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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
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Volume 12, issue 15 | Copyright
Atmos. Chem. Phys., 12, 7117-7133, 2012
© Author(s) 2012. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 07 Aug 2012

Research article | 07 Aug 2012

An assessment of atmospheric mercury in the Community Multiscale Air Quality (CMAQ) model at an urban site and a rural site in the Great Lakes Region of North America

T. Holloway1, C. Voigt1, J. Morton1, S. N. Spak2, A. P. Rutter3, and J. J. Schauer4 T. Holloway et al.
  • 1Nelson Institute Center for Sustainability and the Global Environment (SAGE), University of Wisconsin-Madison, Madison, WI, USA
  • 2Public Policy Center (PPC), University of Iowa, Iowa City, IA USA
  • 3Civil and Environmental Engineering, Rice University, Houston, TX, USA
  • 4Civil and Environmental Engineering, University of Wisconsin-Madison, Madison, WI, USA

Abstract. Quantitative analysis of three atmospheric mercury species – gaseous elemental mercury (Hg0), reactive gaseous mercury (RGHg) and particulate mercury (PHg) – has been limited to date by lack of ambient measurement data as well as by uncertainties in numerical models and emission inventories. This study employs the Community Multiscale Air Quality Model version 4.6 with mercury chemistry (CMAQ-Hg), to examine how local emissions, meteorology, atmospheric chemistry, and deposition affect mercury concentration and deposition the Great Lakes Region (GLR), and two sites in Wisconsin in particular: the rural Devil's Lake site and the urban Milwaukee site. Ambient mercury exhibits significant biases at both sites. Hg0 is too low in CMAQ-Hg, with the model showing a 6% low bias at the rural site and 36% low bias at the urban site. Reactive mercury (RHg = RGHg + PHg) is over-predicted by the model, with annual average biases >250%. Performance metrics for RHg are much worse than for mercury wet deposition, ozone (O3), nitrogen dioxide (NO2), or sulfur dioxide (SO2). Sensitivity simulations to isolate background inflow from regional emissions suggests that oxidation of imported Hg0 dominates model estimates of RHg at the rural study site (91% of base case value), and contributes 55% to the RHg at the urban site (local emissions contribute 45%).

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