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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
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Volume 13, issue 5 | Copyright
Atmos. Chem. Phys., 13, 2691-2702, 2013
https://doi.org/10.5194/acp-13-2691-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 06 Mar 2013

Research article | 06 Mar 2013

Re-evaluation of the lifetimes of the major CFCs and CH3CCl3 using atmospheric trends

M. Rigby1,2, R. G. Prinn2, S. O'Doherty1, S. A. Montzka3, A. McCulloch1, C. M. Harth4, J. Mühle4, P. K. Salameh4, R. F. Weiss4, D. Young1, P. G. Simmonds1, B. D. Hall3, G. S. Dutton3,6, D. Nance3,6, D. J. Mondeel3,6, J. W. Elkins3, P. B. Krummel5, L. P. Steele5, and P. J. Fraser5 M. Rigby et al.
  • 1School of Chemistry, University of Bristol, Bristol, UK
  • 2Center for Global Change Science, Massachusetts Institute of Technology, Cambridge, MA, USA
  • 3NOAA Earth System Research Laboratory, Boulder, CO, USA
  • 4Scripps Institution of Oceanography, University of California at San Diego, La Jolla, CA, USA
  • 5Centre for Australian Weather and Climate Research, CSIRO Marine and Atmospheric Research, Aspendale, Victoria, Australia
  • 6Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA

Abstract. Since the Montreal Protocol on Substances that Deplete the Ozone Layer and its amendments came into effect, growth rates of the major ozone depleting substances (ODS), particularly CFC-11, -12 and -113 and CH3CCl3, have declined markedly, paving the way for global stratospheric ozone recovery. Emissions have now fallen to relatively low levels, therefore the rate at which this recovery occurs will depend largely on the atmospheric lifetime of these compounds. The first ODS measurements began in the early 1970s along with the first lifetime estimates calculated by considering their atmospheric trends. We now have global mole fraction records spanning multiple decades, prompting this lifetime re-evaluation. Using surface measurements from the Advanced Global Atmospheric Gases Experiment (AGAGE) and the National Oceanic and Atmospheric Administration Global Monitoring Division (NOAA GMD) from 1978 to 2011, we estimated the lifetime of CFC-11, CFC-12, CFC-113 and CH3CCl3 using a multi-species inverse method. A steady-state lifetime of 45 yr for CFC-11, currently recommended in the most recent World Meteorological Organisation (WMO) Scientific Assessments of Ozone Depletion, lies towards the lower uncertainty bound of our estimates, which are 544861 yr (1-sigma uncertainty) when AGAGE data were used and 524561 yr when the NOAA network data were used. Our derived lifetime for CFC-113 is significantly higher than the WMO estimates of 85 yr, being 10999121 (AGAGE) and 10997124 (NOAA). New estimates of the steady-state lifetimes of CFC-12 and CH3CCl3 are consistent with the current WMO recommendations, being 11195132 and 11295136 yr (CFC-12, AGAGE and NOAA respectively) and 5.044.925.20 and 5.044.875.23 yr (CH3CCl3, AGAGE and NOAA respectively).

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