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Volume 12, issue 14 | Copyright

Special issue: Megacities: air quality and climate impacts from local to...

Atmos. Chem. Phys., 12, 6335-6355, 2012
© Author(s) 2012. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 23 Jul 2012

Research article | 23 Jul 2012

Impacts of East Mediterranean megacity emissions on air quality

U. Im and M. Kanakidou U. Im and M. Kanakidou
  • Environmental Chemical Processes Laboratory (ECPL), Department of Chemistry, University of Crete, P.O. Box 2208, 71003 Heraklion, Greece

Abstract. Megacities are large urban agglomerations with intensive anthropogenic emissions that have significant impacts on local and regional air quality. In the present mesoscale modeling study, the impacts of anthropogenic emissions from the Greater Istanbul Area (GIA) and the Greater Athens Area (GAA) on the air quality in GIA, GAA and the entire East Mediterranean are quantified for typical wintertime (December 2008) and summertime (July 2008) conditions. They are compared to those of the regional anthropogenic and biogenic emissions that are also calculated. Finally, the efficiency of potential country-based emissions mitigation in improving air quality is investigated.

The results show that relative contributions from both cities to surface ozone (O3) and aerosol levels in the cities' extended areas are generally higher in winter than in summer. Anthropogenic emissions from GIA depress surface O3 in the GIA by ~ 60% in winter and ~ 20% in summer while those from GAA reduce the surface O3 in the GAA by 30% in winter and by 8% in summer. GIA and GAA anthropogenic emissions contribute to the fine particulate matter (PM2.5) levels inside the cities themselves by up to 75% in winter and by 50% (GIA) and ~ 40% (GAA), in summer. GIA anthropogenic emissions have larger impacts on the domain-mean surface O3 (up to 1%) and PM2.5 (4%) levels compared to GAA anthropogenic emissions (<1% for O3 and ≤2% for PM2.5) in both seasons. Impacts of regional anthropogenic emissions on the domain-mean surface pollutant levels (up to 17% for summertime O3 and 52% for wintertime fine particulate matter, PM2.5) are much higher than those from Istanbul and Athens together (~ 1% for O3 and ~ 6% for PM2.5, respectively). Regional biogenic emissions are found to limit the production of secondary inorganic aerosol species in summer up to 13% (non-sea-salt sulfate (nss-SO42−) in rural Athens) due to their impact on oxidant levels while they have negligible impact in winter.

Finally, the responses to country-based anthropogenic emission mitigation scenarios inside the studied region show increases in O3 mixing ratios in the urban areas of GIA and GAA, higher in winter (~ 13% for GIA and 2% for GAA) than in summer (~ 7% for GIA and <1% for GAA). On the opposite PM2.5 concentrations decrease by up to 30% in GIA and by 20% in GAA with the highest improvements computed for winter. The emission reduction strategy also leads to domain-wide decreases in most primary pollutants like carbon monoxide (CO) or nitrogen oxides (NOx) for both seasons. The results show the importance of long range transport of pollutants for the air quality in the East Mediterranean. Thus, improvements of air quality in the East Mediterranean require coordinated efforts inside the region and beyond.

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