UMR CEA-CNRS-UVSQ/IPSL 8212, Gif-sur-Yvette, France
  • 2Department of Atmospheric and Oceanic Sciences, and Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado, USA
  • 3Institute of Earth Sciences, University of Iceland, Reykjavik, Iceland
  • 4Bermuda Institute of Ocean Sciences, St. George's GE 01, Bermuda, UK
  • 5Picarro Inc., Santa Clara, California, USA
  • 6Institute of Arctic and Alpine Research, Campus Box 450, University of Colorado, Boulder, Colorado, USA

Abstract. Continuous, in situ measurements of water vapor isotopic composition have been conducted in the North Atlantic, at the Bermuda Islands (32.26° N, 64.88° W), between November 2011 and June 2013, using a cavity ring-down spectrometer water vapor isotope analyzer and an autonomous self-designed calibration system. Meticulous calibration allows us to reach an accuracy and precision on 10 min average of δ18O, δ D, and d-excess of, 0.14, 0.85, and 1.1‰, verified using two parallel instruments with independent calibration. As a result of more than 500 days with 6-hourly data the relationships between deuterium excess, relative humidity (RH), sea surface temperature (SST), wind speed, and wind direction are assessed. From the whole data set, 84 % of d-excess variance is explained by a strong linear relationship with relative humidity. The slope of this relationship (−42.6 ± 0.4‰ % (RH)) is similar to the theoretical prediction of Merlivat and Jouzel (1979) for SST between 20 and 30 °C. However, in contrast with theory, no effect of wind speed could be detected on the relationship between d-excess and relative humidity. Separating the data set into winter, spring, summer, and autumn seasons reveals different linear relationships between d-excess and humidity. Changes in wind directions are observed to affect the relationships between d-excess and humidity. The observed seasonal variability in the relationship between d-excess and relative humidity underlines the importance of long-term monitoring to make accurate conclusions.

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